Effect of some additives on synthesis of zeolite from coal fly ash

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.     

Cross-formational hydrocarbon fluid flows in the Tertiary deltaic system of the Beaufort–Mackenzie Basin

Molecular and isotopic compositions of crude oils in the Beaufort–Mackenzie Basin confirm three genetic end-member oil groups and suggest extensive cross-formational hydrocarbon fluid flows in the Tertiary deltaic system. Inter- and intra-fractional variations in the geochemistry of the Tertiary-reservoired oils indicate that the oil source/maturity signatures were substantially masked by biomarkers that were picked up along migration pathways. Thus, many of the previously recognized “immature non-marine oils” are in fact thermally mature, probably derived from unpenetrated deeper marine source rocks. Although the effective source rock volumes have not been evaluated and their exact stratigraphic levels remain unknown, the relative timing of oil generation versus trap formation, rather than poor source quality, may be the cause of under-filled traps in the offshore area.     

Are the South and North Liaohe Groups of North China Craton different exotic terranes? Nd isotope constraints

The Liaohe Group is an important Paleoproterozoic stratigraphic unit in the northeastern part of the North China Craton and is traditionally subdivided into the North and South Liaohe Groups. Associated with both the North and South Liaohe Groups are voluminous Paleoproterozoic granitoid rocks, named the Liaoji granitoids. Different tectonic models, including terrane amalgamation, continent–arc collision and rift closure, have been proposed to interpret the tectonic setting and evolution of the North and South Liaohe Groups and associated Liaoji granitoids. At the centre of the controversy between these models is whether or not the North and South Liaohe Groups developed on the same Archean basement. Nd isotopic geochemistry of the Liaoji granitoids provides important constraints on this controversial issue. The Liaoji granitoids associated with the North and South Liaohe Groups display similar ε_Nd values, restricted to a narrow range from 0 to 2, implying that these granitoid rocks were derived from the same or a similar magma source. Moreover, the Liaoji granitoids associated with the North and South Liaohe Groups have similar Nd model ages (T_DM), ranging from 2.4 to 2.6 Ga, suggesting that the protoliths of the Liaoji granitoids associated with both groups may have formed simultaneously, and that the basement rocks underneath the Liaoji granitoids and associated North and South Liaohe Groups belong to the same continental block rather than two different blocks. Combining lithological, structural and geochronological considerations, we interpret the North and South Liaohe Groups as having developed on a single late Archean basement that underwent Paleoproterozoic rifting associated with the intrusion of the Liaoji granitoids and the formation of the Liaohe Group, and closed upon itself in the Paleoproterozoic.     

Weathering and climate change since l820 AD in Hoh Xil, Qinghai-Xizang Plateau, China——Evidence from element geochemistry of lake sediments of Gulug Co Lake

Element geochemistry of lake sediments has been widely used to detect climate change because element composition and ratios can reflect the weathering degree in the source area. Given the dement composition of lake sediments from Gulug Co Lake, Hoh Xil, Qing- hai-Xizang Plateau, chemical index of alteration （CIA）, index of composition variability （ICV） and other element ratios have been used to establish the weathering sequence of this area since 1820 AD. The weathering is so weak that the element composition change is more sensitive to climate change and autochthonous processes. From 1820 to 1984 AD, there were two drier periods with a wetter interval from 1870 to 1945 AD. After 1984 the weather showed a tendency of becoming wet.     

单频GPS接收机天线扼流圈的研制与测试

讨论了多路径效应对GPS共视比对的影响及削弱其影响的方法。结合综合原子时项目的需求,研制了适用于单频GPS接收机的天线扼流圈,并用零基线比对方法进行了测试。结果表明,研制的天线扼流圈可有效地削弱多路径效应的影响,并可明显地改善单频GPS接收机NTSCGPS-1的抗干扰能力。     

