Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.     

Anisotropy from full waveform inversion of multicomponent seismic data using a hybrid optimization method

Seismic waveforms contain valuable information about the media, but the waveform inversion is a non‐linear problem. We present a waveform inversion method that combines a local optimization method with a genetic algorithm to determine the anisotropic parameters of a horizontally stratified medium. Synthetic seismograms for a horizontally stratified anisotropic medium are calculated using the reflectivity technique. In the initial stage of the inversion, the global space‐sampling properties of the genetic algorithm are used to direct the search to the region close to the global solution. This solution is then further improved using a conjugate‐gradient method. The numerical experiments performed with noisy synthetic data show that our hybrid optimization method satisfactorily reconstructs the anisotropic parameters at a reasonable computing cost while the range of slowness is adequate. We found that (i) for small‐angle data neither single‐ nor multiple‐component data are sufficient to determine the anisotropic parameters uniquely; (ii) for medium‐angle data the multiple‐component data are sufficient to determine the anisotropic parameters exactly whereas the single‐component data are not sufficient; and (iii) for wide‐angle data, either single‐ or multiple‐component data are sufficient to determine the anisotropic parameters accurately.     

Visualization issues in the development of electronic atlas in China

In this paper, we discuss the development of electronic atlas in China, with focus on the issues of visualization. We particularly categorise this development into four periods, and then analyse the characters in each period and discuss the visualization issues. The four periods are highlighted: 1) Infant period (<1990) characterized as computer assisted mapping with products of screen maps; 2) Starting period (1991-1995) characterized as object-oriented mapping with products of interactive maps/atlases; 3) Advancing period (1996-2000) characterized as integrated mapping with products of multimedia cartographic maps; 4) New era (> 2001) characterized as web mapping and adaptive map design with products of Internet maps and atlas as well as adaptive maps. It is obvious that the development follows the logical way from static to dynamic, and even real time visualization, from single user to multiple users, from presentation to exploration for effective communication and knowledge construction. Current research and development projects are focused on customisation of atlas information systems for real-time tasks, Internet operability, small displays and mobile environments. The major challenges involved in each of such customisation processes are identified and commented in relation to the further development of visualization.     

Grassland productivity in an alpine environment in response to climate change

Situated in a climatically stressful environment, alpine grassland is sensitive to subtle climate changes in its productivity. We remedy the current deficiency in studying grassland productivity by taking the integrated effect of all relevant factors into consideration. The relative importance of temperature, rainfall and evaporation to the alpine grassland productivity in western China was determined through analysis of their relationship with the normalized difference vegetation index (NDVI) between 1981 and 2000. Climate warming stimulated grassland productivity in the 1980s, but hampered it in the 1990s. Temperature is more important than rainfall to grassland productivity early in the growing season. However, their relative importance is reversed late in the growing season. Monthly summer month rainfall modified by maximum monthly temperature is a good predictor of alpine grassland productivity at 62.0 per cent. However, the best predictor is water deficiency, which is able to improve the estimation accuracy to 78.3 per cent. Hence, the impact of temperature on grassland productivity is better studied indirectly through evaporation.     

福建省水氡观测资料变化规律与质量分析

本文对福建省水氡观测资料变化规律进行分析,并试图利用相对均方差、拟合噪声水平和相对年变幅等三项指标,对福建省8个水氡点的观测资料质量进行初步探索。     

贵州省六盘水市石漠化遥感-GIS评价

以六盘水市为研究区，以ETM遥感数据和1：25万的国家标准基础地理数据为主要数据源，辅助以地面样地调查数据，建立石漠化与诸因子相关关系模型，将诸因子转化为遥感定量指标，研究遥感专题信启，快速提取，形成RS、GIS集成的石漠化信息提取技术。通过以上技术处理，实现了六盘水市喀斯特地区的石漠化现状遥感—GIS快速调查评价，得到六盘水市石漠化信息地理数据库等数据，为政府部门实现宏观决策提供理论依据和科学数据。     

Composition and flux of suspended organic matter in the middle and lower reaches of the Changjiang (Yangtze River) — impact of the Three Gorges Dam and the role of tributaries and channel erosion

