Parameterization of the Absorption of the H2O Continuum, CO2, O2, and Other Trace Gases in the Fu-Liou Solar Radiation Program

The absorption properties of the water vapor continuum and a number of weak bands for H2O, O2, CO2, CO, N2O, CH4, and O3 in the solar spectrum are incorporated into the Fu-Liou radiation parameterization program by using the correlated k-distribution method (CKD) for the sorting of absorption lines. The overlap absorption of the H2O lines and the H2O continuum (2500-14500 cm^-1) are treated by taking the two gases as a single-mixture gas in transmittance calculations. Furthermore, in order to optimize the computation efforts, CO2 and CH4 in the spectral region 2850-5250 cm^-1 are taken as a new singlemixture gas as well. For overlap involving other absorption lines in the Fu-Liou spectral bands, the authors adopt the multiplication rule for transmittance computations under which the absorption spectra for two gases are assumed to be uncorrelated. Compared to the line-by-line (LBL) computation, it is shown that the errors in fluxes introduced by these two approaches within the context of the CKD method are small and less than 0.48% for the H20 line and continuum in the 2500-14500 cm^-1 solar spectral region, -1% for H2O (line) H2O (continuum) CO2 CH4 in the spectral region 2850-5250 cm^-1, and -1.5% for H2O (line) H2O (continuum) O2 in the 7700-14500 cm^-1 spectral region. Analysis also demonstrates that the multiplication rule over a spectral interval as wide as 6800 cm^-1 can produce acceptable errors with a maximum percentage value of about 2% in reference to the LBL calculation. Addition of the preceding gases increases the absorption of solar radiation under all sky conditions. For clear sky, the increase in instantaneous solar absorption is about 9%-13% (-12 W m^-2) among which the H20 continuum produces the largest increase, while the contributions from O2 and CO2 rank second and third, respectively. In cloudy sky, the addition of absorption amounts to about 6-9 W m^-2. The new, improved program with the incorporation of the preceding gases produces a smaller solar absorption in clouds due to the reduced solar flux reaching the cloud top.     

Neotethyan Evolution of the Ankara Mélange,Turkey: An Intraoceanic Subduction-Accretion System

<正>We report here new geochemical and geochronological data from mafic-ultramafic rock suites in the Ankara Mélange in north-central Turkey,and present a new tectonic model for its origin.Considered as one of most important relics of the Neotethyan realm in the region,the Ankara Mélange occurs between the Sakarya Continent     

Retrieval of the single scattering albedo of Asian dust mixed with pollutants using lidar observations

The vertical distribution of single scattering albedos （SSAs） of Asian dust mixed with pollutants was derived using the multi-wavelength Raman lidar observation system at Gwangju （35.10°N,126.53°E）.Vertical profiles of both backscatter and extinction coefficients for dust and non-dust aerosols were extracted from a mixed Asian dust plume using the depolarization ratio from lidar observations.Vertical profiles of backscatter and extinction coefficients of non-dust particles were input into an inversion algorithm to retrieve the SSAs of non-dust aerosols.Atmospheric aerosol layers at different heights had different light-absorbing characteristics.The SSAs of non-dust particles at each height varied with aerosol type,which was either urban/industrial pollutants from China transported over long distances at high altitude,or regional/local pollutants from the Korean peninsula.Taking advantage of independent profiles of SSAs of non-dust particles,vertical profiles of SSAs of Asian dust mixed with pollutants were estimated for the first time,with a new approach suggested in this study using an empirical determination of the SSA of pure dust.The SSAs of the Asian dust-pollutants mixture within the planetary boundary layer （PBL） were in the range 0.88-0.91,while the values above the PBL were in the range 0.76-0.87,with a very low mean value of 0.76 ± 0.05.The total mixed dust plume SSAs in each aerosol layer were integrated over height for comparison with results from the Aerosol Robotics Network （AERONET） measurements.Values of SSA retrieved from lidar observations of 0.92 ± 0.01 were in good agreement with the results from AERONET measurements.     

Accumulation features of trace elements in mass-stranded harbor seals (Phoca vitulina) in the North Sea coast in 2002: the body distribution and association with growth and nutrition status

Body distribution and growth- and nutritional status-dependent accumulation of 21 trace elements were investigated in harbor seals (Phoca vitulina) stranded in the North Sea coast in 2002. Higher concentrations and burdens of Mn, Se, Mo, Ag, Sn, Hg, and Bi in the liver, Cd in the kidney, As in the blubber, and Co, Sr, and Ba in the bone were observed. Significant positive correlations of hepatic Se, Mo, Ag, Cd, Sn, Hg, Tl, and Bi with standard body length were found, while significant negative relationships were detected for Mn, As, Rb, Sr, and Sb in the liver. Concentrations of Co, Se, Sr, Sn, Hg, and Bi in the liver, V, Sr, Ag, Sn, and Hg in the kidney, V, Mn, Co, Rb, Sr, Sn, Ba, and Pb in the blubber increased with decreasing blubber thickness of harbor seals, indicating enrichment of these elements in the target tissue by emaciation.     

