Arctic haze: Perturbation to the radiation field

Summary A model of the polluted arctic troposphere is constructed to estimate the magnitude and seasonal variation of the climate forcing function of arctic haze. Using a pill-box bathtub model for the Arctic and envisioning it to be filled with pollution from industrial sources in Eurasia, we estimate that maximum climate perturbation from arctic contamination occurs in the spring months. The major perturbation to the radiation budget is a lowering of the albedo (heating) of the earth-atmosphere system around the vernal equinox and is due to a trace amount (about 5% by mass) of black carbon associated with the removal-resistant submicron mode of aerosols. The black carbon over the reflecting polar ice/snow introduces a heating of about 1.5 degree per day into the haze layer.With 8 Figures     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

Interplanetary acceleration of energetic particles at 1 and 5 AU

Energetic particle (0.1 to 100 MeV protons) acceleration is studied by using high resolution interplanetary magnetic field and plasma measurements at 1 AU (HEOS-2) and at 5 AU (Pioneer 10). Energy changes of a particle population are followed by computing test particle trajectories and the energy changes through the particle interaction with the time varying magnetic field. The results show that considerable particle acceleration takes place throughout the interplanetary medium, both in the corotating interaction regions (CIR) (5 AU), and in quiet regions (1 AU). Although shocks may contribute to acceleration we suggest statistical acceleration within the CIRs is sufficient to explain most energetic particle observations (e.g., McDonaldet al., 1975; Barnes and Simpson, 1976).The first and second order statistical acceleration coefficients which include transit time damping and Alfvén resonance interactions, are found to be well represented byD _T 8.5×10^–6 T ^0.5 MeV s^–1 andD _TT 4×10^–6 T ^1.5 MeV² s^–1 at 5 AU.By comparison, Fisk's estimates (1976), based on quasi-linear theory for transit-time damping, gaveD _TT 5×10^–7 T MeV² s^–1 at 1 AU.     

1786年康定地震形变特征的初步研究

本文对鲜水河断裂带南东段,康定断裂地震的形变带进行了分析。认为,地震形变带主要由发育于地形斜坡上的线性坡中槽或垄岗组成。形变带具分段特点,单条长850—1500米,呈右阶“斜列式”展布,中段(极震区)一带为现状型。其中的破裂面具正断兼扭动特点。空间特征上,坡中槽一侧的交替上升变化是依次、轮换出现的,它是地震断层运动屈曲作用(Fault buckling)导致地表变形的反映。这种形变现象与该带北西段(炉霍段)走滑型地震的形变带相比有明显的差异,也表明鲜水河断裂带北西、南东两段的地震破裂方式是不尽相同的,它为同一走滑带不同地段运动特征的差异提供了证据。     

综合利用地震多参数预测油气藏

以吉林省境内红星构造带(已发现油田)和杨柳青构造带(未发现油田)为试验区,首先利用地震地层学方法,研究间接参数特征,确定有利相带和有效圈闭,并在有效圈闭上选择了39个2×2cm时窗。在时窗内提取与地震波动力学有关的信息,即频率、振幅、频谱能量等,然后对这种信息进行统计计算,获得振幅方差等九个参数并对其进行综合分析,从已知油气藏出发,对未知圈闭油气状况进行了三级预测,指出了最有利的勘探靶区。     

Na depletion in modern adakites via melt / rock reaction within the sub-arc mantle

Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na₂O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na₂O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na₂O, SiO₂ and perhaps K₂O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.     

Distribution of cadmium, chromium, copper, lead and zinc in marine sediments in Hong Kong waters

Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory. As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization could be a concern. An erratum to this article can be found at     

The research of phosphorus of Xiangxi River nearby the Three Gorges, China

The Xiangxi River is the first middling tributary of the Changjiang River near the Three Gorges Dam. The River is subject to phosphorus pollution mainly from industrial wastewater. As the water quality of the Xiangxi River could directly influence the water quality of the Three Gorges Reservoir, the research on phosphorus levels and its change in the sediment profile of the Xiangxi River could provide useful information in the dynamic changes in the system, thereby offering options for mitigative measures. Water and sediment samples from lower reaches of Xiangxi River were collected and the different forms of phosphorus in sediments of the Xiangxi River were studied. The concentrations of total phosphorus in sediment ranged from 757.67 to 1438.54 mg/kg. Inorganic phosphorus concentrations ranged from 684.63 to 1055.58 mg/kg. Phosphorus contamination was serious in some parts of the Xiangxi River. With an average concentration of 635.17 mg/kg, calcium-bound phosphorus is the main form among different inorganic phosphorus forms. Labile phosphorus and iron/aluminum-bound phosphorus measured 3.40, 0.05and 35.28 mg/kg, respectively. The mobilization potential of phosphorus of sediments was studied through adsorption and release experiments. The equilibrium concentration of phosphorus adsorption and release was around 0.1 mg/L. The initial concentrations of phosphorus in the overlying water and the sediments have obvious effect on phosphorus mobilization potential. In addition, the release rate of phosphorus in sediment increased with water depth.     

The 1786 earthquake-triggered landslide dam and subsequent dam-break flood on the Dadu River, southwestern China — Reply

A short reply to discussion by Chanson.