The extensive Changba-Lijiagou Pb-Zn deposit is located in the north of the Xihe–Chengxian ore cluster in West Qinling. The ore bodies are mainly hosted in the marble, dolomitic marble and biotite-calcite-quartz schist of the Middle Devonian Anjiacha Formation, and are structurally controlled by the fault and anticline. The ore-forming process can be divided into three main stages, based on field geological features and mineral assemblages. The mineral assemblages of hydrothermal stage I are pale-yellow coarse grain, low Fe sphalerite, pyrite with pits, barite and biotite. The mineral assemblages of hydrothermal stage II are black-brown cryptocrystalline, high Fe shalerite, pyrite without pits, marcasite or arsenopyrite replace the pyrite with pits, K-feldspar. The features of hydrothermal stage III are calcite-quartz-sulfide vein cutting the laminated, banded ore body. Forty-two sulfur isotope analyses, twenty-five lead isotope analyses and nineteen carbon and oxygen isotope analyses were determined on sphalerite, pyrite, galena and calcite. The δ34 S values of stage I(20.3 to 29.0‰) are consistent with the δ34 S of sulfate(barite) in the stratum. Combined with geological feature, inclusion characteristics and EPMA data, we propose that TSR has played a key role in the formation of the sulfides in stage I. The δ34 S values of stage II sphalerite and pyrite(15.1 to 23.0‰) are between sulfides in the host rock, magmatic sulfur and the sulfate(barite) in the stratum. This result suggests that multiple S reservoirs were the sources for S2-in stage II. The δ34 S values of stage III(13.1 to 22‰) combined with the structure of the geological and mineral features suggest a magmatic hydrothermal origin of the mineralization. The lead isotope compositions of the sulfides have 206 Pb/204 Pb ranging from 17.9480 to 17.9782, 207 Pb/204 Pb ranging from 15.611 to 15.622, and 208 Pb/204 Pb ranging from 38.1368 to 38.1691 in the three ore-forming stages. The narrow and symmetric distributions of the lead isotope values reflect homogenization of granite and mantle sources before the Pb-Zn mineralization. The δ13 CPDB and δ18 OSMOW values of stage I range from-0.1 to 2.4‰ and from 18.8 to 21.7‰. The values and inclusion data indicate that the source of fluids in stage I was the dissolution of marine carbonate. The δ13 CPDB and δ18 OSMOW values of stage II range from-4 to 1‰ and from 12.3 to 20.3‰, suggesting multiple C-O reservoirs in the Changba deposit and the addition of mantle-source fluid to the system. The values in stage III are-3.1‰ and 19.7‰, respectively. We infer that the process of mineralization involved evaporitic salt and sedimentary organic-bearing units interacting through thermochemical sulfate reduction through the isotopic, mineralogy and inclusion evidences. Subsequently, the geology feature, mineral assemblages, EPMA data and isotopic values support the conclusion that the ore-forming hydrothermal fluids were mixed with magmatic hydrothermal fluids and forming the massive dark sphalerite, then yielding the calcite-quartz-sulfide vein ore type at the last stage. The genesis of this ore deposit was epigenetic rather than the previously-proposed sedimentary-exhalative(SEDEX) type. 相似文献
The Tseng-wen River is a small mountainous river in southern Taiwan that has distinct dry and flood seasons. Several lines of evidence have revealed that the depositional system at the mouth of the river has transformed from a deltaic system to an estuarine system. The evidence includes long to short-term shoreline changes, geomorphology of the river mouth, mixed sediment sources inside the river mouth, mixing and suspended sediment characteristics inside the river mouth, and the grain-size distribution patterns on the river bed. Unlike the long-term evolution of many other coastal systems, the transformation at the Tseng-wen River mouth is largely caused by the building of a reservoir in the middle reaches of the river. The present study provides an example that coastal environments can be influenced by human activities farther inland on a time scale much faster than what would occur naturally. 相似文献
