Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements

Abstract— Organic contamination (?2965 and ?1260 cm^?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.     

Mineralogy and petrography of C asteroid regolith: The Sutter's Mill CM meteorite

Based upon our characterization of three separate stones by electron and X‐ray beam analyses, computed X‐ray microtomography, Raman microspectrometry, and visible‐IR spectrometry, Sutter's Mill is a unique regolith breccia consisting mainly of various CM lithologies. Most samples resemble existing available CM2 chondrites, consisting of chondrules and calcium‐aluminum‐rich inclusion (CAI) set within phyllosilicate‐dominated matrix (mainly serpentine), pyrrhotite, pentlandite, tochilinite, and variable amounts of Ca‐Mg‐Fe carbonates. Some lithologies have witnessed sufficient thermal metamorphism to transform phyllosilicates into fine‐grained olivine, tochilinite into troilite, and destroy carbonates. One finely comminuted lithology contains xenolithic materials (enstatite, Fe‐Cr phosphides) suggesting impact of a reduced asteroid (E or M class) onto the main Sutter's Mill parent asteroid, which was probably a C class asteroid. One can use Sutter's Mill to help predict what will be found on the surfaces of C class asteroids such as Ceres and the target asteroids of the OSIRIS‐REx and Hayabusa 2 sample return missions (which will visit predominantly primitive asteroids). C class asteroid regolith may well contain a mixture of hydrated and thermally dehydrated indigenous materials as well as a significant admixture of exogenous material would be essential to the successful interpretation of mineralogical and bulk compositional data.     

Silicon flux and distribution of biogenic silica in deep-sea sediments in the western North Pacific Ocean

We investigated biogenic silica, several biological components, and silicate in pore-water in the abyssal sediment to determine silicon flux of western North Pacific during several cruises. The surficial sediment biogenic silica content was high at high latitudes with the boundary running along the Kuroshio Extension, and maximum values (exceeding 20%) were found in the Oyashio region. In the subtropical region to the south, most stations showed less than 5% biogenic silica content. This distribution pattern reflected primary production and ocean currents in the surface layer very well. Pore-water samples were collected from 4 stations along the east coast of Japan. The highest asymptotic silicic acid concentration (670 μmol L^?1) in pore-water was observed at the junction of Kuroshio and Oyashio, followed by samples from the Oyashio region. It is at the southern station that the lowest value (450 μmol L^?1) was observed, and the primary production is low under the influence of Kuroshio there. The diffusive flux followed the same geographic trend as the asymptotic silicic acid concentrations did, ranging 77–389 mmol m^?2 yr ^?1. Multiple sampling of pore-water was conducted throughout the year at one station at high latitude. The average annual biogenic silica rain flux observed using sediment traps was 373 mmol m^?2 yr^?1; the diffusive flux and burial flux at the sediment–water interface were 305 and 9 mmol m^?2 yr^?1, respectively. We concluded that most of the settling silica particles dissolved and diffused at the sediment–water interface and approximately 3% only were preserved in this area. In addition, the obvious time lag observed between the peak rain flux and the maximum diffusive flux suggested that primary production in the surface layer has a great influence on the sedimentation environment of abyssal western North Pacific. These transitions of Si flux at the sediment–water interface were considerably greater in northwestern North Pacific than in southwestern North Pacific. In addition, a station in the Philippine Sea indicated high biogenic silica content because of Ethmodiscus ooze, which are scattered randomly on the sea floor in the subtropical region.     

Holocene coastal uplift in the western Pacific Rim in the context of late Quaternary uplift

This paper reviews recent studies of Holocene coastal uplift in tectonically active areas near the plate boundaries of the western Pacific Rim. Emergent Holocene terraces exist along the coast of North Island of New Zealand, the Huon Peninsula of Papua New Guinea, the Japanese Islands, and Taiwan. These terraces have several features in common. All comprise series of subdivided terraces. The highest terrace is a constructional terrace, underlain by estuarine or marine deposits, and the lower terraces are erosional, cutting into transgressive deposits or bedrock. The highest terrace records the culmination of Holocene sea-level rise at ca. 6–6.5 ka BP. Lower terraces were coseismically uplifted. Repeated major earthquakes have usually occurred at ka intervals and meter-scale uplift. The maximum uplift rate and number of terraces are surprisingly similar, about 4 m/ka and seven to four major steps in North Island, Huon Peninsula, and Japan. Taiwan, especially along the east coast of the Coastal Range, is different, reaching a maximum uplift rate of 15 m/ka with 10 subdivided steps. They record a very rapid uplift. Comparison between short-term (Holocene) and long-term since the last interglacial maximum (sub-stage 5e) uplift rates demonstrates that a steady uplift rate (Huon Peninsula) or accelerated uplift toward the present (several areas of Japan and North Island) has continued at least since isotope sub-stage 5e. Rapid uplift in eastern Taiwan probably started only in the early Holocene, judging from the absence of any older marine terraces. Most of the causative faults for the coastal uplift may be offshore reverse faults, branched from the main plate boundary fault, but some of them are onshore faults, which deformed progressively with time.     

