Determination of Early Paleozoic metamorphic event in the Longshan Complex and its geological implicationSCIEI北大核心CSCD

长期以来,陇山杂岩的归属问题一直存在争议。本文对出露于秦岭-祁连山结合部位的陇山杂岩中石榴黑云斜长片麻岩和石榴斜长角闪岩进行了详细的岩石学、P-T温压计算、独居石和榍石U-Pb年代学研究。通过详细的岩相学观察,石榴黑云斜长片麻岩的变质峰期矿物组合为石榴子石+黑云母+斜长石+石英;石榴斜长角闪岩中则识别出了以石榴子石+单斜辉石+角闪石+斜长石+石英为峰期的变质矿物组合。通过传统温压计计算,石榴黑云斜长片麻岩(样品21LS40)和石榴斜长角闪岩样品(样品21LS42-1)的峰期变质P-T条件分别为700℃、0.72GPa和710℃、0.74GPa。激光剥蚀电感耦合等离子体质谱(LA-ICP-MS) U-Pb数据表明,石榴黑云斜长片麻岩中独居石的206Pb/238U的加权平均年龄为407~435Ma。石榴斜长角闪岩中榍石的下交点年龄分别为410±7Ma、409±5Ma和426±10Ma,榍石中Zr含量温度计的计算结果分别为750℃、751℃和748℃(假定压力为0.7GPa)。本文从变质作用的角度出发,将陇山杂岩与秦岭杂岩进行温压条件和变质时代对比研究,认为陇山杂岩与东秦岭杂岩高压-超高压岩石的最后一期退变质作用和西秦岭天水地区的秦岭杂岩麻粒岩相变质作用类似,可能为北秦岭造山带的西延。     

The Partitioning of Tungsten bwtween Aqueous Fluids and Silicate Melts

An experimental study has been carried out to determine the partition coefficients of tungsten between aqueous fluids and granitic melts at 800 °C and 1.5 kb with natural granite as the starting material. The effects of the solutions on the partition coefficients of tungsten show a sequence of P > CO ₃ ²⁻ > B > H₂O. The effects are limited (generallyK _D < 0.3) and the tungsten shows a preferential trend toward the melt over the aqueous fluid. The value ofK _D increases with increasing concentration of phosphorus; theK _D increases first and then reduces with the concentration of CO ₃ ²⁻ when temperature decreases, theK _D between the solution of CO ₃ ²⁻ and the silicate melt increases, and that between the solution of B₄O ₇ ²⁻ and the silicate melt decreases. The partition coefficients of phosphorus and sodium between fluids and silicate melts have been calculated from the concentrations of the elements in the melts. TheK _D value for phosphorus is 0.38 and that for sodium is 0.56. Evidence shows that the elements tend to become richer and richer in the melts.     

重要找矿指示元素的野外快速分析法——金的野外快速分析

近年来,作者发展了七种以上重要找矿指示元素的野外快速分析法,此乃其一。文中提出一种新的金样冷浸技术,引进了新的光导光度检测方法,样品经溴化钠—硫酸—过氧化氢冷浸,用经丙酮—MIBK处理的泡沫塑料富集金,经混合解脱剂解脱并直接取解脱液用改进的微珠析出法或用光导光度法测定。取10g样品,可测定0.0005-50g/t范围内的金。方法简便、快速,可在普查分队驻地进行,每一工作日可测定80多个样品,由于废弃了王水分解样品和泡沫塑料的灰化,具有广阔的应用前景。     

数学插值方法在水文地质学中的应用探讨

论述了水文地质工作者正在应用的几种数学插值方法的特点,针对不足之处,提出了改进方案。     

S,Pb, C and O isotopic compositions and ore genesis of the strata-bound polymetallic sulfide deposits in central Inner Mongolia,China

The strata-bound Cu−Pb−Zn polymetallic sulfide deposits occur in metamorphic rocks of greenschist phase of the middle-upper Proterozoic Langshan Group in central Inner Mongolia. δ³⁴S values for sulfides range from −3.1‰ to +37.3‰, and an apparent difference is noticed between vein sulfides and those in bedded rocks. For example, δ³⁴S values for bedded pyrite range from +10.6‰ to +20.0‰, while those for vein pyrite vary from −3.1‰ to +14.1‰. δ³⁴S of bedded pyrrhotite is in the range +7.9‰–+23.5‰ in comparison with +6.5‰–+17.1‰ for vein pyrrhotite. The wide scatter of δ³⁴S and the enrichment of heavier sulfur indicate that sulfur may have been derived from H₂S as a result of bacterial reduction of sulfates in the sea water. Sulfur isotopic composition also differs from deposit to deposit in this area because of the difference in environment in which they were formed. The mobilization of bedded sulfides in response to regional metamorphism and magmatic intrusion led to the formation of vein sulfides. δ¹⁸O and δ¹³C of ore-bearing rocks and wall rocks are within the range typical of ordinary marine facies, with the exception of lower values for ore-bearing marble at Huogeqi probably due to diopsidization and tremalitization of carbonate rocks. Pb isotopic composition is relatively stable and characterized by lower radio-genetic lead. The age of basement rocks was calculated to be about 23.9 Ma and ore-forming age 7.8 Ma.²⁰⁷Pb/²⁰⁴Pb−²⁰⁶Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb−²⁰⁶Pb/²⁰⁴Pb plots indicate that Pb may probably be derived from the lower crust or upper mantle. It is believed that the deposits in this region are related to submarine volcanic exhalation superimposed by later regional metamorphism and magmatic intrusion.     

