赣南地区寒武纪高滩组碎屑锆石U-Pb年龄和Hf同位素特征及地质意义

寒武纪高滩组广泛分布于赣南武功山-雩山地区,主体为一套浅变质砂岩夹板岩的复理石建造。为分析其物源,并对源区地壳生长和构造演化提供约束,本文对采自高滩组的变长石石英杂砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学和Hf同位素研究。锆石U-Pb年龄数据显示2 500 Ma、1 100~900 Ma和900~700 Ma 3个主要年龄峰值。2 500 Ma的年龄峰值代表了新太古代末期—古元古代的古陆核生长事件。1 100~900 Ma和900~700 Ma两个峰最显著,表明Rodinia超大陆聚合裂解在华南地区的响应,为该区寒武纪地层提供了主要物源。此外,3 003 Ma锆石年龄的捕获说明,华夏地块可能存在太古宙地壳基底。Hf同位素数据表明,源区锆石结晶多为古老地壳组分部分熔融产生的岩浆。结合锆石年龄数据分析认为,华南地区存在强烈的新元古代岩浆活动,该时期岩浆活动主要是古老地壳物质的再循环。     

临涣矿区界沟煤矿工程地质条件研究

根据主采煤层顶底板岩体岩性类型及结构面发育程度对其稳定性进行了评价：72煤层顶板以中等稳定一不稳定类型为主,82煤层顶板以中等稳定类型为主,10煤层顶板以中等稳定一稳定类型为主。在大量统计见煤点硬质岩百分含量（k值）的基础上,结合顶板岩石的单轴抗压强度,对各主采煤层顶底板工程地质类型进行了划分：72煤层以一、二类顶板为主,82、10煤层均以五类顶板为主。综合评价该矿工程地质条件为中等即Ⅲ类二型。根据研究成果,指出该矿在采掘过程中可能出现的工程地质问题,并依此提出了治理建议。     

天津地区地热流体化学成分垂向演化特征研究

天津地区地热流体化学成分具有明显的垂向分层演化特征,由浅至深不仅有TDS增高、水化学类型由HCO3-Na型向SO4-Na或Cl-Na型演化的特征,而且具有分层演化特征,即不同热储层段的地热流体水化学特征及演化规律不同,说明其补给、径流、排泄自成系统。     

湖南香花岭复式碱长花岗岩体侵入期次关系的识别

香花岭碱长花岗岩为一复式岩体。不同期次侵入体之间的接触关系、白色和绿色含铍条纹岩以及磁铁矿条纹岩与不同期次侵入体之间的对应关系、通天庙、塘官铺、太平和新风不同矿化组合与不同期次侵入体之间的成因联系以及遥感图像中的环形构造特点和差异明显的Rb-Sr同位素等时年龄表明该岩体是两期四次碱长花岗质岩浆侵入作用的产物,燕山早期的三次岩浆侵入与本区矿化关系密切;而燕山晚期的一次岩浆侵入与矿化无关。上述认识可对矿区的某些地质问题作出合理的解释。     

用自组织人工神经网络分类,识别矿物

作者运用三维Ｔ．Ｋｏｈｏｎｅｎ自组织人工神经网络对我国沉积碳酸盐型锰矿中菱锰矿进行分类、识别。所选研究实例中，识别成功率达１００％．结果表明，该网络性能良好，可望成为矿物识别的有效手段。     

Magnetic susceptibility of ultrahigh pressure eclogite: The role of retrogression

