The Effect of Oxygen on Anaerobic Color Removal of Azo Dye in a Sequencing Batch Reactor

In this study, various amounts of oxygen were added to the anaerobic phase of an anaerobic‐aerobic sequencing batch reactor (SBR) receiving azo dye remazol brilliant violet 5R to mimic the input of oxygen into the anaerobic zones of biological textile wastewater treatment plants. The effect of oxygen on the anaerobic biodegradative capability of the mixed microbial culture for remazol brilliant violet 5R was investigated. To investigate the effect of oxygen on anaerobic azo dye biodegradation, the anaerobic phase of the SBR cultures were exposed to a very low limited amount of oxygen for various air flow rates. Initially, an air flow rate of 20 mL/min was applied, further on the air flow rate in the anaerobic phase was increased up to 40 mL/min. System performance was determined by monitoring chemical oxygen demand, color removal rate, activities of anaerobic (azo reductase) and aerobic enzymes (catechol 2,3‐dioxygenase, catechol 1,2‐dioxygenase). The results of percentage COD reduction at each stage were similar for all runs, giving an overall reduction of 96%. Anaerobic color removal efficiency and azo reductase activity of anaerobic microorganisms were adversely affected by the addition of oxygen. Color removal efficiencies of the anaerobic phases decreased from 80% down to 42 and 38% for the limited oxygen conditions of 20 mL/min and 40 mL/min, respectively. It was observed that the activity of catechol 2,3‐dioxygenase and catechol 1,2‐dioxygenase, involved in breakage of aromatic rings, increased after they are exposed to oxygen limited conditions compared to fully anaerobic conditions. It was also observed that catechol 1,2‐dioxygenase enzyme activity increased by increasing the oxygen level on oxygen limited conditions in the anaerobic zone.     

Use of Pistachio Shells as an Adsorbent for the Removal of Zinc(II) Ion

In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is examined on the effects of pH, adsorbent dosage, and contact time. The adsorption rates are determined quantitatively and simulated by the Lagergren first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetic models. The adsorption kinetic models are also tested for validity. The thermodynamic parameters, which are also deduced from adsorption experiments, are very useful in elucidating the nature of adsorption. The experimental results reveal that the optimum pH value and the contact time for the adsorption of Zn²⁺ onto PS are found as 6 and 10 min, respectively. According to these parameters, adsorption process follows the pseudo‐second order kinetic model with high correlation coefficients (R² = 0.999). The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn²⁺ from aqueous leachate of hazardous waste.     

The relevance of flood hazards and impacts in Turkey: What can be learned from different disaster loss databases?

Turkey has been severely affected by many natural hazards, in particular earthquakes and floods. Especially over the last two decades, these natural hazards have caused enormous human and economic damage. Although there is a large body of literature on earthquake hazards and risks in Turkey, comparatively little is known about flood hazards and risks. Therefore, this study aims to investigate the severity of flooding in comparison with other natural hazards in Turkey and to analyse the flood patterns by providing an overview of the temporal and spatial distribution of flood losses. These will act as a metric for the societal and economic impacts of flood hazards in Turkey. For this purpose, Turkey Disaster Database (TABB) was used for the years 1960–2014. As input for more detailed event analyses, the most severe flood events in Turkey for the same time interval will also be retrieved. Sufficiency of the TABB database to achieve the main aim of the study in terms of data quality and accuracy was also discussed. The TABB database was analysed and reviewed through comparison, mainly with the Emergency Events Database (EM-DAT), the Global Active Archive of Large Flood Events—Dartmouth Flood Observatory database, news archives and the scientific literature, with a focus on listing the most severe flood event. The comparative review of these data sources reveals big mismatches in the flood data, i.e. the reported number of events, number of affected people and economic loss all differ dramatically. Owing to the fact that the TABB is the only disaster loss database for Turkey, it is important to explore the reasons for the mismatches between TABB and the other sources with regard to aspects of accuracy and data quality. Therefore, biases and fallacies in the TABB loss data are also discussed. The comparative TABB database analyses show that large mismatches between global and national databases can occur. Current global and national databases for monitoring losses from national hazards suffer from a number of limitations, which in turn could lead to misinterpretations of the loss data. Since loss data collection is gaining more and more attention, e.g. in the Sendai Framework for Disaster Risk Reduction 2015–2030, this study offers a framework for developing guidelines for the Turkey Disaster Database (TABB), implications on how to standardize national loss databases and implement across the other hazard events in Turkey.     

Investigation of the Possibility of Copper Removal from Industrial Leachate by Raw and Calcined Phosphogypsum: D‐Optimal and Taguchi Designs

In the present study, the removal of Cu(II) was evaluated by raw and calcined phosphogypsum (PG) as an industrial product. The role of experimental factors on the removal of Cu(II) was examined by using D‐optimal and Taguchi designs. The experimental factors and their related levels were selected as initial pH of 3–6–8, adsorbent content of 5, 10, and 25 g L^?1, contact time of 5, 10, and 20 min, and temperature of 20, 40, and 60°C. The results are evaluated by ANOVA test to extract important experimental factors and their levels. The performances of the suggested factorial designs were then compared and regression models that took into account the significant main and interaction effects were suggested. Taguchi design was found as a reliable solution with less number of experiments for adsorption studies with the optimized values. The resultant removal efficiency is calculated as 78.34%. The results revealed that calcined PG is an appropriate adsorbent for Cu(II) removal from leachate of industrial waste.     

The effects of elevated-CO2 on physiological performance of Bryopsis plumosa

An increase in the level of atmospheric carbon dioxide (CO2) and the resultant rise in CO2 in seawater alter the inorganic carbon concentrations of seawater. This change, known as ocean acidification, ...