Microstructure characteristics and forming environment of late Quaternary Period loess in the Loess Plateau of China

Since the late Quaternary Period, the rapid rising of the northeastern Qinghai-Tibetan Plateau has greatly changed the East Asian climate and formed different regional monsoon climates. Various microstructures of the loess in northern China have formed under a variety of climatic conditions. The scanning electron microscope (SEM) and energy spectrum analysis are used in this paper to study the relationship between the indexes of loess microstructures and the forming climates, and the indexes include the diameter of sand grains, Ca/Fe value and the characteristic shapes of the loess from SEM microstructures pictures. In terms of their respective climatic circumstances, the major microstructures of regional loess may be classified into nine categories according to their forms and particle sizes, such as loess formed in near-sand source, loess of granule sand dropping, and loess formed in hot and rainy places, i.e. with the loess SEM pictures, climates of about 15 ka b.p. in different places may be evaluated. In conclusion, the clear and distinguishable loess microstructures and their indexes in the Loess Plateau of China can also deduce the evolution of climate, such as warm or cold and wet or dry, and even sandstorm activities when the loess is deposited.     

空心块体水沙动力及泥沙淤积特性研究

空心块体具有良好的阻水和促淤功能,近年来被广泛用于生态修复工程。本文结合水槽试验及Flow-3D数值模拟,分析了开敞型和半封闭型空心块体的阻水效应和泥沙淤积特性。结果表明:空心块体的开孔率对内部水流流速、紊动强度起主导作用,开孔率较小的半开敞型空心块体减速、制紊效果更强;开敞型和半封闭型空心块体近底层悬沙浓度分别增大56%和75%,两者均有利于促进泥沙在块体内部淤积,近底层水流紊动越强,泥沙淤积形态差异越大;空心块体所营造的低流速、泥沙微淤、内外连通的水沙环境是大型底栖生物的生境需求,半封闭型空心块体内部的低紊动水流结构更有利于大型底栖生物的栖息、繁衍。     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

电活化硫酸盐处理四环素类废水的研究

本文构建以掺硼金刚石(Boron-doped diamond,BDD)为阳极、不锈钢为阴极、硫酸盐为电解质的电化学体系,考察了电流密度、pH值、硫酸盐浓度以及初始四环素浓度等四个因素对电化学氧化降解废水中四环素的影响,运用响应曲面法对运行参数进行优化;通过电子自旋共振检测技术分析电化学反应中产生的自由基,探究了间歇通电模式下电化学体系持续氧化机理。结果表明,四个因素对TOC去除率的影响大小次序为:电流密度>初始四环素浓度>初始pH值>硫酸盐浓度,其中初始pH值和硫酸盐浓度与电流密度和初始四环素浓度的交互作用对TOC去除率的影响较为显著;最佳运行参数为pH值为5,电流密度为100 mA·cm^-2,硫酸盐浓度为0.25 mol·L^-1,初始四环素浓度为1000 mg·L^-1;间歇通电模式下,BDD电极表面产生的SO₄^·-等高活性物质间相互转化提供了体系的可持续氧化能力。该研究结果为电化学氧化技术的实际应用提供了节省能耗的有效途径。     

The challenges of integrating explainable artificial intelligence into GeoAI

Although explainable artificial intelligence (XAI) promises considerable progress in glassboxing deep learning models, there are challenges in applying XAI to geospatial artificial intelligence (GeoAI), specifically geospatial deep neural networks (DNNs). We summarize these as three major challenges, related generally to XAI computation, to GeoAI and geographic data handling, and to geosocial issues. XAI computation includes the difficulty of selecting reference data/models and the shortcomings of attributing explanatory power to gradients, as well as the difficulty in accommodating geographic scale, geovisualization, and underlying geographic data structures. Geosocial challenges encompass the limitations of knowledge scope—semantics and ontologies—in the explanation of GeoAI as well as the lack of integrating non-technical aspects in XAI, including processes that are not amenable to XAI. We illustrate these issues with a land use classification case study.     

