Influence of redox conditions on iodide migration through a deep clay formation (Toarcian argillaceous rock,Tournemire, France)

With a half-life of 15.7 Ma, a high mobility and the potential to accumulate in the biosphere, ¹²⁹I is considered, in safety assessment calculations for radioactive waste repositories, to be one of the main contributors to the radiological dose. Several authors have reported that, at low concentration, I⁻ is weakly retained on argillaceous rocks. This process is not yet well-understood and different hypotheses have been put forward as to whether reactive phases or experimental artifacts (e.g. pyrite oxidation) could be the reason for the retention of I⁻ observed at low concentration. The aim of this study was to investigate the effect on I⁻ mobility of (i) the redox conditions and (ii) the amount of pyrite and natural organic matter (NOM) contents of the rock. These questions were addressed by performing batch sorption, through-diffusion and out-diffusion experiments on rock samples of Toarcian argillaceous rock from Tournemire (Aveyron, France). One of the challenges faced during this study was to distinguish actual transport properties from experimental artifacts. A especially elaborate experimental set-up allowed limiting the (i) oxidation of both argillaceous rock and I⁻, and (ii) carbonate precipitation. A comparison of the batch sorption results obtained for two Toarcian clay specimens, that differed in their amount of pyrite and NOM, allowed relating I⁻ sorption to pyrite oxidation. However, no evidence was found to associate the I⁻ behavior to the NOM amounts. While the through-diffusion experiments showed a very slight sorption (distribution ratio (R_d) = 0.016 mL g⁻¹) for the lowest I⁻ concentration under oxic conditions, the out-diffusion tests performed after the through-diffusion experiments on the same cells showed significant sorption under both oxic and anoxic conditions, resulting in R_d ranging from 0.02 mL g⁻¹ to 1.25 mL g⁻¹. The range of R_d values was higher for the upstream reservoir under oxic conditions. The discrepancies observed between the through-diffusion and the out-diffusion experiments suggest a kinetic control of the I⁻ uptake by argillaceous rocks under oxic and anoxic conditions.     

Formation and characteristics of post-earthquake debris flow: a case study from Wenjia gully in Mianzhu, Sichuan, SW China

During the three flood seasons following the Wenchuan earthquake in 2008, two catastrophic groups of debris flow events occurred in the earthquake-affected area: the 2008-9-24 debris flow events, which had a serious impact on rebuilding; and the 2010-8-13/14 debris flow events, which destroyed much of the progress made in rebuilding. The Wenjia gully is a typical post-earthquake debris flow gully and at least five debris flows have occurred there. As far as the 2010-8-13 debris flow is concerned, the deposits of the Wenjia gully debris flow reached a volume of 3.1 × 10⁶ m³ in volume and hundreds of newly built houses were buried. This study took the Wenjia gully debris flow as an example and discussed the formation and characteristics of post-earthquake debris flow on the basis of field investigations and a remote sensing interpretation. The conclusions drawn from the investigation and analysis were as follows: (1) Post-earthquake debris flows were a joint result of both the earthquake and heavy rainfall. (2) Gully incision and loose material provision are key processes in the initiation and occurrence of debris flows and a cycle can be presented as the following process: runoff—erosion—collapse—engulfment—debris flow—further erosion—further collapse—further engulfment—debris flow enlargement. (3) The amount of rainfall that triggered debris flows from the Wenjia gully was significantly less than the average daily rainfall, while the intraday rainfall threshold decreased by at least 23.3%. (4) The occurrence mechanism of Wenjia gully debris flow was an erosion type and there was a positive relationship between debris flow magnitude and rainfall, which fitted an exponential model. (5) There were five representative characteristics of Wenjia gully debris flow: the long duration of the occurring process; the long distance of deposition chain conversion during the process of damage; magnification in the scale of debris flow; and the high frequency of debris flow events.     

Experimental and numerical analysis on the responses of slope under rainfall

Rainfall is an important factor to trigger the slope failure such as landslides and debris flows. First, the relationship between rainfall duration with the initiation of debris flow and rainfall intensity was mainly studied by the series tests in a box model. Then, the rainfall induced responses of slopes and the initiation of slope failure were simulated by using the software FLAC2D based on the soil parameters in Weijia Gully, Beichuan County, Sichuan Province. The effects of the slope angle, rainfall intensity, soil parameters on the development of the stress, and pore pressure in the soil of the slope were analyzed. It indicates that largest displacements in the slope are mainly located near the toe. With the increase of the rainfall intensity, the effective stress in the slope decreases and the displacement increases.     

Effects of climatic changes and anthropogenic activities on lake eutrophication in different ecoregions

Climatic changes and anthropogenic activities could affect nutrients?? status significantly in the different lake ecosystems. Nutrients in Lake Hulun and Lake Taihu, two largest shallow cyanobacteria-blooming lakes in northern and southern China, respectively, were at eutrophicated levels in 2009. The concentrations of total nitrogen and total phosphorus were 3.346 and 2.250?mg/L as well as 0.435 and 0.062?mg/L, respectively, in these two lakes with different causes of eutrophication. For Lake Hulun, it was the decreased amount of water as a result of the warming and drying climate that accounted for the abrupt increase of total nitrogen and total phosphorus levels through inspissation. In addition, the icebound effects, no outflows, low nutrients sequestration by the sediment and the reduction of aquatic productivity made the situation even worse. On the contrary, high population densities, the rapid development of agriculture and industry as well as urbanization have increased the nitrogen and phosphorus loads on Lake Taihu. Therefore, higher criteria of total nitrogen and total phosphorus should be applied in Lake Hulun given the difficulties in controlling climatic changes while much more rigorous standards should be established for Lake Taihu since the anthropogenic impacts on nutrient status are relatively easy to control.     

