Evaluation of Upper Triassic T3x5 Source Rocks (Western Sichuan Depression, Sichuan Basin) and their Hydrocarbon Generation and Expulsion Characteristics: Implication for Tight-Sand Gas and Shale Gas Accumulation Potential Assessment

An unconventional, continuous petroleum system consists of an accumulation of hydrocarbons that is found in low-matrix-permeability rocks and contain large amounts of hydrocarbons. Tight-sand gas in the Jurassic and shale gas within the fifth member of Xujiahe Formation (T₃x⁵) are currently regarded as the most prolific emerging unconventional gas plays in China. The conventional and systematical evaluation of T₃x⁵ source rocks was carried out for the first time in the western Sichuan basin (WSD). Hydrocarbon generation and expulsion characteristics (including intensity, efficiency, and amount) of T₃x⁵ source rocks were investigated. Results show that T₃x⁵ source rocks are thick (generally >200 m), have high total organic content (TOC, ranging from 2.5 to 4.5 wt%), and dominated by III-type kerogen. These favorable characteristics result in a great hydrocarbon generating potential under the high thermal evolution history (R _o > 1.2%) of the area. An improved hydrocarbon generation potential methodology was applied to well data from the area to unravel the hydrocarbon generation and expulsion characteristics of T₃x⁵ source rocks in the WSD. Results indicate that the source rocks reached hydrocarbon expulsion threshold at 1.06% R _o and the comprehensive hydrocarbon expulsion efficiency was about 60%. The amount of generation and expulsion from T₃x⁵ source rocks was 3.14 × 10¹⁰ and 1.86 × 10¹⁰ t, respectively, with a residual amount of 1.28 × 10¹⁰ t within the source rocks. Continuous-type tight-sand gas was predicted to develop in the Jurassic in the Chengdu Sag of the WSD because of the good source-reservoir configuration (i.e., the hydrocarbon generation and expulsion center was located in Chengdu Sag), the Jurassic sandstone reservoirs were tight, and the gas expelled from the T₃x⁵ source rocks migrated for very short distances vertically and horizontally. The amount of gas accumulation in the Jurassic reservoirs derived from T₃x⁵ source rocks is up to 9.3 × 10⁸ t. The T₃x⁵ gas shale has good accumulation potential compared with several active US shale-gas plays. Volumetrically, the geological resource of shale gas is up to 1.05 × 10¹⁰ t. Small differences between the amounts calculated by volumetric method compared with that by hydrocarbon generation potential methodology may be due to other gas accumulations present within interbedded sands associated with the gas shales.     

Surface circulation patterns observed by drifters in the Yellow Sea in summer of 2001, 2002 and 2003

In summer of 2001, 2002 and 2003, ten, six and seventeen satellite-tracked surface drifters with drogues centered at 15 and 4 m were deployed, respectively, in the southern Yellow Sea (YS). 23 drifters of them transmitted useful data of at least 30 days. The wind-driven component of the drift was removed from the original drift velocity of drifters. The wind data used are from NCEP (National Center for Environmental Prediction), USA.Trajectories and drift velocities of the 23 drifters depicted the upper circulation structure in the southern YS. There exists an anti-cyclonic eddy with a mean speed and radius of 0.063 m/s and 50km in the central southern YS, whose center lingered within 35.3-36.0°N / 123.5-124.0°E. Showed by 6 drifters, a basin-scale elliptic cyclonic gyre with a mean speed of 0.114 m/s, long and short radius of 250 and 200 km surrounds the anti-cyclonic eddy. In the southwestern part of the southern YS has obvious frontal eddy activities within about 100 km with a mean speed about 0.076     

Numerical Study of Water and Suspended Matter Exchange Between the Yellow Sea and the East China Sea

INTRODUCTIONTheYellowSeaandtheEastChinaSea (ECS)aremarginalseasofthenorthwestPacificandhaveexpansivecontinentalshelves .TheuniqueandstrikingfeaturesoftheYellowSeaandtheECSarethattheyhavestrongtidalcurrent;aresubjecttostrongmonsooninfluence ;andreceiveinflowfromthebiggestriverinChina ,theChangjiangRiver ;andthatthefamouswesternboundarycurrent,theKuroshio ,passesthroughtheECS ,withitsbranchesintrudingupwardintothecontinentalshelfareas.Generallyspeaking ,thewaterexchangecapacityofthe…     

