273.15K下LiCl-Li2B4O7-H2O体系热力学性质的等压研究

用等压法研究了273 15K下LiCl-Li2B4O7-H2O体系中纯盐水溶液(离子强度范围为LiCl0 2046～2 5055mol·kg-1,Li2B4O70 1295～0 3700mol·kg-1)以及混合盐水溶液(离子强度范围为0 0931～2 4911mol·kg-1)渗透系数和水活度;计算了LiCl-Li2B4O7-H2O体系的饱和蒸汽压,获得饱和蒸汽压、渗透系数随离子强度的变化规律。用实验数据以最小二乘法求取了LiCl和Li2B4O7纯盐参数及体系的混合盐参数,拟合的标准偏差分别为0 0077和0 026。用该模型计算的渗透系数值与实验结果取得合理的一致。同时研究结果与273 15K下LiCl-Li2SO4-H2O体系的渗透系数随离子强度变化的规律作了比较。本研究对完善低温下含锂、硼盐湖卤水体系的热力学模型和盐湖资源的综合开发利用具有重要意义。     

网络大数据下的中国现代食甜习惯空间分布特征及其影响因素研究

饮食地理文化作为地域文化中最具地方特色的重要元素,在现代人口大规模流动背景下呈现出全新的多样化局面,而基于传统认知的“南甜北咸”的地域分异已然不能代表中国现代食甜分布的空间特征。因此,本文采用网络爬虫技术,获取我国大陆31个省会城市共计约2000万条美食消费数据,从传统类菜品、主食类菜品、饮料类和甜品类菜品4个方面计算城市食甜度,在ArcGIS、MySQL软件支持下,借助GIS空间分析和数理统计方法探究我国现代食甜习惯的空间分布特征,分析影响食甜分布的因素。研究发现：① 中国食甜在空间分布上存在显著的地域分异特征,聚类分析评价参数R ²高达0.88,现代食甜习惯总体呈现“东高北中,西微内低”的包围式格局;② 从整体抑或局部角度,在1%显著性水平上莫兰指数均为正,中国食甜分布呈现显著的空间正相关关系,形成特色鲜明的3个地理集聚区,即以苏浙沪闽为主的东南沿海高甜集聚区,以渝黔川为主的西南内陆低甜集聚区和以陕宁为主的西北内陆低甜集聚区;③ 构建了中国现代食甜习惯分布影响因素模型,其拟合精度为0.82,分析结果显示降水、湿度、气温等气象要素及地理位置是影响现代我国食甜空间分布的重要因素。     

Submarine groundwater discharge revealed by aerial thermal infrared imagery: a case study on Jeju Island,Korea

Submarine groundwater discharge (SGD) is a global phenomenon that carries large volumes of groundwater and dissolved chemical species such as nutrient, metals, and organic compounds to coastal zones. We report the influence of SGD on the coastal waters of Jeju Island, Korea, using high‐resolution aerial thermal infrared (TIR) mapping techniques and field investigations. An aircraft‐based system was implemented using a cost‐effective TIR camera for aerial TIR mapping. Ground‐based calibrations and system integration with GPS/IMU (global positioning system/inertial measurement unit) were performed for the aerial systems. The aerial surveys showed distinct low‐temperature signatures of SGD along the coasts of Jeju Island, revealing large groundwater inputs from the coastal aquifers to the ocean. Multiple aerial surveys over a range of seasons and tidal stages revealed that SGD rates dynamically affect the sea surface temperature (SST) of the coastal zone. The in‐situ measurements supported that SGD has a substantial influence on the coastal water chemistry as well as SST. Our observations highlight the extent to which aerial‐based TIR mapping can serve as a powerful tool for studying SGD and other coastal processes. Copyright © 2016 John Wiley & Sons, Ltd.     

A two‐dimensional coupled hydromechanical discontinuum model for simulating rock hydraulic fracturing

Within the framework of our discontinuous deformation analysis for rock failure algorithm, this paper presents a two‐dimensional coupled hydromechanical discontinuum model for simulating the rock hydraulic fracturing process. In the proposed approach, based on the generated joint network, the calculation of fluid mechanics is performed first to obtain the seepage pressure near the tips of existing cracks, and then the fluid pressure is treated as linearly distributed loads on corresponding block boundaries. The contribution of the hydraulic pressure to the initiation/propagation of the cracks is considered by adding the components of these blocks into the force matrix of the global equilibrium equation. Finally, failure criteria are applied at the crack tips to determine the occurrence of cracking events. Several verification examples are simulated, and the results show that this newly proposed numerical model can simulate the hydraulic fracturing process correctly and effectively. Although the numerical and experimental verifications focus on one unique preexisting crack, because of the capability of discontinuous deformation analysis in simulating block‐like structures, the proposed approach is capable of modeling rock hydraulic fracturing processes. Copyright © 2014 John Wiley & Sons, Ltd.     