Semivolatile organic compounds removal and health risk reduction in drinking water treatment biofilters applying different backwashing strategies

This study aimed to investigate the removal of 24 semivolatile organic compounds in Yangtze River (China) source water treated by six biofilters using different backwashing methods. Health risks induced by the pollutants in the influent and effluent water were also assessed based on the chemical detections. Comparatively, the biofilter backwashed with both air (15?m/h, 3?min) and water (8?m/h, 5?min) was most efficient in removing semivolatile organic compounds and reducing health risk. PCR-denatured gradient gel electrophoresis showed that backwashing alterations posed considerable influences on microbial community structure in the six biofilters. About 72.4?% of di-n-butyl phthalate and 81.8?% of bis(2-ethylhexyl)phthalate (two main semivolatile organic compounds in the river water) were removed under the optimal backwashing conditions. However, in the effluent of each biofilter, non-carcinogenetic risks of 2,6-dinitrotoluene and bis[2-ethylhexyl]phthalate and carcinogenetic risks of dibenz[a,h]anthracene and benzo[a]pyrene did not reach safety levels, revealing that these pollutants in the source water deserve more public health concerns. This study might serve as a basis for biofiltration process optimization and also as a benchmark for the authorities to reduce the health risk induced by exposure to the hazardous pollutants.     

Comparisons of u ‐, g ‐, r ‐, i ‐, and z ‐band luminosity distributions between galaxy members of compact groups and isolated galaxies

To investigate the environmental dependence of u ‐, g ‐, r ‐, i ‐, and z ‐band luminosities, we perform comparative studies of luminosity distributions between galaxy members of compact groups (CGs) and isolated galaxies. It is found that for the r, i, and z bands isolated galaxies have a higher proportion of faint galaxies and a lower proportion of luminous galaxies than galaxy members of CGs, but for the u band an opposite trend is observed. The correlation between the g ‐band luminosity and the environment has different trends in different luminosity regions (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Radio Variability of First 3-Month Fermi Blazars at 5 GHz: Affected by Interstellar Scintillation?

Blazars from the first-three-months Fermi-AGN list were observed with the Urumqi 25-m radio telescope at 5 GHz in IDV (Intra-Day Variability) mode and inter-month observation mode. A significant correlation between the flux density at 5 GHz and the γ-ray intensity for the Fermi-LAT detected blazars is seen. There is a higher IDV detection rate in Fermi detected blazars than those reported for other samples. Stronger variability appears at lower galactic latitudes; IDV appears to be stronger in weaker sources, indicating that the variability is affected by interstellar scintillation.     

The Correlation between the Magnetic and Velocity Fields on the Full Solar Disk

A possible correlation between the magnetic and velocity fields has been analyzed based on the SOHO/MDI magnetograms and Dopplergrams. It is found that the observed large-scale weak magnetic field (weaker than 50 G (gauss)) is correlated with the velocity statistically. The curves of u⋅b with latitude, where u and b are the velocity and magnetic fields in a rectangular region (±15^○ in longitude, ±45^○ in latitude) on the Sun, show the same patterns in the years 2000, 2004, and 2007. The patterns indicate that u and b are positively correlated near the equator but are anti-correlated at the middle latitudes. For a strong magnetic field between 50 G and 3000 G, the curves of u⋅b with latitude show the same tendencies at the middle latitudes. Near the equator, however, the slope of the curve is positive in 2000 and is negative in 2004 and 2007. In addition, we give an estimation for the amplitude of the cross helicity h _χ (h_c=[`(u·b)]h_{\chi}=\overline{\mathbf{u}\cdot\mathbf{b}}) inferred from the MDI data, which is of the order of 10³ G m s⁻¹ near the center of the solar disk.     

Correlation Analyses Between the Characteristic Times of Gradual Solar Energetic Particle Events and the Properties of Associated Coronal Mass Ejections

It is generally believed that gradual solar energetic particles (SEPs) are accelerated by shocks associated with coronal mass ejections (CMEs). Using an ice-cream cone model, the radial speed and angular width of 95 CMEs associated with SEP events during 1998 – 2002 are calculated from SOHO/LASCO observations. Then, we investigate the relationships between the kinematic properties of these CMEs and the characteristic times of the intensity-time profile of their accompanied SEP events observed at 1 AU. These characteristic times of SEP are i) the onset time from the accompanying CME eruption at the Sun to the SEP arrival at 1 AU, ii) the rise time from the SEP onset to the time when the SEP intensity is one-half of peak intensity, and iii) the duration over which the SEP intensity is within a factor of two of the peak intensity. It is found that the onset time has neither significant correlation with the radial speed nor with the angular width of the accompanying CME. For events that are poorly connected to the Earth, the SEP rise time and duration have no significant correlation with the radial speed and angular width of the associated CMEs. However, for events that are magnetically well connected to the Earth, the SEP rise time and duration have significantly positive correlations with the radial speed and angular width of the associated CMEs. This indicates that a CME event with wider angular width and higher speed may more easily drive a strong and wide shock near to the Earth-connected interplanetary magnetic field lines, may trap and accelerate particles for a longer time, and may lead to longer rise time and duration of the ensuing SEP event.