The effects of agricultural practice and land-use on the distribution and origin of some potentially toxic metals in the soils of Golestan province, Iran

Soil samples were collected from the agricultural lands of Golestan province, north of Iran and analyzed for 24 elements including eight toxic metals of As, Cd, Co, Cr, Cu, Pb, Se and Zn. Electrical conductivity, pH, organic matter, soil texture, calcium carbonate content as well as soil cation exchange capacity were also determined. The possible sources of metals are identified with multivariate analysis such as correlation analysis, principal component analysis (PCA), and cluster analysis. In addition, enrichment factors were used to quantitatively evaluate the influences of agricultural practice on metal loads to the surface soils. The PCA and cluster analysis studies revealed that natural geochemical background are the main source of most elements including Al, Co, Cr, Cs, Cu, Fe, K, Li, Ni, Pb, V and Zn in the arable soils of the province (more than 90 %), however, those soils which have been developed on the mafic and metamorphic rocks were considerably contributed on metal concentration (43 %). Calcium and Sr were constituents of calcareous rocks and Na and S were mainly controlled by saline soils in the north of the province. Loess deposits was also accounting for high levels of selenium concentration. Phosphorous was mostly related to application of P-fertilizers and organophosphate pesticides. The comparison of metal load and enrichment factor for dry and irrigated farmlands showed that Cd, Co, Pb, Se and Zn had higher concentrations in the irrigated lands where considerable amounts of agrochemicals had been applied. However, it also found that proximity of arable lands to urban and industrial areas resulted in higher Pb and Cd values in the irrigated agricultural sources relative to dry ones.     

A numerical study on the basin edge effect on soil amplification

In this paper a numerical study on the effects of the basin edge on the dynamic behavior of the model basins are investigated. For this purpose a range of bedrock inclinations at the valley sides from slighter $10^{\circ }$ and $20^{\circ }$ to steeper $30^{\circ }$ and $40^{\circ }$ are selected. A numerical study using nonlinear code which utilizes appropriate static and dynamic boundary conditions, and includes hysteresis damping formulation based on user defined degradation curves is conducted utilizing two sandy and clayey materials. Using several different real earthquake motions provide opportunity for the assessment of the site response to the variation of the motion intensity. The analyses results are presented in the form of the acceleration and spectral acceleration amplification curves. Also, by conducting 1D analyses along the valley the aggravation curve for every case are evaluated and discussed. It was seen that variation of the bedrock inclination not only affects the peaks of the spectral amplification curves, but also the position of the maximums of the curves on the valley surface are changed. Also, the frequency domain results show that different parts of the valleys are sensitive to different periods. While the lateral parts are sensitive to lower periods, the maximum amplification of the inner parts takes place at higher periods. Based on results the 2D behavior not only is dominant at the latreal parts of the valley, but also affects the behavior of the inner parts. Also, the use of the 1D analyes for the estimation of the 2D behavior remains insufficient. Finally, the results of this research show the important effect of the motion intensity on the 2D behavior of the valley specially on the increase of the resonance period at higher period.     

Application of Leeb Hardness Test in Prediction of Dynamic Elastic Constants of Sedimentary and Igneous Rocks

Geotechnical and Geological Engineering - The Leeb hardness test is a non-destructive and portable technique that can be used both in the laboratory and in-field applications. The main purpose of...     

Stacking Ensemble Machine Learning-Based Shear Strength Model for Rock Discontinuity

Geotechnical and Geological Engineering - Accurate estimation of shear strength (SS) of rock discontinuities is crucial in rock engineering applications such as slope stability. This study proposes...     

Etiology of Salinity and Water Origin,the Main Dilemma of Badab Sourt,a Unique Travertine Spring

Badab Sourt travertine‐depositing springs in the north of Iran, naturally create a unique surreal landscape containing a range of stepped travertine terraces, similarly found only in a few other places on earth. This site comprises of three travertine saline springs with different values of salinity and discharge (SP₁, SP₂, and SP₃) and one non‐travertine fresh karstic spring (SP₄) within a distance of about 300 m. The etiology behind this salinity and the water origin are the main research's dilemma that were investigated using geological, hydrochemical, and stable isotopic techniques. Based on the topography and isotopic results, the carbonate formations in northern (Khoshyeilagh and Mobarak) and southern (Cretaceous limestone) parts of the springs potentially provide the initial hydraulic gradient for deep circulation of the water and CO₂. However, geological studies indicate that the hydraulic connectivity of the Cretaceous formation to the travertine springs is interrupted by impermeable geological formations. Based on the proposed conceptual hydrogeological model and mass balance calculations, the SP₄ spring is locally recharged from the nearby karstic area of Khoshyeilagh formation through shallow, short and steep groundwater flow circulation that is completely different from the travertine springs. The travertine spring (SP₁) is recharged from more distant areas having higher altitudes on Mobarak and Khoshyeilagh limestone and circulate more deeply before emerging on the surface. The SP₂ and SP₃ springs can derive from the mixing of the saline water (SP₁) and fresh water (SP₄). The dissolution of interlayers of halite in Shemshak formation is concluded as the main source of salinity. This is the first research article in detail to survey hydrogeology of the travertine springs in Iran.     

