模糊综合评价-聚类复合模型在地下水质评价与分区中的应用

模糊综合评价法的评价结果具有模糊性，简单依据最大隶属度原则确定评价结果存在不足，笔者提出了模糊综合评价与模糊聚类分析相结合进行地下水质评价与分区的复合模型，并以MATLAB为平台开发了模型计算的常用函数。尝试将模型应用于抚州市地下水环境质量评价与分区，取得良好结果。     

内蒙古西部生态环境综合评价研究

内蒙古西部生态环境比较恶劣，影响生态环境的因子很多，从土地利用方式、环境现状和人类活动排泄物等3个方面出发，选取了对环境影响最重要的17个主导因子，采用综合指数法和灰色关联系数法，以旗县为评价单元进行生态环境综合评价。评价结果显示，内蒙古西部生态环境质量指数在—28．35～2．67之间。根据评价结果将内蒙古西部各旗县的生态环境质量分为4级，其中一级占15.4％，二级占36．5％，三级占34．6％，四级占13.5％。结果表明以牧业为主的旗县生态环境相对良好，旱作农业和灌涸农业次之，城市市区的环境质量最差。     

大别山东部花岗片麻岩的锆石U-Pb年龄

花岗片麻岩是大别山区除超高压变质杂岩外的另一种重要岩石类型,本文测得南大别二长花岗片麻岩中单颗粒锆石U-Pb不一致线的上交点年龄为789±43 Ma.位于五河一水吼韧性剪切带南缘的糜棱岩化二长花岗片麻岩中锆石的²⁰⁷Pb/²⁰⁶Pb表面年龄接近一致年龄,为715～777 Ma,平均757 Ma,U-Pb不一致线的上交点年龄为815±70 Ma,下交点年龄为482±167 Ma.北大别石英二长片麻岩中锆石²⁰⁷Pb/206表面年龄的变化范围较广,介于594～700 Ma,平均为649 Ma,U-Pb不一致线的上、下交点年龄分别为814±97 Ma和477±77 Ma.这说明这些正片麻岩的侵位时间范围大致为750～850 Ma的晚元古代;南、北大别正片麻岩中的锆石年代学显示它们可能具有相似的形成与演化历史;约480 Ma前后的加里东运动对大别山地区可能也有影响.     

黄土中蜗牛壳Mn^2＋的EPR研究及其古气候意义

对黄土高原陕西省洛川和甘肃省西峰剖面中黄土－古土壤层中的蜗牛壳进行了EPR波谱分析，同时对洛川地区的现代蜗牛壳也进行了测定。结果显示：（1）不同种类的蜗牛壳具有相近的EPR信号强度，表明不同种类的蜗牛对Mn^2+的吸收没有差异性。（2）黄土层中蜗牛壳的EPR信号强度远大于占土壤中的，即黄土中蜗牛壳所含的Mn^2+远大于古土壤中的蜗牛壳的Mn^2+的含量，说明前者生活在比较还原的条件下，后者形成环境的氧化性较高。因此本认为为蜗牛壳中Mn^2+的含量可反映其生长环境中Mn^2+的含量和氧化还原条件，对古气候的重建具有重要意义。     

大别山碧溪岭榴辉岩的K-Ca同位素定年:多硅白云母含过剩氩的新证据

40K可以进行分支衰变成40 Ar和40 Ca。在正常情况下 ,这对40 K 40 Ar或3 9Ar 40 Ar年龄与40 K 40 Ca年龄在误差范围内应该一致。测定了国家钾标样的含量、国家钾长石 (W 0 3116 )和球团矿 (W 72 0 0 )的钾钙含量、国内K Ar法标准矿物黑云母 (ZBH 2 5 )和角闪石 (ZBJ)的钾钙含量以及Tachiti标样的 (40 Ca/42 Ca)比值和含量 ,结果实测值与标称值在误差范围内一致。对大别山碧溪岭超高压变质榴辉岩的多硅白云母、绿辉石和石榴子石进行了 (40 Ca/42 Ca)和 (40 K/42 Ca)的测定。由15组数据构成的等时线斜率S =0 .12 0 8± 0 .0 4 2 3,相应的K Ca年龄为 2 2 8± 75Ma。然而多硅白云母和绿辉石的3 9Ar 40 Ar等时线年龄分别为 80 7.1± 32 .6Ma和 4 5 6 .7± 2 7.2Ma ,在误差范围内明显地高于40 K 40 Ca等时线年龄 ,这给出了前者存在过剩氩的直接证椐。此外 ,K Ca等时线的初始值 (40 Ca/42 Ca) i 为 15 1.4 2 4± 0 .0 13,相应的 ξCa为 +2 7。由于地幔岩的 ξCa≈ 0 ,所以前者表明榴辉岩的原岩具有典型的大陆地壳性质 ,这为大别山超高压变质岩体是由大陆物质俯冲至上地幔的深度 ,然后折返至大陆的形成过程提出了又一个判据     

