巩乃斯避暑旅游气象指数分析与评价

根据巩乃斯、和静站2009—2018年6—8月的逐日平均气温、最高气温、相对湿度、风速等气象观测资料,采用对比分析、通径分析及模糊综合评价等方法对巩乃斯地区夏季避暑旅游气象资源优势进行分析和评价.结果表明:巩乃斯夏季气候凉爽、湿度适宜、风速不大,人体感觉凉爽、舒适,适合避暑旅行.人体舒适度与空气温度呈显著正相关,与相对...     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.     

Origin and Evolution of Aquitard Porewater in the Western Coastal Plain of Bohai Bay,China

High‐salinity paleowater from low‐permeability aquitards in coastal areas can be a major threat to groundwater resources; however, such water has rarely been studied. The chemical and isotopic compositions of porewater extracted from a 200‐m‐thick Quaternary sedimentary sequence in the western coastal plain of Bohai Bay, China, were analyzed to investigate the salinity origin and chemical evolution of porewater in aquitards. Porewater samples derived at depths shallower than 32 m are characterized by Cl‐Na type saline water (total dissolved solids [TDS], 10.9–84.3 g/L), whereas those at depths greater than 32 m comprise Cl·SO₄‐Na type brackish water (TDS, 2.2–6.3 g/L). Saline porewater is interpreted as evaporated seawater prior to halite saturation, as evidenced by Cl‐Br relationships. Although substantial dilution of saline porewater with meteoric water is supported by a wider Cl^? range and δ²H‐δ¹⁸O covariance, the original marine waters were not completely flushed out. The deeper brackish porewater is determined to be a mixture of fresher porewater and brine groundwater and had a component of old brine of less than 10%, as indicated by a mixing model defined using δ²H and Cl^? tracers. Porewater δ²H‐δ¹⁸O relationships and negative deuterium excess ranging from ?25.9‰ to ?2.9‰ indicate the existence of an arid climate since Late Pleistocene in Tianjin Plain. The aquitard porewaters were chemically modified through water‐rock interactions due to the long residence time.     

生物气CO2还原途径中碳同位素分馏作用研究及应用

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。     

The nonlinear time lag multivariable grey prediction model based on interval grey numbers and its application

Natural Hazards - The linear relationship of the original grey prediction model is too single, and the original grey prediction model does not consider the time delay of the effect of the current...     

2005年1月18日乳山ML4.3地震序列

对2005年1月18日乳山ML4.3地震序列特征及烈度分布进行了介绍, 认为乳山ML4.3地震序列是一次能量衰减较快、频度起伏衰减的主-余型地震序列, 序列本身不具有明显的前兆意义.     

湘江竹埠港段河床沉积物元素地球化学特征

湘江是我国重金属污染最严重的河流之一。本次工作利用X射线荧光(XRF)和电感耦合等离子质谱(ICP-MS)分析技术,对湘江竹埠港沉积物进行主量和微量元素分析。结果表明沉积物主量元素含量变化相对稳定,富集MnO、P2O5、Fe2O3、Al2O3,亏损CaO、Na2O。微量元素含量变化较大,亏损Ba、Sc、Mn、Sr而富集其他微量元素。对主量元素和稀土元素进行了分析,表明沉积物物源主要是由上游花岗岩风化所提供。对沉积物进行因子分析和相关性分析,表明沉积物源主要以陆源碎屑为主,并有磷灰石和软锰矿等自生副矿物,Ni、Pb、Cu可能来自人为污染源。地累积指数表明Ba为清洁无污染,重金属V、Cr、Co、Ni、Th、U为轻度污染,重金属Cu、Pb、Zn为偏中度污染,Mn为中度污染,Sc为偏重度污染。其中重金属Cr、Ni、Cu、Pb、Zn、Mn、Sc污染应引起关注。     

农田土壤湿度的人工神经网络预测诊断系统

采用人工神经网络（ＡＮＮ）方法，研制了农田土壤湿度预测，诊断分析系统，该系统根据不同的土壤湿度特点和影响因子，可自动提供时间序列拓展的人工神经网络预测模型和人工神经网络的混合预测模型进行土壤湿度的动态预测。并提供不同降水量的土壤湿水分渗透深度诊断分析，系统采用中文菜单显示的人机对话方式操作，使具有准动力学特性，多种可调参数和网络结构的ＡＮＮ方法变得简便易于操作。实际使用表明，该系统对土壤湿度的预测     

隧道支护结构荷载作用的随机反演

提出荷载－结构模式进行随机反分析方法，从隧道支护结构变形反算对应的荷载作用，可反推围岩抗力系数和覆土荷载的分布情况，以及作用于支护结构上各部位的外荷载。提出了以实测位移为基础的样条函数插值．以插值位移补充大量的实测值，满足了反分析所需众多的已知位移数。通过一施工实例对该方法的可行性进行了检验。     

渤海盆地现代构造应力场与强震活动

渤海位于北华北新生代裂陷盆地的东部,是一个晚第四纪形成的内陆海盆. 渤海盆地活动断裂发育,地震活动强烈,交会于渤海中部的NE向营口——潍坊断裂带北段、庙西北——黄河口——临邑断裂带及NW向北京——蓬莱断裂带是主要的活动构造带,将海区分成4个次级新构造区,成为现代应力场作用的构造基础. 综合研究38个震源机制解和75个井区应力场等资料,以及构造应力场二维数值模拟计算结果表明,渤海及其邻区现代构造应力场的压应力方向为NE60～90,张应力为SN——NW30;以水平和近水平应力作用为主;不同构造区主应力方向存在一定的差异. 现今渤海地区地壳发育以NNE——NE和NW——WNW走向的共轭剪切破裂为特征,是控制地震活动的主要构造.