温和水热法制备MZr2(PO4)3(M=Na,K,Rb)

在温和的水热条件下分别制备出纯净的磷酸锆钠 [NaZr2 (PO4) 3 ]、磷酸锆钾 [KZr2 (PO4) 3 ]和磷酸锆铷 [RbZr2 (PO4) 3 ]。研究了原料配比、矿化剂 (氟离子 )、反应时间和温度等水热晶化条件对产物生成的影响。发现在较宽的温和水热条件下可以制得这三种磷酸锆盐 ;随着碱金属离子的增大 ,产物的生成条件越来越窄 ;最佳制备条件是 :F- ZrO2 =2、P2 O5 ZrO2 =3 (均为摩尔比 )、[ZrOCl2 ]=0 6mol L、反应温度 1 5 0℃、反应时间 2天。用水热法没有制备出同一系列磷酸锆盐中的磷酸锆锂 [LiZr2 (PO4) 3 ]和磷酸锆铯 [CsZr2 (PO4) 3 ]。采用XRD、SEM、IR、Raman和XPS等现代物化仪器对产物的结构与物相纯度进行了测定与表征     

氢氧化镁沉淀热力学、动力学及控制

分析了氢氧化镁絮状沉淀生成的热力学、动力学 ,提出了使其结晶的控制措施     

南岳衡山自然景观资源及其开发利用探讨

南岳衡山是中国南方唯一的一座五岳名山，也是中国历史上南方最大的文化、宗教活动中心，素享“五岳独秀”、“文明奥区”、“宗教圣地”、“抗战名山”等盛名，是中国第一批国家级风景名胜区，具有独特的景观美学价值、丰富的科学艺术内容、多彩的景观景目。经数千年人类文明洗礼，又使其积淀了深厚的历史文化，衡山的景观资源开发潜力巨大，但必须坚持可持续发展战略，开发与保护并重，加强规划，合理布局，进一步优化自然生态环境，推出南岳特色生态旅游精品系列，以满足当代旅游者回归自然、绿色消费的心理需求。     

Salt tolerance of Microcoleus vaginatus Gom., a cyanobacterium isolated from desert algal crust, was enhanced by exogenous carbohydrates

Microcoleus vaginatus isolated from a desert algal crust of Shapotou was cultured in BG-11 medium containing 0.2 mol l⁻¹ NaCl or 0.2 mol l⁻¹ NaCl plus 100 mg l⁻¹ sucrose, extracellular polymeric substances (EPS) or hot water-soluble polysaccharides (HWP), respectively. Photosynthetic oxygen evolution rates, photosystem II activity (Fv/Fm) and dark respiration of NaCl-stressed cells were enhanced significantly by the added sucrose or EPS under salt stress conditions (0.2 mol l⁻¹ NaCl). Compared with cells treated with salt alone, sodium contents in cells reduced significantly; the content of cellular total carbohydrate did not change, and intracellular sucrose, water-soluble sugar increased significantly following the addition of exogenous carbohydrates. Sucrose synthase (SS) activity of NaCl-stressed cells increased following the addition of sucrose, and sucrose phosphate synthase (SPS) activity of NaCl-stressed cells increased following the addition of exogenous sucrose, EPS or HWP compared with cells stressed with NaCl only. The results suggested that the extruded EPS might be re-absorbed by cells of M. vaginatus as carbon source, they could increase salt tolerance of M. vaginatus through the changes of carbohydrate metabolism and the selective uptake of sodium ions.     

USING UPLAND FOREST IN SHIMENTAI NATURE RESERVE,CHINA*

ABSTRACT. The Shimentai Nature Reserve in Yingde County, Guangdong Province, China, established recently in a subtropical upland forest area, has served for ages as an essential and customary source of livelihood for local people. Assessment of forest usage indicates heavy reliance by villagers on its diversified biotic resources. This forest dependence, associated with socioeconomic factors such as distance from village, ethnic origin, out‐migration of rural youngsters, and a local tradition of conservation, is unlikely to decline in the near future. The reserve management recognizes the need to address the livelihood issues of local people and to win local support. A pragmatic adherence to provincial and higher‐level policies that exclude forest‐tapping activities could lead to more people‐versus‐park conflicts, which would dilute fundamental conservation objectives. A more enlightened and localized approach that nurtures a synergy between limited forest use and conservation while helping to develop new income sources could furnish workable alternatives.     

高速公路下伏某煤矿采空区地质特征及注浆充填法治理研究

煤矿采空区是工程建设中不良地质条件之一，其地质特征评价和如何治理是两个关键问题。笔者结合高速公路建设中某采空区的治理实践，对这两方面进行了探索，对工程建筑中所遇各类采空区的地质特征评价及其治理方法有一定借鉴意义。     

云南兰坪北部铜多金属矿化区成矿流体流动与矿化分带——流体包裹体和稳定同位素依据

滇西兰坪盆地北部发育了一类受逆冲推覆构造控制的浅成热液Cu—Ag—Pb-Zn矿化，形成了白秧坪、富隆厂、吴底厂、麻栗坪及金满、科登涧等大-中型矿床和矿点，并存在矿化分带。文章利用这些矿化脉体的流体包裹体和热液方解石的碳氧同位素组成资料，研究成矿流体与矿化分带的关系。结果表明，成矿流体主要属于NaCl-H2O成分体系，盐度ω(NaCleq)为2％～11％，形成温度为170～300℃，形成于1．8～3．8km深度内，这些相似性说明这类矿化的发生具有相似的流体性质和沉淀机制。热液方解石在δ^13C-δ^18O图解中呈近水平线展布的型式，指示流体源自地壳浅部的地下水系统，与海相灰岩等围岩作用形成了溶解碳以[HCO3^]-为主的成矿流体，流体与岩石的相互作用可能是成矿流体沉淀的主要机理。从西到东，流体包裹体的盐度-温度由高到低变化与矿化分带和逆冲推覆构造的根带→中带→锋带相配套，显示重力驱动流动可能是主要的流体流动机制。成矿流体在不同构造部位流动的通畅及流体．岩石系统的封闭-开放程度等流体流动性质与矿化发生的强度和规模有关，兰坪北部逆冲推覆构造中带的流体通畅地流动及沉淀时处于相对开放状态，有利于该区形成较大规模的浅成热液多金属矿化。     

叶蜡石传压介质资源初步研究

分析国内叶蜡石传压介质材料供需状况，指出北京赵家台叶蜡石传压介质材料资源枯竭，虽然国内叶蜡石矿石资源丰富，但适宜作叶蜡石传压介质材料资源却极少，急需从资源和材料特性着手，加大研究力度，寻找新的接替资源。     

硬玉的差热分析和紫外荧光光谱研究

通过对缅甸硬玉的差热分析和紫外荧光光谱研究，发现不同颜色硬玉的紫外荧光谱中的617nm处的谱峰，可能是Cr引起的；对不同颜色硬玉进行的差热分析表明，其熔融温度略有不同，说明其生长环境有一定差异，而硬玉也可能是较好的耐热材料，具一定的开发潜能。