PDC钻头切削齿破岩载荷规律的分析

对PDC钻头冠部形状及不同的布齿密度和切削齿在不同的磨损状态下对PDC钻头切削齿受力的影响进行了分析；用相邻的3个切削齿之间的关系(不同的切削齿与切削齿之间的径向距离和切削齿之间的高度差)来分析PDC钻头冠部形状和切削齿布齿密度对切削齿受力的影响，以及将切削齿的磨损状态简化成与切削齿在钻头上装配方向垂直的平面来分析切削齿磨损状态对切削齿受力的影响。     

自重湿陷性黄土地区桩基设计探讨

根据自重湿陷性黄土的特点、《湿陷性黄土地区建筑规范》（GB50025—2004）和《建筑桩基技术规范》（JGJ94—94）中关于桩基设计的对比分析，通过自重湿陷性黄土场地工程实例分析计算，依据负摩擦产生的机理——中性点理论，论述了自重湿陷性黄土场地中桩基设计应考虑中性点，而不应全部计入负摩阻的观点。     

我国入境旅游和经济增长关系分析

文章分析了入境旅游发展的区域差异，并用Granger因果检验来考察入境旅游和各区域经济增长之间是否存在相应的因果关系，Granger因果检验的结果表明在东部地区，入境旅游和经济增长存在单向因果关系。东部地区的入境旅游对区域的经济增长产生显著影响。但是全国和中西部地区的入境旅游与经济增长之间不存在显著的因果关系。类似地，东部地区入境旅游增长是其第三产业增长的Granger原因。但是全国和中西部地区的入境旅游和相应区域第三产业的增长并不存在显著的因果关系。在区域层面上。只有少数区域支持入境旅游是区域GDP增长的Granger原因，它们是东部地区的北京、广东、上海、天津、福建、江苏、浙江、海南和广西；中部地区的黑龙江和湖南以及西部地区的云南和陕西。在这些省区市。入境旅游对区域经济增长产生显著的影响。但总体而言，入境旅游在我国还没有足够的发展。     

用于湿地气候效应模拟的三江平原下垫面数据获取

三江平原是我国沼泽湿地的重要分布区。在20世纪的后50 a中,三江平原在经过几次大规模的开荒后,其下垫面发生了明显的阶段性变化,湿地大面积消失,农田面积不断增加。为了认识20世纪下半叶不同时期三江平原湿地的气候效应,拟采用第三代区域气候模式(RegCM3)来开展研究。而目前被广泛用于RegCM3的GL-CC数据,所反映的研究区下垫面几乎不存在沼泽湿地,这与事实严重不符,所以必须获取三江平原有沼泽湿地存在的真实的下垫面数据,才能得到可靠的湿地气候效应的模拟结果。分别选择了4期(1954年、1985年、1996年和2000年)有阶段代表性的航片、TM影像数据为主要数据源,利用ERDAS8.7和Arcview3.2等软件,首先得到4期研究区的土地利用数据,然后通过土地利用数据类型向模式数据类型的转换,从4期研究区土地利用数据中提取出了三江平原下垫面的模式数据。经过误差分析,认为获取的4期三江平原下垫面模式数据准确的反映出研究区几个时期的湿地下垫面实况,可以作为三江平原湿地气候效应模拟的基础数据。     

应用ISSR标记分析三江平原狭叶甜茅不同种群的遗传多样性

以三江平原狭叶甜茅(Glyceriaspiculosa)为研究对象,选取3个不同群落类型:狭叶甜茅优势种群落、狭叶甜茅和毛苔草(Carexlasiocarpa)为共建种的群落以及狭叶甜茅为主要伴生种的群落,共45个材料进行了ISSR分子标记分析。结果从41个引物中筛选出7个有效引物,扩增出80条清晰条带,平均每个引物扩增了11.4条带,其中70个位点是多态的,总的多态位点比率为87.5%,表明被测材料间ISSR标记多态性较高。利用Popgen(version1.32)软件分析了扩增结果,并得到了狭叶甜茅不同群落类型的遗传距离、遗传一致度、Nei和Shannon信息指数等遗传特征。结果表明,对于一个物种来说,当地理距离太近不能成为影响其遗传多样性水平的因素时,其构成的种群在群落中的地位将是影响遗传多样性水平的主要因素之一。