To investigate the sources of particulate organic matter (POM) and the impact of Three Gorges Dam (TGD), two large lakes and erosion processes on determining the composition and flux of POM in low water discharge periods along the middle and lower Changjiang, suspended particulate samples were collected along the middle and lower reaches of the Changjiang (Yangtze River) in January 2008. Organic geochemistry of bulk sediment (particulate organic carbon, organic carbon to nitrogen molar ratio (C/N), stable carbon isotope (δ¹³C) and grain size) and biomarker of bulk sediment (lignin phenols) were measured to trace the sources of POM. The range of C/N ratios (6.4–8.9), δ¹³C (?24.3‰ – ?26.2‰) and lignin phenols concentration Λ8 (0.45 mg/100 mg OC‐2.00 mg/100 mg OC) of POM suggested that POM originated from the mixture of soil, plant tissue and autochthonous organic matter (OM) during the dry season. POM from lakes contained a higher portion of terrestrial OM than the mainstream, which was related to sand mining and hydropower erosion processes. A three end‐member model based on δ¹³C and Λ8 was performed. The results indicated that soil contributed approximately 50% of OM to the POM, which is the dominant OM source in most stations. POM composition was affected by total suspended matter (TSM) and grain size composition, and the direct OM input from two lakes and channel erosion induced OM. The lower TSM concentration in January 2008 was mainly caused by seasonal variations; the impact from the TGD in the dry season was relatively small. A box model indicated that more than 90% of the terrestrial OM transported by the Changjiang in January 2008 was from the middle and lower drainage basins. Channel erosion induced OM, and contributions from Poyang Lake were the major terrestrial OM sources in the dry season. Copyright © 2012 John Wiley & Sons, Ltd.     

Multi‐temporal scale changes of streamflow and sediment load in a loess hilly watershed of China

Global climate change and diverse human activities have resulted in distinct temporal–spatial variability of watershed hydrological regimes, especially in water‐limited areas. This study presented a comprehensive investigation of streamflow and sediment load changes on multi‐temporal scales (annual, flood season, monthly and daily scales) during 1952–2011 in the Yanhe watershed, Loess Plateau. The results indicated that the decreasing trend of precipitation and increasing trend of potential evapotranspiration and aridity index were not significant. Significant decreasing trends (p < 0.01) were detected for both the annual and flood season streamflow, sediment load, sediment concentration and sediment coefficient. The runoff coefficient exhibited a significantly negative trend (p < 0.01) on the flood season scale, whereas the decreasing trend on the annual scale was not significant. The streamflow and sediment load during July–August contributed 46.7% and 86.2% to the annual total, respectively. The maximum daily streamflow and sediment load had the median occurrence date of July 31, and they accounted for 9.7% and 29.2% of the annual total, respectively. All of these monthly and daily hydrological characteristics exhibited remarkable decreasing trends (p < 0.01). However, the contribution of the maximum daily streamflow to the annual total progressively decreased (?0.07% year^?1), while that of maximum daily sediment load increased over the last 60 years (0.08% year^?1). The transfer of sloping cropland for afforestation and construction of check‐dams represented the dominant causes of streamflow and sediment load reductions, which also made the sediment grain finer. Copyright © 2015 John Wiley & Sons, Ltd.     

雅安芦山4.20震后县级单元生态系统风险评价

区域生态风险评价是对各种生态风险及环境问题进行评价和管理的重要手段。针对雅安地震灾区特殊的自然地理及生态环境特征,选取芦山县为研究对象,采用遥感、GIS及SPSS统计分析的方法,通过风险源、风险受体、暴露和易损性分析,建立生态风险综合评价模型,划分生态风险区类型,进而提出生态风险管理对策。结果表明:1)微度和低度生态风险区集中分布在高海拔的森林及草地生态系统,该区生物多样性丰富,抗干扰能力较强,地质灾害及人类活动影响较小;2)中度和高度生态风险区具有沿农田及建设用地生态系统集聚分布的特征,该区地质灾害频繁,地壳活动性较强,生态系统抵抗灾害的能力较差。研究结果可为地震灾区防御、规避风险及安全选址提供科学依据。     

鹿井铀矿床铀矿物学特征

鹿井矿床位于南华活动带华夏褶皱带武功—诸广断隆区,闽、赣后加里东褶皱地块西缘,诸广山复式岩体中段,受遂川断裂及热水断裂组成的地堑式断陷带控制。本文主要对鹿井矿床内铀矿物的赋存状态、成分特征及组合特征进行了研究。