Antioxidant enzyme activities in different genders and tissues of amphioxus Branchiostoma belcheri tsingtauense

Information regarding antioxidant enzymes in amphioxus remains lacking, and this study was carried out to examine the activities of superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPX) in different genders and tissues of amphioxus Branchiostoma belcheri tsingtauense. Results show that (1) CuZn-SOD, CAT and GPX activities in the whole amphioxus B. belcheri tsing- tauense were basically at the same levels in male and female amphioxus, whereas both T-SOD and Mn-SOD activities in male amphioxus were significantly higher than that in the female (P<0.05); (2) The testis had significantly higher T-SOD and CuZn-SOD activities than the ovary (P<0.05); (3) CuZn-SOD activity was undetectable in the guts of male and female amphioxus; (4) For both male and female am- phioxus, the activities of CAT and GPX in the gonads including testis and ovary were the lowest (P<0.05) among the tissues examined; (5) The gut and gill had the same level GPX activities while the gut had a higher CAT activity; (6) There was no clear difference in CAT and GPX activities in the corresponding tissues between male and female amphioxus. The study on SOD, CAT and GPX activities in different genders and tissues of the protochordate provides data for future comparison of amphioxus antioxidant enzymes with those of invertebrates and vertebrates.     

Abundant Fe–Ti oxide inclusions in olivine from the Panzhihua and Hongge layered intrusions, SW China: evidence for early saturation of Fe–Ti oxides in ferrobasaltic magma

Abundant Fe–Ti oxide inclusions in cumulus olivine (Fo_77–81) from the Panzhihua and Hongge intrusions, Emeishan large igneous province, SW China, document the first evidence for early crystallization of Fe–Ti oxides in ferrobasaltic systems in nature. The intrusions also contain significant stratiform Fe–Ti–V oxide ores. The oxide inclusions are sub-rounded or irregular, range from ∼5 to 50 μm in diameter, and are dominated by either titanomagnetite or ilmenite. The fact that the inclusions are either titanomagnetite- or ilmenite-dominant suggests that they are trapped crystals, instead of immiscible oxide melt, formed during growth of the host olivine. The absence of other silicate phases in the inclusion-bearing olivine is difficult to reconcile with a possible xenocrystic origin of the oxide inclusions. These oxide inclusions are thus interpreted to be cumulus minerals crystallized together and trapped in olivine from the same parental magma. In addition to Fe–Ti oxides, some inclusions contain amphibole + biotite ± fluorapatite that might have formed by reaction of trapped hydrous liquid with the host olivine. Numerical modeling of high-Ti Emeishan basalts using the MELTS program successfully simulates early crystallization of olivine (∼Fo₈₁) and Fe–Ti spinel in the presence of a moderate amount of H₂O (∼1.5 wt%) under pressure and fO₂ conditions generally pertinent to the Panzhihua and Hongge intrusions. The modal mineralogy of the oxide inclusions is in good agreement with the bulk compositions of the ore, as inferred from whole-rock data, in a given intrusion. This is consistent with the interpretation that the stratiform oxide ores in the intrusions formed by accumulation of Fe–Ti oxide crystals that appeared on the liquidus with olivine and clinopyroxene.     

Analysis of a variational Bayesian adaptive cubature Kalman filter tracking loop for high dynamic conditions

GPS Solutions - Under high dynamic conditions, a robust tracking loop is essential for accuracy positioning with the global position system. In previous studies, the extended Kalman filter...     