Touhuanping Fault, an active wrench fault within fold-and-thrust belt in northwestern Taiwan, documented by spatial analysis of fluvial terraces

This study aims at the recent activity and development of an active wrench fault, the Touhuanping Fault in northwestern Taiwan. Northwestern Taiwan has been proposed in a current situation between the mature to waning collision in terms of tectonic evolution. The main drainage in this area, the Chungkang River, flows close to the trace of the fault mentioned above. We examined various types of deformation of fluvial terraces along the Chungkang River as a key to understanding the nature and rate of the late Quaternary tectonics. The E–W trending Touhuanping Fault has long been mapped as a geological boundary fault, but its recent activity was suspected. Field survey revealed that its late Quaternary activity is recorded in the offset fluvial terraces. Our result shows dextral slip and vertical offset with upthrown side on the south, and activated at least twice since the emergence of terrace 4 (older terrace 3 with OSL date of ca. 80 ka). Total amount of offset recorded in the Touhuanping terrace sequence is 15 m for dextral and 10 m for vertical offset. Estimated recurrence time of earthquake rupture may be a few tens of thousand years. Uplift on the upthrown side of the Touhuanping Fault also resulted in the formation of drowned valleys which were graded to terrace 4. Other deformation features, such as back-tilting, westward warping, and a range-facing straight scarp, were also identified. A second-order anticline roughly parallel to the Touhuanping Fault is suggested to be the origin of the northward tilting on terrace 3; it could have resulted from a flower structure on the Touhuanping Fault at shallow depth. This may demonstrate that the buried segment of the Touhuanping Fault has also been active since 80 ka. In the northern study area, the westward warping at terrace 2 probably represents late Quaternary activity of another NE–SW trending Hsincheng Fault.     

Effect of biogeochemical diagenesis on sediment fabric in shallow marine carbonate sediments near the Dry Tortugas, Florida

 Shallow marine carbonate sediments near the Dry Tortugas undergo extensive biogeochemical diagenesis upon deposition, resulting in postdepositional fabric comprised of micritic aggregates of clay-sized particles, a matrix of peloidal mud, and intraparticular cementation. Freshly deposited primary skeletons, mostly Halimeda fragments, yield micritic aggregates of clay-sized particles, which then form peloidal mud fabric upon compaction. The cryptocrystalline particles produced by micritization are later replaced by high magnesian calcite. Cementation is observed in the intra-particular microenvironment. However, no inter-particular, grain-binding cement was detected throughout the gravity core samples investigated.     

Kinetics of organic matter degradation in the Murchison meteorite for the evaluation of parent‐body temperature history

Abstract– To evaluate kinetic parameters for thermal degradation of organic matter, in situ heating experiments of insoluble organic matter (IOM) and bulk of Murchison (CM2) meteorite were conducted under Fourier transform infrared micro‐spectroscopy combined with a heating stage. Decreases of aliphatic C–H band area under Ar flow were well fitted with Ginstling‐Brounshtein three‐dimensional diffusion model, and the rate constants for decreases of aliphatic C–H were determined. Activation energies E_a and frequency factors A obtained from these rate constants at different temperatures using the Arrhenius equation were E_a = 109 ± 3 kJ mol^?1 and A = 8.7 × 10⁴ s^?1 for IOM, and E_a = 61 ± 6 kJ mol^?1 and A = 3.8 s^?1 for bulk, respectively. Activation energy values of aliphatic C–H decrease are larger for IOM than bulk. Hence, the mineral assemblage of the Murchison meteorite might have catalytic effects for the organic matter degradation. Using obtained kinetic expressions, the time scale for metamorphism can be estimated for a given temperature with aliphatic C–H band area, or the temperature of metamorphism can be estimated for a given time scale. For example, using the obtained kinetic parameters of IOM, aliphatic C–H is lost approximately within 200 years at 100 °C and 100 Myr at 0 °C. Assuming alteration period of 7.5 Myr, alteration temperatures could be calculated to be <15 ± 12 °C. Aliphatic C–H decrease profiles in a parent body can be estimated using time–temperature history model. The kinetic expression obtained by the infrared spectral band of aliphatic C–H could be used as an alternative method to evaluate thermal processes of organic matter in carbonaceous chondrites.     

Review of paleoseismological and active fault studies in Taiwan in the light of the Chichi earthquake of September 21, 1999

This paper reviews the research on active and earthquake faults in Taiwan conducted prior and after the 1999 Chichi earthquake. The Chichi earthquake plays as a turning point of the relevant studies, since the 1999 coseismic surface rupture exactly follows preexisting fault scarps, created in turn by previous seismic events along the Chelungpu Fault. This fact indicates that the precise mapping on the other active faults is fundamental to predict the location of surface rupture caused by large future earthquakes. Since 1999, many trenching studies have been carried out along the Chichi earthquake fault. A few of them demonstrates that the penultimate event is as young as probably only 200–430 years old; however, some others show a rather old age of several hundreds years or even older for the last faulting event before 1999. More trenching studies are necessary for such a long fault in order to understand the possible segmentation features and the correlation of the paleoseismic events identified along the entire fault length. In addition, we further discuss the offshore faulting associated with seismic event along the eastern coast of Taiwan, where the multiple Holocene terraces are well known.     

Aggregation of montmorillonite and organic matter in aqueous media containing artificial seawater

Background  

The dispersion-aggregation behaviors of suspended colloids in rivers and estuaries are affected by the compositions of suspended materials (i.e., clay minerals vs. organic macromolecules) and salinity. Laboratory experiments were conducted to investigate the dispersion and aggregation mechanisms of suspended particles under simulated river and estuarine conditions. The average hydrodynamic diameters of suspended particles (representing degree of aggregation) and zeta potential (representing the electrokinetic properties of suspended colloids and aggregates) were determined for systems containing suspended montmorillonite, humic acid, and/or chitin at the circumneutral pH over a range of salinity (0 – 7.2 psu).