Mass balance of heavy metals in the seto inland sea, Japan

To discuss the geochemical and environmental behavior of heavy metals in the Seto Inland Sea, the largest semi-enclosed coastal sea in Japan, mass balances of Cu and Zn were studied by application of a simple box model using sedimentation rates and heavy metal contents of core sediments. In 1980, total sedimentary loads of Cu and Zn over the whole area of the Sea were estimated to be 630 and 3500 tons year⁻¹, respectively. Further, the sedimentary loads without (natural) and with human activities were estimated separately to be, respectively, 320 and 310 tons year⁻¹ for Cu and 1800 and 1700 tons year⁻¹ for Zn. Total inputs of Cu and Zn into the Sea, in 1980 were estimated to be 870 and 4250 tons year⁻¹ about one half of this being the result of human activities. 70% of the Cu input and 80% of the Zn input are taken into the sediments. Mean residence times of Cu and Zn in the Sea are calculated to be ≈0.3 and 0.2 years, respectively. Since these values are relatively small compared to the mean residence time of the seawater (0.9 years), Cu and Zn supplied to the Sea are considered to be accumulated rapidly in the sediments.     

Rare Earth Element Enrichment in Late Archean Manganese Deposits from the Iron Ore Group,East India

The major, trace and rare earth element (REE) composition of Late Archean manganese, ferromanganese and iron ores from the Iron Ore Group (IOG) in Orissa, east India, was examined. Manganese deposits, occurring above the iron formations of the IOG, display massive, rhythmically laminated or botryoidal textures. The ores are composed primarily of iron and manganese, and are low in other major and trace elements such as SiO₂, Al₂O₃, P₂O₅ and Zr. The total REE concentration is as high as 975 ppm in manganese ores, whereas concentrations as high as 345 ppm and 211 ppm are found in ferromanganese and iron ores, respectively. Heavy REE (HREE) enrichments, negative Ce anomalies and positive Eu anomalies were observed in post‐Archean average shale (PAAS)‐normalized REE patterns of the IOG manganese and ferromanganese ores. The stratiform or stratabound shapes of ore bodies within the shale horizon, and REE geochemistry, suggest that the manganese and ferromanganese ores of the IOG were formed by iron and/or manganese precipitation from a submarine, hydrothermal solution under oxic conditions that occurred as a result of mixing with oxic seawater. While HREE concentrations in the Late Archean manganese and ferromanganese ores in the IOG are slightly less than those of the Phanerozoic ferromanganese ores in Japan, HREE resources in the IOG manganese deposits appear to be two orders of magnitude higher because of the large size of the deposits. Although a reliable, economic concentration technique for HREE from manganese and ferromanganese ores has not yet been developed, those ores could be an important future source of HREE.     

A quadratic element method for evaluating groundwater flow by the inversion of surface tilt with application to the Tono Area, Japan

By modifying a previous method with constant elements, we developed a quadratic element method for more accurately estimating groundwater flow by the inversion of tilt data. In this method: (1) a region of groundwater flow is divided into quadratic elements in which the change in groundwater volume per unit volume of rock (Δv) and the Skempton coefficient (B) vary in a quadratic manner with the coordinates, (2) the values of Δv are set to zero at the boundaries of the region of groundwater flow and (3) the sum of the squared second derivatives of Δv is adopted as a constraining condition that is weighted and added to the sum of the squared errors in tilt. First, analyses were performed for a flow model to determine the accuracy of this method for estimating groundwater flow and also to clarify the effect of the assumed size of a region of groundwater flow. These analyses showed that the quadratic element method proposed in this study gives a much better estimation of Δv than the constant element method and that a large region of groundwater flow should be assumed, rather than a small region, since the values of Δv at points outside of the actual region of groundwater flow are estimated to be nearly zero when a large region is assumed while these values are greatly overestimated when an excessively small region is assumed. Finally, the quadratic element method was applied to the site of the Mizunami Underground Research Laboratory in the Tono area, Japan. Inverse analyses were performed for tilt data measured by four tiltmeters with a resolution of 10⁻⁹ radians during the excavation of two shafts under the assumption that the rock mass is an isotropic and homogeneous half- space. The results showed that the method proposed in this study reproduced the tilt data very accurately. Thus, the distribution of Δv was estimated without sacrificing the reproducibility of the tilt data. The contour maps of B(1 + ν)Δv (ν: Poisson’s ratio) showed that the heterogeneous flow of groundwater occurred at the site and that groundwater volume decreased mainly in the area surrounded by two faults. The latter result is consistent with the finding obtained by previous investigations that these faults have low permeability in the direction perpendicular to the strike and may act as a flow barrier.     

