湘赣地区龙潭煤系的成煤背景与煤层气

湘赣地区龙潭煤系是华南重要的含煤地层之一,煤层气资源丰富,是浅层煤层气开发利用的理想场所。本文分析了湘赣地区龙潭煤系的成煤古地理条件及大地构造环境,在此基础上讨论了龙潭煤系的原始生气能力、储集层及围岩的储气能力,并讨论了印支运动和燕山运动对煤层气富集、分布的影响      

Quaternary bimodal volcanism in the Niğde Volcanic Complex (Cappadocia,central Anatolia,Turkey): age,petrogenesis and geodynamic implications

The late Neogene to Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia is one of the most impressive volcanic fields of Turkey because of its extent and spectacular erosionally sculptured landscape. The late Neogene evolution of the CVP started with the eruption of extensive andesitic-dacitic lavas and ignimbrites with minor basaltic lavas. This stage was followed by Quaternary bimodal volcanism. Here, we present geochemical, isotopic (Sr–Nd–Pb and δ¹⁸O isotopes) and geochronological (U–Pb zircon and Ar–Ar amphibole and whole-rock ages) data for bimodal volcanic rocks of the Ni?de Volcanic Complex (NVC) in the western part of the CVP to determine mantle melting dynamics and magmatic processes within the overlying continental crust during the Quaternary. Geochronological data suggest that the bimodal volcanic activity in the study area occurred between ca. 1.1 and ca. 0.2 Ma (Pleistocene) and comprises (1) mafic lavas consisting of basalts, trachybasalts, basaltic andesites and scoria lapilli fallout deposits with mainly basaltic composition, (2) felsic lavas consisting of mostly rhyolites and pumice lapilli fall-out and surge deposits with dacitic to rhyolitic composition. The most mafic sample is basalt from a monogenetic cone, which is characterized by ⁸⁷Sr/⁸⁶Sr = 0.7038, ¹⁴³Nd/¹⁴⁴Nd = 0.5128, ²⁰⁶Pb/²⁰⁴Pb = 18.80, ²⁰⁷Pb/²⁰⁴Pb = 15.60 and ²⁰⁸Pb/²⁰⁴Pb = 38.68, suggesting a moderately depleted signature of the mantle source. Felsic volcanic rocks define a narrow range of ¹⁴³Nd/¹⁴⁴Nd isotope ratios (0.5126–0.5128) and are homogeneous in Pb isotope composition (²⁰⁶Pb/²⁰⁴Pb = 18.84–18.87, ²⁰⁷Pb/²⁰⁴Pb = 15.64–15.67 and ²⁰⁸Pb/²⁰⁴Pb = 38.93–38.99). ⁸⁷Sr/⁸⁶Sr isotopic compositions of mafic (0.7038–0.7053) and felsic (0.7040–0.7052) samples are similar, reflecting a common mantle source. The felsic rocks have relatively low zircon δ¹⁸O values (5.6 ± 0.6 ‰) overlapping mantle values (5.3 ± 0.3 %), consistent with an origin by fractional crystallization from a mafic melt with very minor continental crustal contamination. The geochronological and geochemical data suggest that mafic and felsic volcanic rocks of the NVC are genetically closely related to each other. Mafic rocks show a positive trend between ⁸⁷Sr/⁸⁶Sr and Th, suggesting simultaneous assimilation and fractional crystallization, whereas the felsic rocks are characterized by a flat or slightly negative variation. High ⁸⁷Sr/⁸⁶Sr gneisses are a potential crustal contaminant of the mafic magmas, but the comparatively low and invariant ⁸⁷Sr/⁸⁶Sr in the felsic volcanics suggests that these evolved dominantly by fractional crystallization. Mantle-derived basaltic melts, which experienced low degree of crustal assimilation, are proposed to be the parent melt of the felsic volcanics. Geochronological and geochemical results combined with regional geological and geophysical data suggest that bimodal volcanism of the NVC and the CVP, in general, developed in a post-collisional extensional tectonic regime that is caused by ascending asthenosphere, which played a key role during magma genesis.     

The 2014 seismic hazard model of the Middle East: overview and results

The Earthquake Model of Middle East (EMME) Project aimed to develop regional scale seismic hazard and risk models uniformly throughout a region extending from the Eastern Mediterranean in the west to the Himalayas in the east and from the Gulf of Oman in the south to the Greater Caucasus in the North; a region which has been continuously devastated by large earthquakes throughout the history. The 2014 Seismic Hazard Model of Middle East (EMME-SHM14) was developed with the contribution of several institutions from ten countries. The present paper summarizes the efforts towards building a homogeneous seismic hazard model of the region and highlights some of the main results of this model. An important aim of the project was to transparently communicate the data and methods used and to obtain reproducible results. By doing so, the use of the model and results will be accessible by a wide community, further support the mitigation of seismic risks in the region and facilitate future improvements to the seismic hazard model. To this end all data, results and methods used are made available through the web-portal of the European Facilities for Earthquake Hazard and Risk (www.efehr.org).     

Current velocity forecasting in straits with artificial neural networks,a case study: Strait of Istanbul

Owing to their complex character, modeling flow patterns of narrow straits has always been a challenge, even with the numerical techniques of today. This study was aimed at predicting vertical current profiles of a given point in a narrow strait, the Strait of Istanbul. On account of the speed and simplicity it offers, and of its remarkable success in solving complex problems, the feed forward back propagation (FFBP) artificial neural network (ANN) technique was chosen for this study. The model was built on 7039 hours of concurrent measurements of current profiles, meteorological conditions, and surface elevations. The model predicted 12 outputs of East and North velocity components at different depths in a given location. Various alternative models with different inputs and neuron numbers were evaluated attaining the best model by trial and error. Predictions from proposed ANN model were in accordance with the observations with average root mean square error of 0.16 m/s. The same input parameters were then used to build models that predicted current velocities 1–12 h into the future. Results of these predictions show good overall agreement with observations and that FFBP ANN can be used as a reliable tool for forecasting current profiles in straits.     

Petrogenesis of the Neogene volcanic units in the NE–SW-trending basins in western Anatolia,Turkey

The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline (HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly enriched in large ion lithophile elements (LILE), have high ⁸⁷Sr/⁸⁶Sr_(i) (0.70631–0.71001), low ¹⁴³Nd/¹⁴⁴Nd_(i) (0.512145–0.512488) and high Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb = 18.838–19.148; ²⁰⁷Pb/²⁰⁴Pb = 15.672–15.725; ²⁰⁸Pb/²⁰⁴Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization processes in the upper crust, such that have undergone a two-stage petrogenetic evolution.     

Effect of organic solvent type on the removal of nitrate ion using liquid membrane technique

In this study, the removal of nitrate ions from aqueous solutions with liquid membrane technique has been investigated for different organic solvent types in which solubilized tetradecyl trimethyl ammonium bromide (TDTMABr) as carrier. n-butyl alcohol, chloroform, and mixture of chloroform + n-hexane (n-hexane 85% + chloroform 15%) were used as organic solvent. Kinetic parameters (k _1d, k _2m, k _2a, t _max, R _m^max, J _m^max, J _a^max) were calculated from obtained data. time R _a values of mixture, butyl alcohol, and chloroform are 0.81, 0.78, and 0.55, respectively. Similarly R _d, R _m, and t _max values of the mixture equal to 0.14, 0.04, and 87.92 min, respectively. This behavior of the system shows the organic solvent type is an effective parameter on separation yield. It can be concluded that the mixture is the most effective organic solvent type among the investigated ones, because liquid membrane systems should be operated within the range of having the R _m, R _d, and t _max values are minimum while R _a values are maximum.