基于GPS的“雪龙”船冲击式破冰模式识别研究

"雪龙"号破冰船是我国目前唯一的极地考察船,破冰航行是极地船舶的重要特征之一。以"雪龙"号破冰船的GPS数据为基础,通过建立模型算法识别冲击式破冰这一特殊的航行状态,在整个中国第28次南极考察航次的数据分析中,整体识别率超过86.1%,识别正确率达到98%以上。利用此算法,在中国第27次南极考察航次的破冰识别率也超过85%,识别正确率达到93.5%。雪龙船两个航次实测GPS数据验证了本文算法的可用性,而破冰识别统计结果表明,不同航次的破冰模式具有较大的差异。     

国内外农户对气候变化/变异感知与适应研究

基于国内外农户气候变化感知和适应研究进展,在辨析气候变化和气候变异概念的基础上,阐释农户气候变化/变异感知结果及影响因素。研究发现农户气候变化感知与适应行为之间存在不确定关系,农户气候变化感知直接转化为适应策略需克服一系列障碍因素。针对农户气候变化适应策略,在系统梳理国内外农户适应策略的基础上,对这些策略是否属于气候变化和变异适应行为提出质疑,认为不能忽略其他复杂的社会经济和政治因素对这些措施的驱动作用。最后,对中国未来研究提出慎重大规模开展农户气候变化感知及适应研究、厘清气候变化/变异感知与适应策略之间关系和重视时空异质性以及农户异质性研究三点展望。     

Cap setting and allowance allocation in China's emissions trading pilot programmes: special issues and innovative solutions

Seven emissions trading scheme (ETS) pilots have been established in China. They have introduced some unique methods to set emissions caps and allocate allowances, different from textbook models and their counterparts in the EU, California, and many other regions. This article provides a detailed introduction to the methods for cap setting and allowance allocation adopted by the pilots, and presents detailed comparisons of these methods. In terms of cap setting, the pilots adopt flexible caps that can be adjusted where necessary, which primarily depends on the outcomes of the bottom-up approach, namely aggregating the allowances allocated to participants. As for allowance allocation, the pilots not only adopt such methods as grandfathering and benchmarking, which are also widely applied in other existing schemes, but also some special methods that require ex post adjustment, such as those based on enterprises’ historical emissions intensity (including both physical quantity and added-value intensity) and current production/output. The factors influencing the design are further analysed, including the impacts of theory and experience from foreign systems, concerns about economic development, traditions regarding intensity targets and policy, constraints from data availability and preparation time, tight regulation of the electricity and heat generation sector, and concerns regarding price stability. The practice of pilots presents an improvement opportunity and a challenge for China to further balance the theoretical and practical requirements in ETS design in establishing its national system.

Policy relevance

China is piloting emissions trading in seven regions, as part of efforts to try to rely more on market-based instruments to achieve GHG emissions control targets. All seven pilots have been confronted with special issues in the design process when compared with existing foreign schemes. This article analyses in depth the special issues related to cap setting and allowance allocation and the approaches adopted to address these issues. Flexible cap setting through a bottom-up approach and different types of allocation methods with or without ex post adjustment are adopted in the pilots. The flexible and innovative approaches the pilots have developed could provide useful experience for designing the nationwide ETS in China and promoting emissions trading policy in other parts of the world.     

Geochemical and isotopic characteristics of fluids in the Niutuozhen geothermal field,North China

Niutuozhen geothermal field is located in the Jizhong graben, belonging to the northern part of Bohai Bay Basin in North China. Chemical and isotopic analyses were carried out on 14 samples of the geothermal fluids discharged from Neogene Minghuazhen (Nm), Guantao (Ng), and Jixianian Wumishan (Jxw) formations. The δ²H and δ¹⁸O in water, δ¹³C in CH₄, δ¹³C in CO₂, and ³He/⁴He ratio in the gases were analyzed in combination with chemical analyses on the fluids in the Niutuozhen geothermal field. The chemical and isotopic compositions indicate a meteoric origin of the thermal waters. The reservoir temperatures estimated by chemical geothermometry are in the range between 60 and 108 °C. The results show that the gases are made up mainly by N₂ (18.20–97.42 vol%), CH₄ (0.02–60.95 vol%), and CO₂ (0.17–25.14 vol%), with relatively high He composition (up to 0.52 vol%). The chemical and isotopic compositions of the gas samples suggest the meteoric origin of N₂, predominant crustal origins of CH₄, CO₂, and He. The mantle-derived He contributions are calculated to be from 5 to 8% based on a crust–mantle binary mixing model. The deep temperatures in the Jxw reservoir were evaluated based on gas isotope geothermometry to be in the range from 141 to 165 °C. The mantle-derived heat fraction in the surface heat flow is estimated to be in the range of 48–51% based on ³He/⁴He ratios.