Application of geostatistics and GIS technique to characterize spatial variabilities of bioavailable micronutrients in paddy soils

To understand the spatial dependency of bioavailable micronutrients in paddy soils, 134 soil samples were taken from Pinghu County, Zhejiang Province, south-east China to characterize the spatial variabilities of bioavailable Cu, Zn, Fe, and Mn. The geostatistics and geographic information system (GIS) techniques were applied. Bioavailable Zn and Mn were fitted to an exponential model with a range of 4.4 km and 2.97 km, respectively. Bioavailable Fe was fitted to the linear model with the longest range of 23.48 km. Bioavailable Cu did not show any spatial correlation with the fitted pure nugget effect model. Bioavailable Zn and Mn had strong spatial dependence due to the effects of intrinsic factors such as parent material, relief and soil types. Bioavailable Fe had moderate spatial dependence over a long distance. The spatial distribution of the four bioavailable micronutrients were significantly correlated to the soil formation factors. Human activity, such as application of fertilizer and pesticide, emission of waste gas and industrial pollution also had significant effects on the spatial distributions of the bioavailable micronutrients.     

Polygonal faulting and petroleum geological significance of Qn1 formation in the Sanzhao Sag,Songliao BasinEI北大核心CSCD

Numerous small-scaled, extensional faults occur densely in the mudstone layer of the Qingshankou 1st member (Qn1) in Songliao Basin. Its attribute and genetic mechanism are highly concerned but still controversy. The high-resolution 3D seismic datasets of a new block that covers most of the Sanzhao sag of Songliao Basin is studied., The characteristics of the profile and plane geometry of the extensional fracture system in the Sanzhao sag were depicted in detail through fine seismic interpretation using coherent technology. Based o the results, we proposed that: (1) The extensional fault system is mainly polygonal fault, which probably resulted from rupture pressure related to the episodic hydrocarbon-expulsion from the mudstone of Qn1. However, the tectonic inversion in Songliao Basin may also contribute to the formation and development of the polygonal fault system; (2) The polygonal faults were mainly formed by the end of deposition period of the Nenjiang Formation, and some experienced vertical direction propagation caused by the strong tectonic inversion at the end of deposition period of the Mingshui Formation; (3) The polygonal faults connect the Qn1 hydrocarbon source rock with the underlying Fuyang oil layer and the overlying Putaohua oil layer, and thus are important migration channels for the oil and gas accumulation; (4) Until the end of deposition period of the Nenjiang Formation, hydrocarbon generated in the Qn1 mainly migrated downward into the underlying Fuyang oil layer via the small polygonal faults rather than upwards to the Putaohua oil layer. On the contrary, by the end of deposition period of the Mingshui Formation, the oils from Qn1 source rock can migrate either downward into the Fuyang oil layer or upward into the Putaohua oil layer. It is noteworthy that the vertical propagation of the polygonal faults induced by the tectonic inversion might also damage the Fuyang accumulations formed earlier. ©, 2015, Science Press. All right reserved.     

A new family of orthonormal wavelet bases

In this contribution we introduce the concept of multiresolution analysis (MRA) and give an explanation of the relationship between MRA and orthonormal wavelet basis. The construction of the orthonormal B-spline wavelet bases is described in detail. We extend the B-splines to `non-integral order' cases and thus obtain a new family of orthonormal wavelet bases for the space L ²(R). Some good properties of the new wavelets are demonstrated. The new wavelet family gives satisfactory performances in our research projects including seismic signal compression and gravity tide data processing. Received: 19 July 1996 / Accepted: 17 November 1997     

Isotopic analyses of nitrogenous compounds from the Murchison meteorite: ammonia, amines, amino acids, and polar hydrocarbons

The combined volatile bases (ammonia, aliphatic amines, and possibly other bases), ammonia, amino acids, and polar hydrocarbons were prepared from the Murchison meteorite for isotopic analyses. The volatile bases were obtained by cryogenic transfer after acid-hydrolysis of a hot-water extract and analyzed by combined gas chromatography-mass spectrometry of pentafluoropropionyl derivatives. The aliphatic amines present in this preparation comprise a mixture that includes both primary and secondary isomers through C5 at a total concentration of > or = 100 nmoles g-1. As commonly observed for meteoritic organic compounds, almost all isomers through C5 are present, and the concentrations within homologous series decrease with increasing chain length. Ammonia was chromatographically separated from the other volatile bases and found at a concentration of 1.1-1.3 micromoles g-1 meteorite. The ammonia analyzed includes contributions from ammonium salts and the hydrolysis of extractable organic compounds, e.g., carboxamides. Stable isotope analyses showed the volatile bases to be substantially enriched in the heavier isotopes, relative to comparable terrestrial compounds delta D < or = +1221%; delta 13C = +22%; delta 15N = +93%). Ammonia, per se, was found to have a somewhat lower delta 15N value (+69%) than the total volatile bases; consequently, a higher delta 15N (>93%) can be inferred for the other bases, which include the amines. Solvent-extractable polar hydrocarbons obtained separately were found to be enriched in 15N (delta 15N = +104%). Total amino acids, prepared from a hydrolyzed hot-water extract by cation exchange chromatography, gave a delta 15N of +94%, a value in good agreement with that obtained previously. Nitrogen isotopic data are also given for amino acid fractions separated chromatographically. The delta 15N values of the Murchison soluble organic compounds analyzed to date fall within a rather narrow range (delta 15N = +94 +/- 8%), an observation consistent with their formation, or formation of their precursors, by interstellar chemistry.     

