汶川8级地震前后陕西地形变异常特征分析

分析了汶川8.0级地震前后的关中垂直形变及陕西地区地倾斜变化特征。结果表明：震前,跨断层垂直形变表现出阶段性变化特征,南大同、大塬、涧峪口、清河口、口镇等场地的垂直形变出现了明显的趋势转折、加速变化。汉中、宝鸡、乾县、西安台的地倾斜潮汐因子γ存在3个月左右异常变化。     

大气电场仪观测结果的修订

大气电场仪是测量大气电场的重要设备,其测量结果受多种因素影响.通过一系列对比试验表明:电场仪采用探头正置或倒置结构时的观测结果基本一致,倒置结构有利于避免雨水带来的影响.不同的安装环境对测量结果的影响很大,为了消除这种影响,提出了对观测数据进行地面修订的方法,得到不同天气条件下的修订系数.所得结果对于实现多站电场仪联网观测的数据一致性有重要实际意义.     

EGNOS对流层延迟改正模型及其精度分析

对流层延迟是GPS定位中一个主要的误差源,目前处理对流层延迟的主要方法是通过模型法、差分法等;当基线的距离较短时,基线两端气象条件基本相同差分法可以很好地修正对流层延迟误差,当基线的距离很长时,由于基线两端的气象参数差别较大差分法不能很好地消除对流层误差,模型法却能很好地消除对流层误差.对EGNOS模型进行了详细的介绍...     

Single-crystal EPR and DFT studies of a [BO<Subscript>4</Subscript>]<Superscript>0</Superscript> center in datolite: electronic structure,formation mechanism and implications

A natural datolite CaBSiO₄(OH) (Bergen Hill, NJ, USA), before and after gamma-ray irradiation (up to ~70 kGy), has been investigated by single-crystal and powder electron paramagnetic resonance (EPR) spectroscopy from 10 to 295 K. EPR spectra of gamma-ray-irradiated datolite show the presence of a boron-associated oxygen hole center (BOHC) and an atomic hydrogen center (H⁰), both of which grow with increasing radiation dose. The principal g and A(¹¹B) values of the BOHC at 10 K are: g ₁ = 2.04817(3), g ₂ = 2.01179(2), g ₃ = 2.00310(2), A ₁ = −0.401(7) mT, A ₂ = −0.906(2) mT, A ₃ = −0.985(2) mT, with the orientations of the g ₁ and A ₁ axes approximately along the B–OH bond direction. These experimental results suggest that the BOHC represents hole trapping on the hydroxyl oxygen atom after the removal of the proton (i.e. a [BO₄]⁰ center): via a reaction O₃BOH → O₃BO^· + H⁰, where · denotes the unpaired electron. Density functional theory (DFT) calculations (CRYSTAL06, B3PW, all-electron basis sets, and 1 × 2 × 2 supercell) support the proposed structural model and yield the following ¹¹B hyperfine coupling constants: A ₁ = −0.429 mT, A ₂ = −0.901 mT, A ₃ = −0.954 mT, in excellent agreement with the experimental results. The [BO₄]⁰ center undergoes the onset of thermal decay at ~200°C and is completely annealed out at 375°C but can be restored readily by gamma-ray irradiation. Isothermal annealing experiments show that the [BO₄]⁰ center exhibits a second-order thermal decay with an activation energy of 0.96 eV. The confirmation of the [BO₄]⁰ center (and its formation from the O₃BOH precursor) in datolite has implications for not only understanding of BOHCs in alkali borosilicate glasses but also their applications to nuclear waste disposal.     

优化EWT-NLM的自适应GNSS高程时间序列降噪方法

提出一种引入样本熵（SE）优化的经验小波变换（EWT）结合非局部均值（NLM）滤波的组合自适应降噪方法。该方法使用SE确定全部经验模态分量中低频有效信号界限,叠加其余中高频分量后进行NLM滤波处理,之后重构滤波信号与有效信号为最终降噪信号,从而达到滤除高频噪声的目的。模拟数据与实测数据的实验结果表明,优化的EWT-NLM方法整体优于EMD、EWT方法,RMSE分别降低13.41%/10.63%（实测数据/模拟数据）、7.13%/5.78%,信噪比分别提升22.03%/22.54%、9.72%/7.42%。     

P507萃淋树脂分离-电感耦合等离子体质谱法快速测定化探样品中的银

应用电感耦合等离子体质谱法(ICP-MS)测定化探样品中低含量的Ag时,常受到Zr、Nb氧化物离子91Zr16O和93Nb16O的严重干扰,使得低含量Ag结果误差较大.本文报道了一个简易的测定化探样品中Ag的新方法,将用于ICP-MS测定常规微量元素的溶液通过P507萃淋树脂交换柱,Zr、Nb等干扰元素被P507树脂强烈吸附,而Ag和内标元素Rh通过交换柱,实现了化探样品中待测元素Ag和内标元素Rh与干扰元素Zr、Nb的有效分离,Ag和Rh的回收率达到95％以上,检出限为0.05 μg/g,标准样品的测定结果准确可靠.该方法在测定常规微量元素的基础上,不需要另外称样及处理样品,相对于其他方法,流程简单、快速,适合化探样品Ag的测定,且树脂经氢氟酸处理后可重复使用,降低了实验成本.     