In‐situ analysis of trace elements and Sr–Pb isotopes of K‐feldspars from Tongshankou Cu–Mo deposit,SE Hubei Province,China: Insights into early potassic alteration of the porphyry mineralization system

In the Tongshankou porphyry deposit (SE Hubei Province, South China), three types of K‐feldspars are recognized: (I) the phenocryst type in the porphyry that crystalized during the magmatic stage, (II) the megacryst type and (III) the vein type in the altered porphyry and orebody that was produced by hydrothermal fluids. A detailed in‐situ analysis of trace elements and Sr–Pb isotopes was carried out on K‐feldspars in an attempt to unravel their formation processes and to trace the element sources during potassic alteration. The Type III K‐feldspars show lower Sr contents and Sr‐isotope ratios but higher Pb contents and Pb‐isotope ratios than the Type I and II K‐feldspars, possibly reflecting a contribution from the country carbonate rocks with less radiogenic Sr but more radiogenic Pb sources, and indicate that the ore‐forming fluids and materials may have been partially derived from external sources such as the host sedimentary rocks during the early potassic alteration stage.     

Multiple overpressure systems and their relationship with hydrocarbon accumulation in the Qikou Depression of the Bohai Bay Basin,China

Pressure measurements using drill stem tests and estimates from log data calculation indicate that three vertically stacked regional pressure compartments exist in the Qikou Depression of Bohai Bay Basin, N. China. The compartments comprise hydrostatic, upper weak, and lower overpressure systems. Laterally, overpressure (pressure coefficient > 1.2) occurs in the deeper areas and weakens gradually from the centre to the margin of the depression. The accumulation of oil and gas exhibits the interesting characteristics of oil‐bearing layers above gas‐bearing layers in the Qikou Depression. The pattern can be accounted for by the evolution of overpressure system, the maturity process of the source rock and the main fault activity. In the late Dongying Formation (Ed, 30 Ma), the lower overpressure system began to form shape, and the hydrocarbon sources generated a large volume of oil. However, because there was no migration pathway, the oil only accumulated in the original strata. In the late Guantao Formation (Ng, 12 Ma), the gas was generated, the upper overpressure system formed gradually, and the activity of the main fault gradually increased. Then, the overpressure pushed the early gathered oil to flow from the lower overpressure system into the upper overpressure system. Afterwards, the activity of the main fault decreased again and remains weak until now. Thus, later generated natural gas cannot keep migrating along the main fault and can only accumulate in the lower overpressure system. Copyright © 2014 John Wiley & Sons, Ltd.     

Satellite evidence for no change in terrestrial latent heat flux in the Three-River Headwaters region of China over the past three decades

Terrestrial latent heat flux (LE) in the Three-River Headwaters region (TRHR) of China plays an essential role in quantifying the amount of water evaporation and carbon sink over the high altitude Tibetan Plateau (TP). Global warming is expected to accelerate terrestrial hydrological cycle and to increase evaporation. However, direct field observations are lacking in this region and the long-term variability in LE remains uncertain. In this study, we have revised a semi-empirical Penman LE algorithm based on ground eddy covariance (EC) observations from an alpine grass site and provided new satellite-based evidence to assess LE change in the TRHR during 1982–2010. Our results show that the average annual terrestrial LE in the TRHR is about 38.8 W/m ² and there is no statistically significant change in annual LE from 1982 to 2010. We also found that during the same time period, terrestrial LE over the east region of the TRHR significantly decreased, on average, by 0.7 W/m ² per decade, which was driven primarily by the surface incident solar radiation (R_s) limitation, offsetting the increased LE over the west region of the TRHR caused by the increased precipitation (P) and soil moisture (SM).     

博格达山东段苏吉山辉长岩LA-ICP-MS锆石U-Pb年龄、地质地球化学特征及构造意义

苏吉山辉长岩体位于博格达碰撞造山带东段,卡拉麦里蛇绿混杂岩带西南侧,出露面积约1.8 km~2,岩性为石英角闪辉长岩。苏吉山辉长岩体富含普通角闪石(20%)和磁铁矿物,表明原生岩浆富水、高氧逸度特征,岩石化学组成属于拉斑玄武岩系列,岩石弱富集大离子亲石元素Cs、Rb、Ba、Th、U,显著亏损Nb、Ta、Zr、Hf和弱亏损Ti,显示源区为受俯冲流体交代改造的岩石圈地幔,应是洋壳俯冲的产物。苏吉山辉长岩体锆石U-Pb年龄为308.1±3.3Ma,早于卡拉麦里混杂岩带内碱性花岗岩侵位,介于博格达裂谷活动期,是裂谷作用由全面伸展向局限伸展转换的标志。苏吉山辉长岩空间上位于古亚洲洋板块沿卡拉麦里蛇绿混杂岩带向准噶尔板块斜向俯冲的前进方向,时间上介于博格达裂谷活动期,地球化学上显示洋壳俯冲的特征,各种事实表明,古亚洲洋沿卡拉麦里碰撞带向准噶尔板块斜向俯冲作用形成撕裂型博格达裂谷,博格达裂谷由伸展机制向伸展-碰撞过渡机制的应力调整导致了苏吉山辉长岩体的侵位。     

近年我国十大重要金属矿种找矿重大进展与成果

近年我国重要矿产资源勘查成果不断快速涌现。为服务矿产勘查进展长期动态跟踪与成果集成研究,2010~2014年,笔者依托原中国地质调查局发展研究中心承担的《重点成矿区带矿产勘查跟踪与成果集成》、《全国地质勘查进展分析》等项目,以铁、铜、铝、铅锌、金、钨、锡、钼、镍、锰等十大重要金属矿产勘查进展为主要研究对象,研究分析了勘查成果特征。