A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.     

应用MODIS影像监测海州湾无机氮浓度的研究

利用连云港海州湾2004年至2006年的水质监测资料,选取时间上完全同步的空间分辨率为500m的MODIS Terra 1B数据,对反射率的单波段因子和波段组合因子与可溶无机氮（DIN）质量浓度之间进行相关分析。从总体上看,单波段因子与DIN质量浓度的相关性较低,但在含氮基团倍频和合频吸收带附近的波段（波段2、7）反射率与DIN质量浓度呈负相关,显示了含氮基团对水体光谱特征的影响;在波段组合因子中,因子F11（3.4）和F13（3.4）与DIN质量浓度呈显著正相关,用这两个因子建立DIN质量浓度的回归模型,R^2都达到0．7以上,相对精度达70％左右,最终选择因子F11（3.4）的线性模型反演该海域的DIN质量浓度,其结果与实际情况非常吻合。     

菏泽市土地利用存在的问题及潜力分析

1土地利用特点 泽市土地总面积121.94万hm2,已利用土地115.28万hm2,土地利用率为94.54%,农用土地97.99万hm2,占土地总面积的80.36%,其中耕地83.30万hm2,占土地总面积的.68.26%,园地1.22万hm2,占土地总面积的1.00%,林地6.38万hm2,占土地总面积的5.22%;其他农用地7.24万hm2,占土地总面积的5.88%;建设用地18.93万hm2,占土地总面积的15.52%;未利用土地5.35万hm2,占土地总面积的4.12%.     

菏泽市提高财务管理水平适应国土资源管理新形势

近几年,菏泽市国土资源事业发展迅速,土地收益逐年增加、土地整理项目效益日渐显现、土地市场秩序逐渐规范、涉矿项目由单纯的黏土逐渐将成为华东地区唯一一块未开发的整装煤田。随着体制调整逐步到位,财务部门面临新的形势,横向衍生出具有专业职能的事业单位,纵向延伸到县乡,国土资源财务管理范围和难度加大。为此,必须进一步规范国土资源财务管理,加强各项资金的监督与管理,更好地发挥国土资源在经济社会发展中的保障作用。     

海州湾海域赤潮灾害与成因探讨

2004～2006年海州湾海域共发生有记录的赤潮7起,涉及海域面积近2000 km2,海洋生态环境受到严重威胁.本文根据近年来海州湾赤潮发生的情况和相关资料,阐述了海州湾赤潮的发生及其影响、赤潮主要藻种,从物理、化学、气候、生物等因素上分析和讨论了海州湾赤潮发生的原因,并在此基础上提出了相应的防治对策:(1)加强赤潮的研究工作;(2)控制陆源污染物的入海,防止海水富营养化;(3)加强赤潮监测.     

基于GIS与三维激光扫描的占建筑保护研究

以三维激光扫描点云数据作为基础数据,以河南大学明伦校区近代建筑群为研究对象,结合地理数据库和三维建模技术.建立了古建筑数据库.利用ArcGIS Engine二次开发平台,设计了基于GIS的古建筑数字化保护系统,并同时探讨了系统建立过程中的若干技术问题.研究结果说明.基于三维激光扫描和GIS的新技术手段,为古建筑的数字化保护带来了新的契机.     

对《土地利用现状分类》中有关问题的探讨

按照土地的属性、利用方式和覆盖特征,结合土地利用特点,对土地利用现状分类含义进行了深入的研究,认为部分土地分类的含义值得商榷,并提出了解决问题的途径.     

3维地形环境仿真中点阵文本技术研究

在3维地形环境仿真中,经常需要输出大量文本信息.通常的做法是用位图方式进行渲染,但在某些情况下(如嵌入式操作系统)无法实现这一功能.针对某些3维地形环境仿真中位图方式渲染文本的局限性,研究如何用点阵方式渲染文本.研究内客包括点阵字库的创建和点阵文本的渲染,并根据实时渲染中不同类型文本的特点,将点阵文本的渲染分为缓存和非缓存两种方式.最后在基于VxWorks嵌入式系统的3维地形环境中实现了点阵文本的渲染.     

Study on the isotherms of the interaction between suspended particles and Cu (II) in the Huanghe River

The isotherms of the interaction between the suspended particles and Cu²⁺, and the effects of lysine and asparaginic acid on the isotherms in the Huanghe (Yellow) River were studied by applying the theory and method of interfacial stepwise ion/coordination particle exchange. We obtained a new stepped river isotherm, formed by two curves joined together with a “plateau” in the middle. The adsorption equilibrium constantsK ₁ andK ₂ were calculated by using the isothermal equation of surface stepwise ion exchange. Amino acid in small amount promotes exchange adsorption of the suspended particles with Cu²⁺. The degree of promotive action relates to the isoelectric point of amino acid. The promotive effect of lysine is bigger than that of asparaginic acid. Project 29361001 supported by NSFC.     

Total lipid and fatty acid composition of eight strains of marine diatoms

Fatty acid composition and total lipid content of 8 strains of marine diatoms (Nitzschia frustrula, Nitzschia closterium, Nitzschia incerta, Navicula pelliculosa, Phaeodactylum tricornutum, Synedra fragilaroides) were examined. The microalgae were grown under defined conditions and harvested at the late exponential phase. The major fatty acids in most strains were 14∶0 (1.0%–6.3%), 16∶0 (13.5–26.4%), 16∶1n−7 (21.1%–46.3%) and 20∶5n−3 (6.5%–19.5%). The polyunsaturated fatty acids 16∶2n−4, 16∶3n−4, 16∶4n−1 and 20∶4n−6 also comprised a significant proportion of the total fatty acids in some strains. The characteristic fatty acid composition of diatoms is readily distinguishable from those of other microalgal groups. Significant concentration of the polyunsaturated fatty acid 20∶5n−3 (eicosapentaenoic acid) was present in each strain, with the highest proportion in B222 (19.5%). Project supported by the Hi-Tech “863” Programs of the China Ministry of Science and Technology (863-819-02-01).