利用膨润土与工业废渣制轻质保温材料

本文介绍了利用膨润土、钙质造纸废渣制备轻质保温材料的研究,分析了膨润土在轻质保温材料制备中的作用,优选出制备轻质保温材料的配方和工艺。该材料的导热系数为０ ．１７１ Ｗ／ｍ·Ｋ,抗压强度约为９ ．３７ ｋｇ／ｃｍ２ ,容重为０ ．４９ ｇ／ｃｍ３ 。     

对矿物包裹体溶液性质的新认识——兼论含矿溶液是酸性溶液的地质证据

对金属矿床成矿溶液的性质 ,特别是 pH值 (酸碱度 )的确定 ,是认识含矿溶液的成因、成矿条件和成矿机理的关键。目前对成矿溶液性质的研究主要局限在对围岩蚀变矿物包裹体的测定方面 ,并得出近中性热卤水成矿的结论。作者认为 ,多数围岩蚀变矿物的包裹体溶液不能代表原成矿溶液的性质 ,“近中性的热卤水成矿”的认识有误 ,应是酸性水形成的含矿溶液成矿 ,并从矿物包裹体溶液的特征、Roedder的高金属含量的矿物包裹体溶液的发现、氢氧同位素资料、矿物包裹体中高卤水溶液的起源以及成矿溶液的演化机理等方面论述了酸性金属含矿溶液的成因及成矿演化过程。     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

山东开元洞发现典型"北方型"石笋微生长层

石笋中微层的形成一般认为与地表气候环境具有明显的季节变化有关~([1,2]).石笋微层的发育不仅具有明确的年代学意义~([2]),还具有重要的气候环境变化指示意义~([2,3]).     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

关于间接测定碘的分析方法研究

用硝基苯萃取[Cd（Phen）3]^2＋I2^-离子对,再用盐酸反萃取,利用氢化物发生-原子荧光光谱法测定镉的含量,从而间接测定碘。实验在pH=5．2的NaAc-HAc缓冲体系下进行,优化了还原剂KBH;中邻菲罗啉的浓度,镉溶液用量,萃取剂硝基苯的用量,反萃取盐酸的酸度,并制备碘的标准曲线,其线性相关系数R2≥0．9942,线性范围0～10ng／mL,精密度为8．5％,检出限0．80ng／mL,利用标准曲线测出水样中碘的浓度为17．78ng／mL,结果令人满意。实验表明,开发原子荧光光谱间接分析方法,使其能够准确测量更多种类的元素,有着十分积极的意义,同时也能够促进该方法得到更广范的应用。     

大气污染物SOx输送方程的尺度分析

文中用量纲分析方法分析了控制大气污染物输送方程的动力学特性。提出了 6种反映大气污染物输送过程中各种动力、物理和化学过程相对重要性的动力学参数。并以硫氧化物为例进行了各参数量级大小分析 ,尤其对 3种起汇作用 (去除机理 )的机理 (化学转化、干沉降和湿清除 )在不同尺度大气污染过程中的作用进行了详细分析。结果表明 :在一般情况下 ,SO2 的气相化学作用小于干沉降和湿清除的作用 ;干沉降作用很依赖于模式最底层厚度的选取 ;在有降雨时湿清除作用一般较大。文中还对大气污染物SOx 输送方程各项特征量的量级作了分析对比 ,得出了控制不同尺度大气污染物输送过程的零级近似方程和一级近似方程 ,并指出了这些方程的基本特征     

Multi-stage onset of the summer monsoon over the western North Pacific

 The climatological summer monsoon onset displays a distinct step wise northeastward movement over the South China Sea and the western North Pacific (WNP) (110°–160°E, 10°–20°N). Monsoon rain commences over the South China Sea-Philippines region in mid-May, extends abruptly to the southwestern Philippine Sea in early to mid-June, and finally penetrates to the northeastern part of the domain around mid-July. In association, three abrupt changes are identified in the atmospheric circulation. Specifically, the WNP subtropical high displays a sudden eastward retreat or quick northward displacement and the monsoon trough pushes abruptly eastward or northeastward at the onset of the three stages. The step wise movement of the onset results from the slow northeastward seasonal evolution of large-scale circulation and the phase-locked intraseasonal oscillation (ISO). The seasonal evolution establishes a large-scale background for the development of convection and the ISO triggers deep convection. The ISO over the WNP has a dominant period of about 20–30 days. This determines up the time interval between the consecutive stages of the monsoon onset. From the atmospheric perspective, the seasonal sea surface temperature (SST) change in the WNP plays a critical role in the northeastward advance of the onset. The seasonal northeastward march of the warmest SST tongue (SST exceeding 29.5 °C) favors the northeastward movement of the monsoon trough and the high convective instability region. The seasonal SST change, in turn, is affected by the monsoon through cloud-radiation and wind-evaporation feedbacks. Received: 19 October 1999 / Accepted: 5 June 2000     

郑州市大雾气候特点及一次个例分析

为了了解近20 a郑州市大雾的时空变化特征,根据1980-2005年郑州市大雾观测记录,统计分析了这一时期郑州市大雾的变化特点及产生大雾时的气象要素特征;并利用河南省地面和探空观测资料以及NCEP1°×1°再分析资料,从要素场、大气稳定度等方面,对2007年12月25-27日郑州市大雾形成原因进行了分析.结果表明:郑州市年雾日数呈下降趋势,每月都可以出现大雾,但12月最多,6月最少.降水后较大的相对湿度、稳定的大气层结以及近地层较小风速等是大雾形成的必要条件.     

NCAR绘图软件在Windows下的编程

介绍了NCAR绘图软件在Windows下的编程方法和具体实现，解决了在科研绘图工作中遇到的一些实际问题，对在Windows下编程的静态链接和动态链接进行了分析和研究，为Fortran编程员提供了在Windows下编程的基础。