弹性波逆时偏移及其成像条件

从弹性波动方程出发,推导了二维各向同性介质情况下弹性波逆时传播的高阶差分格式,实现了弹性波在数值空间中的逆时延拓。从程函方程出发,采用逆时差分格式求取网格空间中各点的直达波旅行时,以此作为弹性波逆时偏移的成像条件(激发时间成像条件),实现多波多分量资料的逆时偏移。文中给出了几个典型模型的理论记录的偏移结果,数值试验表明,逆时偏移能够使地表接收到的波场准确归位,提高资料处理的精度。     

敖包山铅锌矿区地质特征及找矿方向探讨

敖包山铅锌矿区位于华北陆块北缘 ,少郎河多金属成矿带的东段 ,已发现有敖包山、大孤山、双山子等三处矿床。敖包山矿床矿脉呈对称状分布于敖包山倒转背斜两翼 ,志留系下统水泉沟组为主要含矿地层 ,矿脉均受石英绿片岩、绿片岩控制。为“沉积 -变质 -热 (气 )液改造型”矿床。矿床向 NE方向应有相当长度的延伸 ,矿区进一步找矿方向应是 D3极化率异常区     

In situ trace metal speciation in a eutrophic lake using the technique of diffusion gradients in thin films (DGT)

We evaluated the application of DGT (diffusion gradients in thin films) as a tool to determine Cu, Zn, Ni, Cd, Pb and Mn concentrations and speciation in a hardwater eutrophic lake. This technique was used in situ during six sampling periods over one year in Lake Greifen. The DGT-labile species of Cu and Ni amounted to 15-25% of the total dissolved concentrations. Speciation by ligand-exchange/DPCSV indicated that Cu and Ni were predominantly organically complexed (>99%). Thus, the DGT-labile species for Cu and Ni were much more abundant than the free ionic and inorganic species determined by ligand-exchange/DPCSV. The results can be explained by incomplete metal exchange of very strong complexes with the chelating resin in the DGT devices, metal exchange of less abundant weaker complexes, and by slow diffusion of exchangeable organic complexes. For Zn (36 to >90% DGT-labile) and Mn (50 to 100% DGT-labile), the results indicated that these metals are less strongly organically complexed. A larger fraction of Zn occurred in DGT-labile species in the hypolimnion than it did in the surface water, probably due to a larger concentration of strong ligands in the productive surface water. DGT-labile Cd- (0.01-0.02 nM) and Pb-species (0.03-0.06 nM) were detected at very low levels. The combination of measurements of dissolved and DGT-labile species showed a decrease of Cu, Zn, Cd and Mn concentration at 2.5 m from June to August, which was probably linked to intensive sedimentation of organic matter during summer stagnation. Mixing and oxygenation of the lake in winter-spring led to an increase in dissolved and DGT-labile Ni, Zn and Cd, whereas Mn decreased in the hypolimnion.     

Sedimentary records of environmental evolution in the Sanmen Lake Basin and the Yellow River running through the Sanmenxia Gorge eastward into the sea

A series of independent faulted basins developed in the present middle reaches of the Yellow River during late Cenozoic, among which the Sanmen Lake Basin is located in the east edge of the Loess Plateau, a transitional zone between the second and third macromorphological step of China. The thick strata of the Sanmen Group deposited in the large basin. The Sanmen Group is a perfect place for the study on paleoenvironmental change, tectono-climatic cycles as well as the formation and evolution of the Yellow River. In this paper, the paleoenvironmental changes, regional tectonic movement and the evolutionary process of the Sanmen Lake Basin during the past 5 Ma were reconstructed based on the analysis of paleomagnetic stratigraphy, pollen, TOC and carbonate content from the Huangdigou outcrop near the Sanmenxia Reservoir, Pinglu County, Shanxi Province. The sedimentary records from the outcrop indicate that the basin was first formated by fault activity at about 5.4 MaBP, and after the strong tectonic movement at 3.6 MaBP the lake enlarged and the rainfall of summer monsoon increased. There was no great climatic transition near 2.6 MaBP, corresponding to the bottom age of loess in the Loess Plateau. After Olduvai event (about 1.77 MaBP) the Picea and Abies were presented in the sediments, which indicates a colder climate. The tectonic movement at 1.2 MaBP caused the light angular discordance between the upper and lower Sanmen Group. The sedimentary records show a cold and wet climate during the prosperous periods of loess accumulation such as L15, L9, L6. The tectonic intensification periods of the Sanmen Basin correspond with the tectonic movements in the Qinghai-Xizang Plateau chronologically. The earliest age of the outflow from the Paleo-Sanmen Lake or the partly cutting off of the Sanmenxia Gorge was about 0.41- 0.35 MaBP. The age of cutting thoroughly the Sanmenxia Gorge by the Yellow River and the disappearance of the Paleo-Sanmen Lake was about 0.15 MaBP, which symbolized the formation of the present Yellow River and had an important influence on the environmental and morphological evolution in the middle and lower reaches of the Yellow River.