加权最小范数平差的伪观测解法

首先证明了加权最小范数平差一般解的一个重要性质，由此提出了利用附加的观测值来求解加权最小范数平差问题的方法，并证明了该法与利用一般解法等价性的充要条件。     

塔里木西南早第三纪古地磁和地壳缩短

属于帕米尔弧山前带的乌帕尔剖面和属于南天山山前带的巴对布拉克剖面，现今的纬度差为０．５６°，但是下第三系古地磁测定结果表明其古纬度差很大．乌帕尔剖面齐姆根组上部的古纬度为８°Ｎ，而巴什布拉克剖面巴什布拉克组第５段的古纬度为３６．１°Ｎ。若考虑到当时板块的相对运移速度，估计始新世早期巴什布拉克地区的古纬度大致为３１°Ｎ，与当时乌帕尔所处位置的纬差达２３°。又根据Ｋｌｏｏｔｗｉｊｋ测得的帕米尔西北缘利什坦层的古纬度值，在始新世末期．包括乌帕尔在内的帕米尔前缘与以巴什布拉区为代表的南天山山前带之间还有至少１０°的纬度差。古地磁资料表明，始新世早期，塔里木海宽达２０００ｋｍ，此时印度板块西北端已与欧亚板块局部碰撞，至始新世末，印度板块向北推进２０°，帕米尔弧前缘与南天山山前的距离缩短到约１０００ｋｍ，原塔里木海的两侧上升为山前平原。     

Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.     

辽宁省精细化暴雨洪涝灾害风险评估与预评估

基于辽宁省61个国家气象站1961—2020年和998个区域自动气象观测站建站至2020年逐小时、逐日降水资料,分析了辽宁省暴雨洪涝灾害主要致灾因子,计算了暴雨洪涝孕灾环境指标,完成了辽宁省暴雨洪涝灾害危险性评估。结果表明：暴雨洪涝高危险性地区主要位于丹东;暴雨洪涝灾害人口高风险区主要位于沈阳和大连市区;经济高风险区主要位于大连和盘锦市区;水稻、玉米高风险区主要位于锦州、盘锦和丹东。利用辽宁省无缝隙智能网格预报数据对2022年7月28—29日的暴雨过程灾害风险进行了预评估,发现暴雨灾害危险性高值区域主要分布在朝阳、葫芦岛以及辽宁中部。暴雨灾害可能造成的人口、经济高风险区域主要位于辽宁西部和中部地区;暴雨灾害可能造成的水稻和玉米高风险区主要位于沈阳、铁岭和朝阳北部等地区。预计高风险区主要影响人口约为449万人,经济损失约为1432万元,受影响的水稻面积约为1.028万公顷、玉米面积约为1.798万公顷。通过灾后效果检验,发现预评估模型效果良好,可在实际的暴雨洪涝灾害风险评估业务中使用。     

吉林省桦甸市隆兴铁矿床深部地质特征

隆兴铁矿赋存于太古宙夹皮沟岩群三道沟岩组和腰抢子片麻岩中。认为矿床成因类型是属于受变质(火山沉积)铁硅建造铁矿。富矿部分则是混合岩化热液作用,使铁发生迁移而富集的。确定三道沟组内的火山铁硅质沉积建造岩层是寻找此类型矿床的地层标志,而地球物理标志是地面磁异常强度在1 000 n T以上的面积性异常即为矿致异常。     

新疆锰矿成矿规律研究

最近新疆西昆仑地区锰矿勘查实现重大突破,伴随大型优质锰矿的发现和勘查,锰已成为新疆区域优势金属矿种之一。通过系统收集资料,总结新疆锰矿成矿类型及区域时空规律。指出寒武纪、二叠纪、石炭纪是新疆锰矿成矿的3个重要时代,西昆仑-昆盖山裂谷带、塔里木陆块北部边缘活动带是新疆锰矿成矿的重要构造单元,以海相沉积型锰矿为主要成矿类型。同时,对比中国南方重要锰矿成矿特征,指出新疆奥尔托喀讷什、穆呼锰矿与广西下雷超大型锰矿在地质构造背景、成矿时代、含矿建造、矿石类型等方面均有相似之处,在成矿空间上具某种“亲缘性”。新疆西昆仑穆呼-玛尔坎苏锰矿带具超大型锰矿成矿潜力。     

金试样加工与分解的最新进展

概述了金试样加工与分解的最新进展，对湿法分解方法进行了重点评述。     

河南省近年来遥感监测的森林火灾时空分布规律分析

森林火灾作为一种自然灾害,其发生原因不仅来自于自然因素,从众多的火灾调查中发现,更多地来自于人类活动因素,其发生的时空分布特点和规律,受自然和人类活动共同影响.对2003-2008年春、冬季(11月-次年4月)河南省森林防火期内遥感监测并已查明的森林火灾进行统计分析,结果发现:河南省森林火灾近年来有逐年增多的趋势;冬、春之交的3月为森林火灾的高发月份;从火灾的日变化规律来看,12-15时为一天中森林火灾的高发时段;从火灾发生的空间分布来看,伏牛山南麓发生森林火灾的频率较高.     

A Case study of a snowstorm at the Great Wall Station,Antarctica

A case of a snowstorm at the Great Wall Station was studied using data of NCEP (National Centers for Environmental Prediction) analysis, in situ observations and surface weather charts. The storm occurred on August 29th,2006, and brought high winds and poor horizontal visibility to the region.It was found that the storm occurred under the synoptic situation of a high in the south and a low in the north. A low-level easterly jet from the Antarctic continent significantly decreased the air temperature and humidity.Warm air advection at high level brought sufficient vapor from lower latitudes for the snowstorm to develop.The dynamic factors relating to strong snowfall and even the developmentof a snowstorm were deep cyclonic vorticity at middle and low levels,the configuration of divergence at high level and convergence at low level, and strong verticaluplift. There was an inversion layer in the low-level atmosphere during the later phase of the storm.This vertical structure of cold air at low levels and warm air at high levels may have been important to the longevity of the snowstorm.     

基于地面运动强度及标准贯入试验的上海地区砂土地震液化评价

上海市地处长江三角洲前缘,黄浦江和苏州河交汇区域,特殊的地理环境与沉积环境导致浅部砂层广泛发育。随着城市建设的不断推进,上海城市区域范围的砂土地震液化风险评价成为亟待研究的课题。文章基于上海市工程钻孔数据,结合地震地面运动加速度分布与标准贯入试验,建立区域性地震液化危险性评价模型,对上海市进行了地震液化危险性评价。研究认为当发生50年超越概率10%的地震条件下,上海市陆域面积的66.0%将不会产生地震砂土液化灾害,21.8%的陆域面积仅发生轻微液化,只有崇明、横沙、长兴三岛,黄浦江及苏州河两岸地震液化等级达到中等甚至严重,占全市陆域面积12.3%;50年超越概率2%的地震条件下,随着峰值地面运动加速度整体升高,全市范围内轻微—严重液化区域明显增多,可能发生地震液化的总面积达到全市陆域面积46.25%。上海市存在砂土地震液化的危险性,但是发生概率较低。研究认为,目前的抗震设计规范中上海市的设防烈度偏高,可能导致不必要的建设成本。同时研究中的不同超越概率下的地震液化危险性评价结果为上海市工程建设相关标准的合理化改进的提供了建议和参考。