Retrograde metamorphism played the dominant role in changing the low-field rock magnetic properties and density of 198 specimens of variably retrograded eclogites from the main borehole of the Chinese Continental Scientific Drilling Project (CCSD) and from surface outcrops in the Donghai area in the southern part of the Sulu UHP belt, China. Bulk magnetic susceptibility (κ) of unretrogressed UHP eclogite is controlled by whole-rock chemical composition and ranges from 397 to 2312 μSI with principal magnetic susceptibility carrying minerals paramagnetic garnet, omphacite, rutile and phengite. Partially retrograded eclogites show large variations in magnetic susceptibility between 804 and 24,277 μSI, with high mean magnetic susceptibility values of 4372 ± 4149 μSI caused by appreciable amounts of Fe-Ti oxide minerals such as magnetite, ilmenite and/or titanohematite produced by retrograde metamorphic reactions. Completely retrograded eclogites have lower susceptibilities of 1094 ± 600 μSI and amphibolite facies mineral assemblages lacking high magnetic susceptibility minerals. Jelínek's corrected anisotropy (P_j) of eclogites ranges from 1.001 to 1.540, and shows a positive correlation with low-field magnetic susceptibility (κ). Arithmetic mean bulk density (ρ) shows a steady decrease from 3.54 ± 0.11 g/cm³ (fresh eclogite) to 2.98 ± 0.06 g/cm³ (completely retrograded eclogite). Retrograde metamorphic changes in mineral composition during exhumation appear to be the major factor causing variations in low field magnetic susceptibility and anisotropy. Retrograde processes must be taken into account when interpreting magnetic surveys and geophysical well logs in UHP metamorphic terranes, and petrophysical properties such as density and low-field magnetic susceptibility could provide a means for semi-quantifying the degree of retrogression of eclogite during exhumation.     

四川盆地彭水地区五峰组黑色页岩中硫酸盐热化学还原反应矿物学研究

对四川盆地彭水地区奥陶系五峰组剖面黑色页岩中的硬石膏、黄铁矿、方解石脉进行了矿物学分析,结果显示,脉体中硬石膏为溶蚀残余,黄铁矿平行于脉体两边对称分布,从中心至边缘,晶体大小和完整性不断变化,方解石为次生自形晶,这些特征都表明该矿物组合是黑色页岩中发生过TSR的特色矿物组合。溶蚀硬石膏能提供反应所需的硫酸根离子,黑色页岩中有机质及其演化产物提供了还原剂,TSR形成的硫化氢与铁形成的黄铁矿沿脉体分布,方解石主要为成矿流体沉淀所致。这一特征拓宽了高演化阶段成烃流体TSR发生的范畴,证明了TSR在地质条件下的广泛发育,有利于对海相层系油气形成的认识。     

Calcified roasting-acid leaching process of vanadium from low-grade vanadium-containing stone coal

The low-grade vanadium-containing stone coal used in this experiment was collected from Wuxi Coun- try, Chongqing City, China. The experiment focused on the vanadium recovery from roasted residue through opti- mizing the process conditions of an effective and environmentally-friendly technology, named calcified roast- ing-sulfuric acid leaching technology. By single-factor experiments and orthogonal experiments, the effects of roast- ing temperature, roasting time, sulfuric acid concentration and leaching time on the leaching ratio of vanadium were analyzed. The results showed that the leaching ratio of vanadium reached 85.5% under the proper technological con- ditions of roasting temperature=950℃, roasting time=4 h, 40% concentration of sulfuric acid and leaching time=6 h.     

斜方辉石的反演畴结构对其衍射效应的影响

斜方辉石内部存在着众多的相邻间呈反演关系的(100)晶畴。这些晶畴的存在使斜方辉石的K为奇数的okl衍射之强度明显减弱,且参与衍射的晶畴的数目越多,其减弱的程度也就越大。这一现象在一定程度上掩盖了斜方辉石P2_(1ca)的真实对称性。与X射线衍射相比,利用电子衍射来研究斜方辉石的空间群类型具有明显的优越性。     

利用膨润土与工业废渣制轻质保温材料

本文介绍了利用膨润土、钙质造纸废渣制备轻质保温材料的研究,分析了膨润土在轻质保温材料制备中的作用,优选出制备轻质保温材料的配方和工艺。该材料的导热系数为０ ．１７１ Ｗ／ｍ·Ｋ,抗压强度约为９ ．３７ ｋｇ／ｃｍ２ ,容重为０ ．４９ ｇ／ｃｍ３ 。