乙酰褐藻酸丙二酯的制备与表征

为了改变褐藻酸丙二酯的溶解性,本文以氢碘酸为催化剂,将褐藻酸丙二酯与乙酐反应,制备了乙酰褐藻酸丙二酯。生成物不溶于水,可溶于多种中等极性的有机溶剂。本文用IR,~1H-NMR,HGPC对其进行了表征,并对反应条件对产率的影响进行了探讨。     

PRESENT KINEMATICS CHARACTERISTICS OF THE NORTHERN YUMUSHAN ACTIVE FAULT AND ITS RESPONSE TO THE NORTHEASTWARD GROWTH OF THE TIBETAN PLATEAU

Qilian Shan and Hexi Corridor, located in the north of Tibetan plateau, are the margin of Tibetan plateau's tectonic deformation and pushing. Its internal deformations and activities can greatly conserve the extension process and characteristics of the Plateau. The research of Qilian Shan and Hexi Corridor consequentially plays a significant role in understanding tectonic deformation mechanism of Tibetan plateau. The northern Yumushan Fault, located in the middle of the northern Qilian Shan thrust belt, is a significant component of Qilian Shan thrust belt which divides Yumushan and intramontane basins in Hexi Corridor. Carrying out the research of Yumushan Fault will help explain the kinematics characteristics of the northern Yumushan active fault and its response to the northeastward growth of the Tibetan plateau.Because of limited technology conditions of the time, different research emphases and some other reasons, previous research results differ dramatically. This paper summarizes the last 20 years researches from the perspectives of fault slip rates, paleao-earthquake characteristics and tectonic deformation. Using aerial-photo morphological analysis, field investigation, optical simulated luminescence(OSL)dating of alluvial surfaces and topographic profiles, we calculate the vertical slip rate and strike-slip rate at the typical site in the northern Yumushan Fault, which is(0.55±0.15)mm/a and(0.95±0.11), respectively. On the controversial problems, namely "the Luotuo(Camel)city scarp" and the 180 A.D. Biaoshi earthquake, we use aerial-photo analysis, particular field investigation and typical profile dating. We concluded that "Luotuo city scarp" is the ruin of ancient diversion works rather than the fault scarp of the 180 A.D. Biaoshi earthquake. Combining the topographic profiles of the mountain range with fault characteristics, we believe Yumu Shan is a part of Qilian Shan. The uplift of Yumu Shan is the result of Qilian Shan and Yumu Shan itself pushing northwards. Topographic profile along the crest of the Yumu Shan illustrates the decrease from its center to the tips, which is similar to the vertical slip rates and the height of fault scarp. These show that Yumu Shan is controlled by fault extension and grows laterally and vertically. At present, fault activities are still concentrated near the north foot of Yumu Shan, and the mountain ranges continue to rise since late Cenozoic.     

金沙江支流黑水河松新电站短须裂腹鱼（Schizothorax wangchiachii）过坝后上溯行为

鱼类过坝后的上溯行为对鱼类寻找适宜的产卵、索饵等功能性栖息地至关重要。现阶段我国大多数研究聚焦于鱼类上溯通过鱼道的游泳行为量化,而过坝后的上溯行为分析鲜有报道。本研究在金沙江下游支流黑水河松新坝址处利用PIT(passive integrated transponder)遥测技术对松新电站过鱼对象短须裂腹鱼(Schizothorax wangchiachii)过坝后的上溯行为开展监测,考虑监测过程中水文情势变化对过坝后上溯行为的影响,采用生存分析方法,构建了耦合多因素(流量、水温、河道涨落水率、昼夜节律、肥满度等)的Cox风险比例回归模型,利用AIC模型准则筛选出最优模型参数,识别了影响鱼类过坝后上溯成功率的关键因素。结果表明:(1)短须裂腹鱼在松新鱼道的上溯效果显著优于河道;(2)水温及河道涨落率是影响短须裂腹鱼过坝后上溯效果的关键因素;(3)水温与短须裂腹鱼过坝后河道上溯成功率呈负相关,当水温超过短须裂腹鱼最适温度后,河道上溯成功率随着温度的上升呈递减趋势;河道涨落水率与短须裂腹鱼过坝后河道上溯成功率呈正相关,其中涨水情势下短须裂腹鱼河道成功上溯的概率高于落水,河道上溯成功率随着涨...     