Water quality variations in different climates of Iran: toward modeling total dissolved solid using soft computing techniques

In present paper, wavelet analysis of total dissolved solid that monitored at Nazlu Chay (northwest of Iran), Tajan (north of Iran), Zayandeh Rud (central of Iran) and Helleh (south of Iran) basins with various climatic conditions, have been studied. Daubechies wavelet at suitable level (db4) has been calculated for TDS of each selected basins. The performance of artificial neural networks (ANN), two different adaptive-neurofuzzy inference system (ANFIS) including ANFIS with grid partition (ANFIS-GP) and ANFIS with subtractive clustering (ANFIS-SC), gene expression programming (GEP), wavelet-ANN, wavelet-ANFIS and wavelet-GEP in predicting TDS of mentioned basins were assessed over a period of 20 years at twelve different hydrometric stations. EC (μmhos/cm), Na (meq L^?1) and Cl (meq L^?1) parameters were selected (based on Pearson correlation) as input variables to forecast amount of TDS in four studied basins. To develop hybrid wavelet-AI models, the original observed data series was decomposed into sub-time series using Daubechies wavelets at suitable level for each basin. Based on the statistical criteria of correlation coefficient (R), root mean square error (RMSE) and mean absolute error (MAE), the hybrid wavelet-AI models performance were better than single AI models in all basins. A comparison was made between these artificial intelligence approaches which emphasized the superiority of wavelet-GEP over the other intelligent models with amount of RMSE 18.978, 6.774, 9.639 and 318.363 mg/l, in Nazlu Chay, Tajan, Zayandeh Rud and Helleh basins, respectively.     

First Record of the Belemnite Genus Hibolithes from Late Jurassic–Early Cretaceous Turbidites from Malaysia

Discovery of the remains of belemnites referred to the Hibolithes sp. from the Jurassic–Cretaceous Pedawan Formation in Sarawak, on the island of Borneo(Malaysia) comprises four fragments of belemnite rostra. The specimens are characterized by multiple fractures and vein filling. Two fragments measuring about 130 mm are relatively intact, with only part of the alveolar region missing; a third piece represents the middle part of a rostrum, and the fourth specimen is too fragmentary to be assigned to any specific part of the rostrum. Based on specimen characteristics, a Tithonian–Hauterivian age is plausible. The sedimentary succession that yielded the belemnite material comprises thick shale that reflects the Te division of Bouma sequence. The occurrence of a Hibolithes taxon in the uppermost Jurassic to lowermost Cretaceous Pedawan Formation sediments in Borneo reflects a near to global palaeobiogeographic distribution of this genus.     

Report on the Diatoms and Dinoflagellates Distribution along the Algerian Coasts: Inter-Region Comparison

The phytoplankton group’s composition is an excellent indicator of the state of coastal waters. The aim of this study is to explore spatial variability of phytoplankton in shallow coastal areas from different regions (East, Center and West) of the Algerian coast. The quantitative and qualitative study of the phytoplankton population was conducted on samples taken during the 2012-2013 period by the research vessel GRINE BELKACEM. The qualitative results show a significant diversity of diatoms and dinoflagellates, which rank first and second in the total flora (Fr > 50%). This finding is also confirmed quantitatively by the abundance values in both 2013 and 2012 samples which largely exceeds the average value in most other areas of the western region (56%) and slightly exceeding 52% in all central areas which represent an equi-distribution between diatoms and dinoflagellates. The Dinoflagellates contribute significantly to the quantitative richness in the eastern region (>60%). The minimum value of Dia/Dino index, recorded in the eastern region confirms the dominance of the dinoflagellates especially in Skikda (0.31) (Skikda).However, our results reveal the presence, in smaller proportion, of other groups such as the cocolithophoridae and euglenophyceae.