贺兰山构造带构造—地层层序及构造演化

贺兰山构造带及邻区形成演化经历有多期叠加改造和多个伸展—聚敛旋回构造运动,形成了区域内多套构造—地层层序,因此,开展贺兰山构造带构造—地层层序及构造演化研究对深入理解其地质结构和油气勘探有着重要的意义。本文旨在综合利用野外调查、地震数据和1：50 000区域地质资料,采用野外实地调查和地震剖面精细解析相结合的方法对研究区区域不整合面的分布特征和规律进行详尽分析研究,根据区域不整合面的发育特征,建立区域地层年代格架,划分构造—地层层序,进而对盆地演化阶段进行探讨。研究表明,研究区自下至上发育Pt₂Ch-Jx/Pt₁、∈₁/An∈、C₂/O、T/P、J_1-2/An J、K₁/An K₁、E₃q—N/AnE,据此将研究区垂向上划为7个构造—地层层序：基底构造层、中元古界构造层、震旦系—奥陶系构造层、石炭系—三叠系构造层、侏罗系构造层、下白垩统构造层、新生界构造层。贺兰山构造带构造演化经历中新元古代—早古生代陆缘盆地坳陷—裂谷演化阶段;晚古生代—中三叠世陆相盆地坳陷沉积阶段;晚三叠世局部伸展;中侏罗世—早白垩世大规模逆冲推覆阶段,普遍发育多条大型北东向逆冲断裂;始新世开始进入盆—岭构造形成阶段。     

北半球低频扰动能量结构特征及其与西风急流的关系

对1980年7月29日—8月16日西太平洋副高位置持续偏南和1983年7月16日—8月12日西太平洋副高位置持续偏北的两次季节内副高中期进退过程的环流特征和加热差异作了对比分析,讨论了东亚季风与对流活动、副高进退之间的关系.     

长江中下游及邻区基底和花岗岩成矿元素丰度背景的研究

本文系统地研究了长江中下游及邻区的结晶基底,褶皱基底及花岗岩岩基成矿元素丰度背景,从而为区域Ｃｕ、Ａｕ,Ｗ、Ｓｎ等成矿作用提供了一套完整的基础地球化学数据,用此来作为窥视地壳组成及成矿作用时空演变的窗口。     

Permian High Ba-Sr Granitoids: Geochemistry, Age and Tectonic Implications of Erlangshan Pluton, Urad Zhongqi, Inner Mongolia

Abstract: Erlangshan Pluton from Urad Zhongqi, central Inner Mongolia, is located in the middle segment of the northern margin of the North China Plate. The rocks consist mainly of diorites with gneissic structure. Petrochemical characteristics reveal that the diorites belong to metaluminous, high-potassium calc-alkaline series, with chemical signatures of I-type granites. They are characterized by low SiO2 contents (56.63%–58.53%) and A/CNK (0.90–0.96), high Al2O3 contents (17.30%–17.96%) and Na2O/K2O ratios (1.20–1.70), enrichment in large ion lithophile elements (LILE, e.g., Ba=556–915 ppm, Sr=463–595 ppm), and relative depletion in high field strength elements (HFSE, e.g., Nb, Ta, Ti) in primitive mantle-normalized spidergram, and right-declined rare earth element patterns with slightly negative Eu anomalies (d?Eu=0.72–0.90). They have Sr/Y ratios (20–25) evidently less than Kebu Pluton (49–75) to its east. Sensitive high resolution ion micro-probe U-Pb zircon dating of the diorites has yielded an intrusive age of 270±8?Ma. This leads us to conclude that Erlangshan diorites were formed by mixing between the middle or lower crustal-derived magma and minor mantle-derived mafic magma, followed by fractional crystallization, which was trigged by crustal extension and fault activity in post-collisional setting.     

Fractal kinetic characteristics for dissolving and leaching processes of strontium residue

The pore structural characteristics of strontium residue were studied with the N₂ adsorption method (ASAP2010). The kinetic properties concerning dissolving and leaching strontium waste were described by determining the concentrations of Sr²⁺, Ba²⁺ and soluble sulphides in solutions. The results showed that the specific surface area and pore volume increased with decreasing granule diameter, and the micropore surface of the residue was fractal. In the dissolving and leaching processes of strontium residue, soluble ion concentrations increased with decreasing granule diameter of the residue, and the reaction dimension was lower than the fractal dimension of pore surface. Sr²⁺ and soluble sulphide concentrations significantly exceeded the defined standard values, while Ba²⁺ concentrations did not, either in the dissolving or leaching solutions. In addition, dissolving and leaching reactions selectively occurred on the micropore surface of strontium residue.