Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea

The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward electric field, and are not associated with the increase of the O/N₂ ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically coupled upward to generate ionospheric perturbations and oscillations.     

GIS支持的城市固体废弃物规划管理信息系统构建

研究了基于组件式GIS平台MapX的城市固体废弃物规划管理信息系统的设计与实现;讨论了系统框架与系统功能设计、数据库设计和系统实现的关键技术。以昆明市为例,构建了基于MapX的城市固体废弃物规划管理信息系统。该系统能够实现城市固体废弃物各类数据的采集、表达和输出,提供与城市固体废弃物管理模型无缝集成的接口,可利用地图、文字、表格等多种手段为城市固体废弃物规划管理提供辅助决策。     

Study on Recovering the Earth＇s Potential Field Based on GOCE Gradiometry

Given the second radial derivative Vrr（P） ｜δs of the Earth＇s gravitational potential V（P） on the surface δS corresponding to the satellite altitude, by using the fictitious compress recovery method, a fictitious regular harmonic field rrVrr（P）^＊ and a fictitious second radial gradient field V：（P） in the domain outside an inner sphere Ki can be determined, which coincides with the real field V（P） in the domain outside the Earth. Vrr^＊（P）could be further expressed as a uniformly convergent expansion series in the domain outside the inner sphere, because rrV（P）^＊ could be expressed as a uniformly convergent spherical harmonic expansion series due to its regularity and harmony in that domain. In another aspect, the fictitious field V^＊（P） defined in the domain outside the inner sphere, which coincides with the real field V（P） in the domain outside the Earth, could be also expressed as a spherical harmonic expansion series. Then, the harmonic coefficients contained in the series expressing V^＊（P） can be determined, and consequently the real field V（P） is recovered. Preliminary simulation calculations show that the second radial gradient field Vrr（P） could be recovered based only on the second radial derivative V（P）｜δs given on the satellite boundary. Concerning the final recovery of the potential field V（P） based only on the boundary value Vrr （P）｜δs, the simulation tests are still in process.     

长江流域沿江镉异常源追踪与定量评估的方法技术研究:以长江流域安徽段为例

长江全流域性的Cd异常是被中国正在进行的多目标地球化学调查发现的重大生态环境问题。以长江流域安徽段为研究对象,对沿江镉异常源追踪与定量评估的方法技术进行了系统研究。通过对安徽段长江干流及其主要支流悬浮物中元素含量的测量查明:悬浮物是流域内重金属元素大跨度迁移的主要载体;Cd在悬浮物中的富集程度远远大于其他重金属元素,这或许正是Cd可以形成沿江流域性异常的主要原因;长江干流悬浮物中重金属元素含量的变化明显受到沿江支流的影响。安徽段长江干流及其主要支流重金属元素输出通量定量计算结果表明:秋蒲河是安徽段重金属元素输出通量最大的支流,每年在安徽段长江两岸土壤中沉积下约4.45t的Cd。利用悬浮物加密测量、1∶5万土壤测量和岩石测量对顺安河流域Cd异常源追踪结果显示:内生金属矿床特别是铅锌矿是悬浮物中Cd的最大的供应源。采用河漫滩沉积物分层采样技术和同位素测年技术,初步恢复了研究区Cd等重金属元素沉积和污染的地球化学历史,对研究区Cd等重金属元素异常的未来演变趋势进行了预警预测。     

成都经济区天降水与下渗水元素地球化学特征及土壤元素输入输出通量

论文研究了成都经济区天降水和下渗水中元素含量、在农田耕层中的输入输出通量及其影响因素.研究表明,研究区雨水中含有大量SO2-4、NO-3等酸性物质,雨水中SO2-4 >NO-3>Cl-.雨水中Ca2 和NH 4含量最高,且NH 4>Ca2 >K >Na >Mg2 .雨水的pH与阴、阳离子摩尔浓度差值具有显著相关性.下渗水中以Ca2 为主要阳离子,且Ca2 >Na >Mg2 >K >NH 4;HCO-3为主要阴离子,且HCO-3>NO-3>SO2-4>Cl->F-,下渗水pH与阳、阴离子摩尔浓度差值具有显著相关性.不同地区雨水中Pb>As>Cd>Se>Hg,下渗水中Pb>As>Se>Cd>Hg,因此,Cd、Pb、Se和Hg等元素累积在耕层中,而As则被下渗水携带迁移出耕层进入地下水.由降雨输入土壤中的Cd通量均大于下渗水输出Cd的通量,局部地区As下渗通量高于雨水输入通量的5.45～13.16倍.土壤中元素的下渗比与土壤质地、pH有关.     

禹城市城乡用地结构和布局分析

统筹城乡用地、优化城乡用地结构和布局,既是节约和集约用地的重要途径,又是统筹城乡发展的客观需要。通过分析禹城市城乡用地结构和布局,提出优化城乡用地结构和布局的建议和对策,从而为制定合理的土地利用总体规划提供基本的依据。     

地质空间信息元数据服务模式的实现

地质空间信息元数据为解决地质空间信息的共享提供了有效的手段。从地质空间信息核心元数据的标准着手,介绍了基于分布式结点自治的地质空间信息元数据服务体系的结构,给出了元数据的服务模式的解决方案。其中重点阐述了元数据的管理、发布与服务功能。将该元数据服务模式应用于国家地质空间信息网格平台,提供元数据应用的服务示范,取得了良好的信息共享应用效果。     

中国数字地质调查系统的基本构架 及其核心技术的实现

数字地质调查系统是贯穿整个地质矿产资源调查全过程的软件,涵盖地质矿产调查、矿产资源勘查、矿体模拟、品住估计、资源量估算、矿山开采系统优化等内容。考虑数字地质调查系统的应用技术层面,从数据“层”模型、数据流“池”技术、不同阶段数据模型继承技术、数据互操作技术等几个方面讨论了核心技术及其实现,通过基于无缝一体化技术的数据采集、管理、综合处理与成果表达,在实体或矿块的矿床建模技术与品住估计、储量估算等方面展现了全地质调查过程的数字化,不但为地质人员应用高新技术降低了门坎,而且极大地提高了研究精度和效率,丰富了成果的表现形式和服务形式。随着数字地质调查系统的完善和应用水平的提高,数字地质调查系统将成为中国地质调查的主流软件体系。     

山西保德—静乐地区新近纪地层时代讨论

通过对山西保德-静乐地区新近纪地层的野外地质调查和实测剖面,对分布于该区的新近纪地层进行了详细的研究和划分,获得了新的ESR和古地磁测年数据,并结合生物地层序列确定了该区新近系地层的顺序为：新近系上新统静乐组（N2j）、新近系中新统上部保德组（N1^26）和中新统下部芦子沟组（N1^1l）。