Erciyes stratovolcano, culminating at 3917 m, is located in the Cappadocian region of central Anatolia. During its evolution, this Quaternary volcano produced pyroclastic deposits and lava flows. The great majority of these products are calc-alkaline in character and they constitute Kocdag and Erciyes sequences by repeated activities. Alkaline activity is mainly observed in the first stages of Kocdag and approximately first-middle stages of Erciyes sequences. Generally, Kocdag and Erciyes stages terminate by pyroclastic activities. The composition of lavas ranges from basalt to rhyolite (48.4–70.5 wt.% SiO2). Calc-alkaline rocks are represented mostly by andesites and dacites. Some compositional differences between alkaline basaltic, basaltic and andesitic rocks were found; while the composition of dacites remain unchanged. All these volcanics are generally enriched in LIL and HFS elements relative to the orogenic values except Rb, Ba, Nb depleted alkaline basalt. 87Sr/86Sr and 143Nd/144Nd isotopic composition of the volcanics range between 0.703344–0.703964, 0.512920–0.512780 for alkaline basalts and change between 0.704322–0.705088, 0.512731–0.512630 for alkaline basaltic rocks whereas calc-alkaline rocks have relatively high Sr and Nd isotopic ratios (0.703434–0.705468, 0.512942–0.512600). Low Rb, Ba, Nb content with high Zr/Nb, low Ba/Nb, La/Yb ratio and low Sr isotopic composition suggest an depleted source component, while high Ba, Rb, Nb content with high La/Yb, Ba/Nb, low Zr/Nb and low 87Sr/86Sr ratios indicate an OIB-like mantle source for the generation of Erciyes alkaline magma. These elemental and ratio variations also indicate that the different mantle sources have undergone different degree of partial melting episodes. The depletion in Ba, Rb, Nb content may be explained by the removal of these elements from the source by slab-derived fluids which were released from pre-collisional subduction, modified the asthenospheric mantle. The chemically different mantle sources interacted with crustal materials to produce calc-alkaline magma. The Ba/Nb increase of calc-alkaline samples indicates the increasing input of crustal components to Erciyes volcanics. Sr and Nd isotopic compositions and elevated LIL and HFS element content imply that calc-alkaline magma may be derived from mixing of an OIB-like mantle melts with a subduction-modified asthenospheric mantle and involvement of crustal materials in intraplate environments. 相似文献
During the Early Tertiary epoch a basin of deposition covered almost all the present Himalayan foot hill zone. Large quantities of detrital sediments were transported from the northern source area to the depositional basin. The rivers carrying the sediment load formed large delta complexes. In the area studied at least two such delta complexes, one around Kalka and the other around Nahan, were formed; of these the one around Kalka contains the greatest volume of sediments.
The recognition of the deltas is based on: (a) greater abundance of stream deposits than deposits of other environments; (b) lithologic criteria, particularly sedimentary structures, repetitive lithologic associations; (c) the general coarsening-upward nature of the sediments; (d) strong unimodal current direction; (e) the typical lenticular lithogenetic model, common in recent deltas.
The rocks of the Nahan Group are divisible into three formations at Kalka and two formations at Nahan where central formation did not develop. Himalayan tectonism has largely controlled both delta formation and stratigraphy.
The differential rates of sedimentation greatly influenced the rates of subsidence within the Nahan basin. The sediments of the Nahan Group are roughly bounded between two major phases of Himalayan uplift, namely Eocene and middle Miocene tectonic movements. The effects of intermittent tectonic pulses are well depicted in rocks of the Nahan Group. The intensity of the tectonism that controlled both the source-area rise and basin subsidence during deposition of the Nahan Group of sediments was nonuniform, both in vertical and lateral directions. Because of a generally higher rate of deposition compared to the rate of subsidence, the rocks of the Nahan group represent a normal regressive basin-filling sedimentation, forming thick detrital deposits due to progradation of younger deltas beyond the distal end of older deltas. 相似文献
Total mercury was estimated in liver, gonads and muscle of some of the marine fishes from the Indian Ocean. The highest mercury concentration was observed in the muscle of sharks while the total mercury concentration was practically non-detectable in the liver and gonads. The range of all the values was 0.09–0.21 ppm (wet weight basis) and is quite low to reflect any possible mercury contamination. 相似文献