Nickel–bearing Djerfisherite in Gehlenite-Spurrite Skarn at Kushiro, Hiroshima Prefecture, Japan

Abstract: Djerfisherite occurs intimately intergrown with troilite and pentlandite in gehlenite-spurrite skarn at Kushiro, mainly as inclusions in gehlenite and andradite grains. The mode of occurrence indicates that the djerfisherite formed in the culminated stage of the contact metamorphic-metasomatic process. The chemical compositions of the mineral are approximately represented by a formula of K₆Na(Fe, Ni, Cu)₂₄S₂₆Cl with Ni up to 4. 85. It is likely that high temperature condition corresponding to the formation of gehlenite-spurrite skarn as well as low f_O2 and f_S2 conditions are responsible for the formation of djerfisherite in the potassium-rich chemical environments.     

Experimental investigation on cohesionless sandy bank failure resulting from water level rising

In the last decade, sediment replenishment forming cohesionless sandy banks below dams has become an increasingly common practice in Japan to compensate for sediment deficits downstream. The erosion process of the placed cohesionless sediment is a combination of lateral toe-erosion and the following mass failure. To explore cohesionless bank failure mechanisms, a series of experiments was done in a soil tank using a compacted sandy soil mass exposed to an increasing water level. Two types of uniform sand(D_(50) = 0.40 mm and 0.17 mm) and two bank heights(50 cm and 25 cm) were used under the condition of a constant bank slope of 75°. The three dimensional(3D) geometry of the bank after failure was measured using a handheld 3D scanner. The motion of bank failure was captured using the particle image velocimetry(PIV) technique, and the matric suction was measured by tensiometers. The compacted sandy soil was eroded by loss of matric suction accompanying the rise in water level which subsequently caused rotational slide and cantilever toppling failure due to destabilization of the bank. The effect of erosion protection resulting from the slumped blocks after these failures is discussed in the light of different failure mechanisms. Tensile strength is analyzed by inverse calculation of cantilever toppling failure events. The tensile strength had non-linear relation with degree of saturation and showed a peak.The findings of the study show that it is important to incorporate the non-linear relation of tensile strength into stability analysis of cantilever toppling failure and prediction of tension crack depth within unsaturated cohesionless banks.     

Softening effects of RC nonstructural flat walls on ductile concrete buildings

Nonstructural reinforced concrete flat walls architecturally designed as exterior/partition walls in concrete buildings were severely damaged by the 2011 earthquake off the Pacific coast of Tohoku. This damage was observed in the monolithic nonstructural flat walls of relatively old ductile concrete buildings. Although these flat walls might affect the overall seismic performance and behavior of a building, the nonstructural wall effects have not been clarified because of the complex interactions among the structural components. To understand these effects, this paper conducts an experimental and numerical investigation of the nonstructural wall effects, focusing on a typical residential building damaged by the 2011 earthquake. A single‐story, one‐bay moment‐resisting frame model of the building with a nonstructural flat wall was tested to clarify the fundamental behavior. The results reveal that the wall significantly contributed to the seismic performance of the overall frame until it failed in shear, subsequently losing structural effectiveness. Such experimental wall behavior could be simulated by the isoparametric element model. Moreover, the structural effects of the nonstructural flat walls on the global seismic performance and behavior of the investigated building were discussed through earthquake response analyses using ground motions recorded near the building site and pushover analyses. Consequently, the building damage could be simulated in an analytical case considering the nonstructural flat walls, showing larger inter‐story drifts in the lower stories due to softening of the walls. The analytical results also indicated that the softening of the nonstructural flat walls decreased the building ductility, as defined by ultimate inter‐story drifts. Copyright © 2017 John Wiley & Sons, Ltd.