金沙江下游支流黑水河松新电站幼鱼下行过坝研究

梯级小水电的开发一定程度上破坏了河流连通性并阻碍了鱼类洄游通道。黑水河流域松新坝址为了满足鱼类上行产卵修建了松新鱼道,然而作为洄游物种生命周期中的关键行为,鱼类下行洄游的需求也同等重要。为了寻求一种可行、高效、低损伤的下行过鱼方式,了解河流中不同环境因素对鱼类下行效率的影响,本研究在金沙江下游支流黑水河松新水电站补水通道开展鱼类下行过坝效果评估研究。针对两种鲤科鱼类(棒花鱼Abbottina rivularis和短须裂腹鱼Schizothorax wangchiachii)幼鱼和两种鳅科鱼类(短体副鳅Paracobitis potanini和红尾副鳅Paracobitis variegatus)幼鱼各放鱼90尾,定量分析鱼种、水体透明度、放鱼位置、流量、水温、水位等因素对鱼类下行效率的影响。结果表明:棒花鱼、短须裂腹鱼、短体副鳅、红尾副鳅的下行率依次为22.22%(20尾)、28.89%(26尾)、8.89%(8尾)、15.56%(14尾);幼鱼下行成功率与上游河道水温呈正相关趋势,且放鱼位置、鱼种、上游河道水温和流量均对鱼类下行成功率有显著影响。通过构建二元Logistic回归模型识...     

A Simplified Solution Using Izbash's Equation for Non-Darcian Flow in a Constant Rate Pumping Test

This paper derives an equivalent of Darcian Theis solution for non-Darcian flow induced by constant rate pumping of a well in a confined aquifer. The derivation, which is valid at later times only, is original. It utilizes Izbash's equation. This introduces an additional parameter to Darcian condition, namely, empirical exponent. The solution is a non-Drcian equivalent of Jacob straight line method for analyzing pumping tests at late times. It can be used to determine aquifer parameters: storativity, analogous hydraulic conductivity, and empirical exponent. However, while the Jacob method requires a minimum of only one pumping test with one observation well, the additional parameter in the present solution means that a minimum of two observation wells in one test or two pumping tests at different rates with one observation well are required. The derived solution is applied to a case study at Plomeur in Brittany, France, and is shown to provide a practical and efficient method for analyzing pumping tests where non-Darcian groundwater flow occurs.     

四川2015速度模型在九寨沟M_S7.0地震震源深度测定中的应用

利用四川2015模型,选择Msdp嵌入的几种常用定位方法对九寨沟M_S7.0地震进行重新定位,比较震源深度结果,并用PTD方法验证合适的震源深度,从而得到较为可靠的震源深度。本文最终判定九寨沟M_S7.0地震震源深度为12±2km。     

A method to estimate the forces exerted by internal solitons on cylindrical piles

Internal soliton is the large amplitude wave existing in the pycnocline, induced by internal tide in the condition of special bottom topography. During its propagation process, the induced disturbance can bring about strong convergence of sea water and sudden strong current (wave-induced-current), which can cause severe threat to the ocean engineering structures, such as oil drilling platform and pipeline. In this paper, Morison’s empirical method, modal separation and regression analyses are introduced to estimate the forces and torques exerted by internal soliton on cylindrical piles. As an example, a limited set of observational data recording a passage of the internal soliton near Dongsha Islands is used to estimate the horizontal velocity and its acceleration in a vertical section for computing the force and torque on a supposed pile, and the estimation results are reasonable. It is shown that, the higher number of the modes retained in the calculation, the better the estimation of velocity profile fits the observational one. A better overall approximation to the real solution can be reached if there are more observational current data acquired in a whole vertical profile.     

空间互相关方法在分析海底沙波迁移规律中的应用

海底沙波具有显著的活动性并能够对海底工程设施造成潜在威胁,因此对海底沙波活动性的评估一直以来受到广泛关注。目前大多数研究者仍利用平面剖面对比来分析海底沙波的迁移特征。然而,该方法难以全面高效地获取海底沙波二维平面迁移矢量。本文基于2007年和2009年的高分辨率多波束测深数据,详细阐述了空间互相关方法在分析北部湾东南海域海底沙波迁移规律中的应用过程。利用实测数据进行对比分析,获得了研究区海底沙波的活动特征,并进一步讨论了空间互相关算法中不同参数的选取对结果的影响。结果显示,利用空间互相关分析方法能够有效获取海底沙波二维迁移矢量,获得的海底沙波迁移速率和迁移方向与前人研究成果吻合,表明了该方法的可行性和可靠性。但在对实际DTM数据进行空间互相关分析时,需根据海底沙波形态、数据质量等因素选取合适的参数及矢量获取方法。本研究实验了一种确定海底沙波迁移规律的新方法,该方法将有效提升获得海底地形变化规律的效率和准确度,可获得更加精细的海底地形动力过程。     

Electro-osmotic permeability model based on ions migration

Acta Geotechnica - Electro-osmotic permeability is a very important parameter in soil drainage and electrochemical remediation. The present widely used equation for calculating the electro-osmotic...