Changes in Land Use and Agricultural Production Structure Before and After the Implementation of Grain for Green Program in Western China–Taking Two Typical Counties as Examples

Soil erosion becomes a serious environmental problem in the world, especially in western China. An effective management practice called the Grain for Green Program （GGP）, which was launched in 1999, aims to reduce soil and water loss and alleviate the ecological environment problem in western China. Two typical counties in western China, the Zhongxian （in Chongqing Municipality） and Ansai （in Shaanxi Province） were chosen to evaluate the dynamic changes of land use and agricultural production structure before and after the implementation of the Program in this paper. The results showed that the cultivated land area was reduced by 7.08% from 1989 to 2003. The cultivated land per person was decreased by 8.42% during 1999-2003. Moreover, the stability index of the secondary sector of the economy was increased from 0.91 in the period 1990-1999 to 0.94 in the following ten years. In addition, the stability index of tertiary economic sector increased from 0.88 to 0.92 in Zhongxian county. Meanwhile, the cultivated land area was reduced by 15.48% from 1990 to 1999. The soil erosion modulus was decreased by 33.33% from 1999 to 2006. Also, the stability index of secondary and tertiary economic sectors was 0.86 in the period 1998-2002. However, it decreased by 77% during 2002 to 2007 in Ansai County. These results imply that the Grain for Green Program had different impact on the two regions. Several effective strategies of soil and water conservation have been carried out to ameliorate the sustainable development of ecological environment and economy in these two counties of western China.     

鄂尔多斯盆地子北地区长6段油藏成藏条件及主控因素

分析了鄂尔多斯盆地子北地区延长组长6段油层构造特征、沉积相分布及砂体展布特征,从烃源岩、储层、盖层等方面对长6段油藏成藏条件进行了探讨,并就油藏类型、主控因素及成藏期次进行了讨论。结果表明:子北地区长6段油藏具有较好的生、储、盖配置关系,主要受沉积微相及储层物性控制;长6段油气主要储存在长61、62、63段河道砂体内,油藏类型主要为岩性圈闭;长6段油藏主控因素有主分流河道、储层物性及其非均质性、原油分布;长6段油层中,油气包裹体均一温度分布呈双峰状,主要在100℃~110℃和130℃~140℃;利用热演化史与流体包裹体均一温度法对油气成藏期次进行判断,长7段烃源岩生成的油气在早白垩世运移并大量聚集至长6段油层组,形成长6段油藏。     

南京市居民网络消费的影响因素及空间特征简

在互联网络和信息技术的影响下,网上购物、团购等基于电子商务平台的网络消费方式得到极大发展,网络消费逐渐成为城市居民消费选择的重要方式,网络消费市场得到了较快的发展。同时,由于居民社会阶层的差别及相应居住空间的分异,导致网络消费呈现出不同的空间特征,并且对实体空间产生不同程度的影响。通过对南京居民网络消费情况的问卷调查,分析个人社会经济属性、住房状况、交通方式以及移动网络使用等体现居民社会阶层状况的要素对居民网络消费选择的影响,进而分析居民网络消费的空间分布特征,研究城市不同空间的网络消费构成和网络消费商品类型特征,在此基础上分析不同空间网络消费对交通出行和实体商业空间结构的影响程度。     

基于空间自相关的东莞市主体功能区划分简

中国“十一五”规划纲要明确提出,根据资源环境承载能力、现有开发密度和发展潜力,统筹考虑未来中国人口分布、经济布局、国土利用和城镇化格局,将国土空间划分为优化开发、重点开发、限制开发和禁止开发四类主体功能区。至今已有不少学者开展主体功能区划分研究,但所用方法工作量大,或带有一定的主观性,且未考虑同类功能区集聚或分散程度。因此提出利用遗传算法改进传统聚类方法,自动划分主体功能区,在划分过程中考虑区域的全局空间自相关特性,使同类功能区在空间上呈集聚分布的格局。以近年来城市快速扩张的东莞市为例,验证了此方法的可行性,能简单有效地进行主体功能区划分。与常用的K-means聚类方法相比,新方法划分结果更符合实际情况,能进一步推广应用到其它地区的主体功能区划分。     

闽江流域水体氨氮降解系数实验模拟研究

本研究采用模拟实验对闽江流域氨氮的降解规律进行研究,降解系数采用稳态一维降解模型进行分析计算,闽江上游流域氨氮的平均降解系数为0.140~0.260 d-1,中下游流域氨氮的平均降解系数为0.099~0.203 d-1。结果表明,闽江上游流域氨氮自净能力比中下游流域的自净能力好,古田溪断面的氨氮平均降解系数低于全国的平均值,说明氨氮自净能力相对较弱,本研究为确定流域水环境容量和纳污能力及制定污染物总量控制提供科学依据。