辽宁凌源四合当地区九佛堂组珍稀化石层划分及意义

辽宁省凌源市四合当地区九佛堂组含有丰富的中生代热河生物群化石,尤其是珍稀化石.通过剖面测制、化石采集以及实地调查等手段,将九佛堂组划分为3个段,确定了化石层的分布及重要化石的产出层位,同时命名了3个化石层：一段的韩家沟层、二段的卅二道湾层、三段的四合当层,加深了辽西九佛堂组化石层的研究程度.     

Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.     

Geochemistry of organic matter and elements of black shale during weathering in Northern Guizhou,Southwestern China: Their mobilization and inter-connection

Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale.     

面向矿产资源信息的空间关联性分析

关联性分析是综合多源、多类数据,发现和挖掘数据中潜在的相关关系,提取和挖掘数据之间的关联性。该方法对于充分利用地质大数据、发现地质要素之间的共生组合规律具有重要的意义。本文首先基于数据的空间位置,将不同类型的地质空间数据建立联系,形成空间属性数据库;其次应用统计方法,对不同来源数据中的属性特征进行分析,发现热液型金矿的形成与火山作用存在明显相关性;最后基于Apriori算法提取热液型金矿的伴生矿与侵入岩的频繁项集,发现伴生矿与侵入岩酸碱性二者密切相关。因此,在今后的工作中,有望应用空间关联性的方法对地球物理、地球化学、遥感等多源地质数据开展深入的研究分析。     

Intraseasonal oscillation of the rainfall variability over Rwanda and evaluation of its subseasonal forecasting skill

非洲中东部地区的经济主要依靠自给农业支撑,该地区农业经济对降水的变化尤为敏感.本文以卢旺达为例,观测分析指出卢旺达的次季节降雨主要集中在10-25天;根据次季节尺度降水变率的单点相关方法,发现卢旺达的次季节降水变率和周围区域变化一致;进一步合成结果显示该地区次季节降水变率与异常西风有关,这可追溯到赤道地区西传的赤道Rossby波.最后,本文评估了当前动力模式ECMWF对 卢旺达地区(即非洲中东部)次季节降水变率的预报能力,发现EC模式在对该区域降水和相关风场指数的预报技巧都在18天左右,且预报技巧表现出一定的年际差异,这可能与热带太平洋的背景海温信号有关.该工作增进了当 前对非洲中东部地区的次季节降水变率和预测水平的认知,并且对该地区国家粮食安全和防灾减灾具有启示性意义.     

Intraseasonal oscillation of the southwest monsoon over Sri Lanka and evaluation of its subseasonal forecast skill

斯里兰卡的雨季发生于5-9月间,主要受西南季风的控制.本文发现该地区的西南季风降水存在很强的次季节变率,主导周期为10-35天.降水的季节内变化与西传的异常气旋有关.进一步,利用S2S比较计划中欧洲中心的数值预报模式(ECMWF)提供的回报试验数据,评估了当今动力模式对斯里兰卡西南季风次季节变化的预报技巧.结果显示,对季风指数的预测技巧超过30天,而对降水指数的预测技巧大约两周,且模式的预报技巧具有明显的年际差异.分析表明,能否正确模拟出大尺度环流对热带对流的响应是影响斯里兰卡降水预测的重要因子.     

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.     

基于DBSCAN算法的孔深测量与地层反演理论研究

论文针对地质勘探取心工况复杂、钻进深度大、事故发生率高、岩性复杂、钻进参数难以获取、无法实时掌握钻进状态的难题,在充分调研现有工况识别技术的采集原理、功能种类、现场实测的基础上,结合钻探智能化、自动化的发展方向,运用硬件与软件结合的思想,设计了实时测量钻探参数的方案。论文首次提出使用DBSCAN（针对噪声空间基于分布密度进行聚类的算法）密度聚类法分析钻进参数,结合光电编码器增量的正负性进行工况判别,以获取钻头位置以及钻孔深度。该方案可以判别钻进状态,获取钻进工艺参数,将测量数据作为所钻地层的可钻参数来反演地层。钻机的自动化、智能化研究能获取大量地层资料,有利于推进钻进工艺学发展,实现从经验钻探到智能钻探进的突破。同时,为智能钻进系统奠定基础。     

中国内蒙古下白垩统白彦华群胜利组的首个同位素年龄

由于丰富的煤炭资源,内蒙古的下白垩统地层具有重要的经济价值.但长期以来相关地层一直缺乏同位素测年研究,影响了区域地层对比工作的开展.本文对内蒙古锡林浩特下白垩统胜利组煤层夹层中的火山灰锆石应用LA-ICP-MS进行U-Pb法测年,结果显示胜利组5煤(层)和6煤(层)形成于大约109-107 Ma(早白垩世阿尔布期).这...     

2012—2016年象山近岸海域水质评价与模拟研究

为了解象山近岸海域水质污染状况,文章根据2012—2016年象山县近岸海域的水质监测结果,分析象山近岸海域水质现状及年际变化。应用灰色预测的模型来对象山近岸海域水质主要污染物的相关数据进行处理,得出主要污染物的预测结果。分析结果表明：象山近岸海域主要污染物为无机氮。用预测结果和实际数值通过残差验证,最后模拟出今后几年的监测值,为象山县近岸海域生态环境相关管理部门提供数据支撑和决策依据。