延边天宝山多金属矿田辉钼矿Re-Os同位素 年龄及其地质意义

延边天宝山为一大型中高温热液多金属(铅,锌,铜,钼等)矿田,是由新兴铅锌、立山铅锌铜和东风铅锌铜钼3个矿床所组成.文章在矿田地质特征研究的基础上,进行了辉钼矿Re-Os同位素体系定年研究,得到结果w(Re)为0.353～9.306 μg/g,模式年龄为174.7～200.3 Ma,加权平均值年龄为(194.6±3.9) Ma,等时线年龄为(196.6±2.5) Ma(MSWD=0.94,n=9),表明天宝山多金属矿田为早侏罗世岩浆作用及相关流体活动的产物,形成于华北板块和西伯利亚板块碰撞拼合后伸展环境,初步认为成矿物质来源主要为壳源.结合区域上已有的高精度年代学数据,将吉林省中东部山区钼成矿作用划分为2期:早侏罗世(196.6～186Ma)和中侏罗世(176.9～166.9Ma),且以中侏罗世钼矿化最为发育.     

青城子层状/脉状铅锌矿床稀土元素地球化学特征及地质意义

位处华北板块北缘东段的辽吉裂谷带内发育有多处中、小型铅锌矿床,其中,同时发育层状和脉状铅锌矿的青城子矿床是典型的代表。为了探讨青城子层状铅锌矿和脉状铅锌矿矿质来源及成因的异同及其所代表的地质意义,利用ICP-MS对层状铅锌矿及其围岩、脉状铅锌矿及其围岩和后期穿矿脉岩进行了稀土元素测试。结果表明,所有样品均具有轻稀土元素（LREE）富集和明显分异的特点。层状铅锌矿及其围岩具有Eu正异常和较弱的Ce负异常,表明其成矿物质均来自上升的深部热水流体与海水的混合热液,在高温、还原流体和海水的参与下成矿。脉状铅锌矿及其围岩稀土元素配分模式与层状铅锌矿及其围岩相似,但其Eu为负异常和Ce异常不明显,部分样品出现较弱的Ce正异常,对比分析穿矿脉岩明显的Eu负异常和Ce正异常以及二者稀土元素总量稍大于层状铅锌矿的特点,文章认为青城子层状矿石为沉积成矿,成矿热液为深部热水流体与海水的混合热液,但后期受到岩浆侵入叠加改造的影响而在局部形成脉状铅锌矿体,引起了Eu负异常和局部Ce正异常的出现以及稀土元素总量的增加。     

陕北盐盆马五6亚期构造分异对成钾区位的控制

本文以16口钻井资料为基础,通过井震联合标定解释,获取累计5595km二维地震剖面的速度等特征物性参数,利用变速成图方法,初步编制出陕北奥陶纪盐盆主要含钾层段——马家沟组五段六亚段盐系等厚图,并进行相应的构造分异解析。提出在陕北盐盆奥陶系马家沟组五段六亚段沉积期,盆底总体表现为"两坳夹一隆"的构造样式,其中厚度大于150m的成盐凹陷主要有5个。西部盐坳的发现、东二盐凹被进一步分解为东、西2个次级盐洼、以及"两坳夹一隆"构造样式的提出,系本次研究取得的新进展和认识,表明陕北盐盆并非是一个"平底锅",其内部存在多个受同沉积断裂控制的、相对活动的次级盐凹,这些次级盐凹将有利于富钾卤水的汇聚,为可能的大规模海相钾盐成矿提供了足够的可容空间和有利的构造区位。     

A Review of the Tetrapod Track Record in China,with Special Reference to Type Ichnospecies:Implications for Ichnotaxonomy and Paleobiology

<正>"Splitting" and "lumping" are perpetual problems in vertebrate,especially dinosaur, ichnotaxonomy.Chinese dinosaur ichnotaxonomy,which began in 1940,provides a series of interesting case studies,highlighting the dual problems of historical and dubious ichnotaxonomy. Chinese Mesozoic tetrapod track types have been placed into 63 ichnospecies(one Triassic,28 Jurassic,and 34 Cretaceous),exclusive of other,non-type ichnospecies or ichnotaxa identified from China.Fifty-two(～83%) of these 63 tetrapod ichnospecies were placed in monospecific ichnogenera. At the ichnogenus level,we prune—either by recognizing nomina dubia or by synonymy—17 from the list of 53 dinosaurian ichnogenera(a 32%reduction),leaving 36 ichnotaxa that we consider valid. Most of the cuts affect Jurassic theropod ichnotaxa,which are reduced from 23 to only nine because most ichnogenera are subjective junior synonyms of Grallator and Eubrontes.Fewer Chinese Cretaceous ichnotaxa(only six of 21 ichnogenera) are obvious nomina dubia or subjective synonyms, suggesting greater east Asian endemism during this time.Because ichnospecies differences are subtle, we provisionally retain ichnospecies as valid pending detailed comparative analyses of congeneric ichnospecies.This synthesis is long overdue and is necessary to address problems of historical and provincial ichnotaxonomy,which severely hamper comparisons of tetrapod ichnofaunas in space and time.