Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

强震地面运动的解析解

本文用具有非线性Ｒａｙｌｅｉｇｈ阻尼的断裂动力学的控制方程组或方程来研究水平强震地面运动或垂直强震地面运动，并得出其解析解，数值计算结果显示，本文得出的结果与任意选择的两个强震记录是很相似的。     

石墨炉原子吸收法测定地球化学样品中痕量银

本文采用石墨炉原子吸收光谱法测定地球化学样品中痕量银。选择硝酸镁和硫脲混合溶液为基体改进剂,银的灰化温度为800℃,研究了最佳的分析测定条件。该方法检出限为0．01μg／g。用该方法对国家地球化学标准样品的测定结果与标准值相符。     

Coupled assimilation for an intermediated coupled ENSO prediction model

The value of coupled assimilation is discussed using an intermediate coupled model in which the wind stress is the only atmospheric state which is slavery to model sea surface temperature (SST). In the coupled assimilation analysis, based on the coupled wind–ocean state covariance calculated from the coupled state ensemble, the ocean state is adjusted by assimilating wind data using the ensemble Kalman filter. As revealed by a series of assimilation experiments using simulated observations, the coupled assimilation of wind observations yields better results than the assimilation of SST observations. Specifically, the coupled assimilation of wind observations can help to improve the accuracy of the surface and subsurface currents because the correlation between the wind and ocean currents is stronger than that between SST and ocean currents in the equatorial Pacific. Thus, the coupled assimilation of wind data can decrease the initial condition errors in the surface/subsurface currents that can significantly contribute to SST forecast errors. The value of the coupled assimilation of wind observations is further demonstrated by comparing the prediction skills of three 12-year (1997–2008) hindcast experiments initialized by the ocean-only assimilation scheme that assimilates SST observations, the coupled assimilation scheme that assimilates wind observations, and a nudging scheme that nudges the observed wind stress data, respectively. The prediction skills of two assimilation schemes are significantly better than those of the nudging scheme. The prediction skills of assimilating wind observations are better than assimilating SST observations. Assimilating wind observations for the 2007/2008 La Niña event triggers better predictions, while assimilating SST observations fails to provide an early warning for that event.     

自适应双层网格的空间索引研究

空间数据索引是GIS系统中的关键技术,针对目前主流的网格空间索引方法进行了充分的研究比较,指出了网格索引方法对空间要素进行索引是高效的,但对于非规则地图它是不适应的.在此基础上设计了一种新的空间索引的方法,即自适应双层网格索引.详细地介绍了这种模型的实现过程,并且用实验充分论证了这个模型的效率,认为利用自适应双层网格索引检索空间数据时,处理、查询效率和占用空间等各方面具有较大优势.     

Quantifying the effects of climate variability and human activities on runoff from the Laohahe basin in northern China using three different methods

Much attention has recently been focused on the effects that climate variability and human activities have had on runoff. In this study, these effects are quantified using three methods, namely, multi‐regression, hydrologic sensitivity analysis, and hydrologic model simulation. A conceptual framework is defined to separate the effects. As an example, the change in annual runoff from the semiarid Laohahe basin (18 112 km²) in northern China was investigated. Non‐parametric Mann‐Kendall test, Pettitt test, and precipitation‐runoff double cumulative curve method were adopted to identify the trends and change‐points in the annual runoff from 1964 to 2008 by first dividing the long‐term runoff series into a natural period (1964–1979) and a human‐induced period (1980–2008). Then the three quantifying methods were calibrated and calculated, and they provided consistent estimates of the percentage change in mean annual runoff for the human‐induced period. In 1980–2008, human activities were the main factors that reduced runoff with contributions of 89–93%, while the reduction percentages due to changes in precipitation and potential evapotranspiration only ranged from 7 to 11%. For the various effects at different durations, human activities were the main reasons runoff decreased during the two drier periods of 1980–1989 and 2000–2008. Increased runoff during the wetter period of 1990–1999 is mainly attributed to climate variability. This study quantitatively separates the effects of climate variability and human activities on runoff, which can serve as a reference for regional water resources assessment and management. Copyright © 2011 John Wiley & Sons, Ltd.     

A new standardized Palmer drought index for hydro‐meteorological use

Accepting the concept of standardization introduced by the standardized precipitation index, similar methodologies have been developed to construct some other standardized drought indices such as the standardized precipitation evapotranspiration index (SPEI). In this study, the authors provided deep insight into the SPEI and recognized potential deficiencies/limitations in relating to the climatic water balance it used. By coupling another well‐known Palmer drought severity index (PDSI), we proposed a new standardized Palmer drought index (SPDI) through a moisture departure probabilistic approach, which allows multi‐scalar calculation for accurate temporal and spatial comparison of the hydro‐meteorological conditions of different locations. Using datasets of monthly precipitation, temperature and soil available water capacity, the moisture deficit/surplus was calculated at multiple temporal scales, and a couple of techniques were adopted to adjust corresponding time series to a generalized extreme value distribution out of several candidates. Results of the historical records (1900–2012) for diverse climates by multiple indices showed that the SPDI was highly consistent and correlated with the SPEI and self‐calibrated PDSI at most analysed time scales. Furthermore, a simple experiment of hypothetical temperature and/or precipitation change scenarios also verified the effectiveness of this newly derived SPDI in response to climate change impacts. Being more robust and preferable in spatial consistency and comparability as well as combining the simplicity of calculation with sufficient accounting of the physical nature of water supply and demand relating to droughts, the SPDI is promising to serve as a competent reference and an alternative for drought assessment and monitoring. Copyright © 2013 John Wiley & Sons, Ltd.     

TH-PPL CT防护铅罐屏蔽效果的模拟与研究

本文利用Geant 4模拟了FD3013数字γ辐射仪探测器探测晶体,对¹³⁷Cs(0.661MeV)的γ射线的探测效率,和TH-PPLCT教学仪防护铅罐对¹³⁷Cs源的防护效果,并建立了简易人体模型,仿真计算了人体吸收剂量,结果显示防护铅罐屏蔽后的辐射剂量在可接受的水平内。     

MVT铅-锌矿床的地球化学研究方法及其成矿系统探讨

本文总结MVT铅-锌矿床的最新地球化学研究方法及研究成果,包括δ18O、87Sr/86Sr、δ34S、206Pb/204Pb、Cl/Br、δ44Ca、同位素定年,以及利用地球化学参数所进行的数值模拟等。以这些方法的研究成果为依据,结合对白云石化作用和有机质在成矿系统中作用的分析,深入探讨了MVT铅-锌矿床的成矿系统,总结出一个与有机质密切相关的流体混合成矿假说。另外,强调了最新研究成果——金属硫化物和脉石矿物相异的流体包裹体成分,将在今后成矿系统的研究中发挥重要作用。