Anthropogenic organic contaminants in water, sediments and benthic organisms of the mangrove-fringed Segara Anakan Lagoon, Java, Indonesia

Segara Anakan, a mangrove-fringed coastal lagoon in Indonesia, has a high diversity of macrobenthic invertebrates and is increasingly affected by human activities. We found >50 organic contaminants in water, sediment and macrobenthic invertebrates from the lagoon most of which were polycyclic aromatic compounds (PACs). Composition of PACs pointed to petrogenic contamination in the eastern lagoon. PACs mainly consisted of alkylated PAHs, which are more abundant in crude oil than parent PAHs. Highest total PAC concentration in sediment was above reported toxicity thresholds for aquatic invertebrates. Other identified compounds derived from municipal sewage and also included novel contaminants like triphenylphosphine oxide. Numbers of stored contaminants varied between species which is probably related to differences in microhabitat and feeding mode. Most contaminants were detected in Telescopium telescopium and Polymesoda erosa. Our findings suggest that more attention should be paid to the risk potential of alkylated PAHs, which has hardly been addressed previously.     

地面运动的平均周期对单自由度和多自由度体系的非弹性动力反应的影响

主要研究地面运动的频率成分在非弹性需求下对单自由度（SDF）和多自由度（MDF）钢架结构的作用。通过对文献进行详细的审查,识别出最能代表地面运动频率成分的指标。选择地面运动的平均周期（Tm）是由于它能区别各种不同地面运动的频谱形态及其与震级、距离和场地特征的关系。首先使用一组128次地面运动的记录根据L对单自由度体系在特定延性水平时的非弹性位移要求进行研究。然后通过采用相同的地面运动资料做增量动力分析,把研究扩展到多自由度系统,评价Tm对各种工程需求参数的影响。得到的结果表明,对于单自由度体系,当弹性周期（Te）与Tm的比值低于1时,位移将增大。对于多自由度体系,结果证明了高阶振型对于基底剪力的影响和当Tm接近结构的高阶振型周期时,对最大层间侧移的影响变得更加显著。对单自由度体系和多自由度体系,在非弹性水平较高时这些观测更为明显。研究结果对于欧洲抗震设计法是尤为重要的。     

Occurrence of endocrine-disrupting chemicals in riverine sediments from the Pearl River Delta, China

The endocrine-disrupting chemicals (EDCs) was investigated in 28 riverine sediments from the Pearl River system, China and analyzed by an ultrasonication extraction and GC-MS method. The concentrations of 4-tert-octylphenol (OP), 4-nonylphenol (NP), and bisphenol A (BPA) in the sediments were in the ranges of <2.0-210, 107-16198 and <1.7-430 ng/g dw, respectively. The steroid estrogens estrone (E1) and 17β-estradiol (E2) in the sediments ranged from <1.3 to 10.9 ng/gdw and from <0.9 to 2.6 ng/gdw, respectively. The spatial distribution of these chemicals was related to the discharge of domestic and industrial wastewater along the rivers. The positive correlation between EDCs and total organic carbon indicates that sedimentary organic carbon is an important factor in controlling the distributions of EDCs. Compared with other previous studies, the ZR and DR rivers from the PRD were heavily contaminated by APs and BPA.     

Chemical characterization of naturally weathered oil residues in the sediment from Yellow River Delta, China

With its close proximity to Shengli Oilfield, China’s second largest oilfield, the Yellow River Delta is at high risk for crude oil contamination. The massive oil discharge in oilfield may offer a chance for a natural experiment to investigate compositional changes of oil residues and study the stability of source- and weathering-dependent molecular parameters in oil residues after spills. The results demonstrate that the conventional diagnostic ratios, such as C₂₉20S/(20S + 20R), C₂₉/C₃₀H, C₃₀βα/αβ, C₃₁22S/(22S + 22R), C₂-DBTs/C₂-PHENs, C₃-DBTs/C₃-PHENs, DBT/MCHRY, CHRY/PHENs, are also valid for oil source identification even after extensive weathering of spilled oils in terrestrial environment, although some exceptions were encountered for extensively weathered sample. Moreover, the ratios of selected specific biomarkers (the oleanane index, the gammacerane index) have been developed and assessed as source indicators. Finally, we find that some maturity parameters based on alkyl naphthalenes and methyl phenanthrenes in petroleum geochemistry, such as the methylnaphthalene ratios (TMNr, TeMNr, PMNr), the methylphenanthrene ratios (MPI-1, MPDF), can be applied for the source identification and correlation at their lightly to moderately weathered stage.