Three‐dimensional dynamic response of ground with a poroviscoelastic interlayer to a harmonic moving rectangular load

Stratification is a basic characteristic of ground. Due to the influence of ground water, saturated weak interlayers widely exist, particularly in soft soil area. An interlayer of high compressibility and low strength has a substantial effect on dynamic response of the ground, especially under high speed moving load. Thus, a comprehensive investigation in the influence of interlayer is essential and useful in geotechnical and transportation‐related engineering. This paper presents a three‐dimensional semi‐analytical approach to study the dynamic response of a layered ground with a soft saturated interlayer. The ground is modelled as a half‐space consisting of three parts: a viscoelastic upper layer, a saturated poroviscoelastic interlayer governed by Biot's theory and a viscoelastic half‐space. An ‘adapted stiffness matrix’ is proposed to obtain the semi‐analytical solution to the system. Comprehensive parametric study is conducted to investigate the influences of existence, geometrical and physical properties of the interlayer. Depth, thickness, hydraulic permeability of the interlayer, load speed and frequency significantly influence the dynamic response of the ground, among which the interlayer depth plays a dominant role. Resonant frequency exists, which is highly affected by the interlayer thickness, especially in low speed regime. Both hydraulic permeability and boundary conditions of the interlayer influence the characteristics of pore pressure distribution. Copyright © 2017 John Wiley & Sons, Ltd.     

Trends in land surface evapotranspiration across China with remotely sensed NDVI and climatological data for 1981–2010

Abstract

Using satellite observations of Normalized Difference Vegetation Index (NDVI) from NOAA-AVHRR and Terra-MODIS, together with climatic data in a physical evapotranspiration (ET) model, the spatio-temporal variability of ET is investigated in terrestrial China from 1981 to 2010. The model predictions of actual ET (ET_a) are validated with ET values from in situ eddy covariance flux measurements and from basin water balance calculations. The national averaged crop reference ET (ET_p) and ET_a values are 916 ± 21 and 415 ± 12 mm year^-1, respectively. The annual ET_a pattern is closely associated with vegetation conditions in the eastern part of China, whereas ET_a is low in the sparsely-vegetated areas and deserts in the northwestern region, corresponding to scarce rainfall events and amounts. The trends of ET_p and ET_a are remarkably different over the country, and the complementary relationship between ET_p and ET_a is revealed for the study period. Averaged over the whole country, ET_a showed an increasing trend from the 1980s to the mid-1990s, followed by a decreasing trend, consistent with the precipitation anomaly. Across the main vegetation types, annual ET_a amounts are found to correspond clearly with the bands of precipitation and ET_p.     

Monthly and annual statistical distributions of daily rainfall at the Fabra Observatory (Barcelona, NE Spain) for the years 1917–1999

Summary Three empirical distributions of the daily rainfall collected at the Fabra Observatory from 1917 to 1999 are fitted to different statistical models. The first two are designated as the distributions of cumulative amounts and cumulative times. The third distribution accounts for the time interval between two consecutive rainy days with rain amounts equalling or exceeding a threshold amount. Whereas the distribution of cumulative amounts follows an exponential model at monthly and annual scale, except for a few cases, the distribution of the cumulative times is well modelled by a Weibull function, whether monthly or annual scales are considered. The distribution of time intervals also follows a Weibull distribution for the different thresholds considered. In addition, the combination of the two first distributions leads to the normalised rainfall curve, NRC, which is also reproduced satisfactorily by a beta (type 1) distribution. It is worth mentioning that the NRCs follow the expected behaviour with respect to the coefficient of variation of daily rain amounts at monthly and annual scales. In addition, a better understanding of fluctuations and time trends affecting the daily pluviometric regime is achieved by analysing the annual NRCs. The impact of some features of this rain regime, developed for Barcelona, a crowded metropolitan area, on many human activities, may provides the focus of future interdisciplinary analyses.     

Statistical distribution and spectral analysis of rainfallanomalies for Barcelona (NE Spain)

Summary  Rainfall anomaly patterns are obtained for the city of Barcelona from a statistical and a spectral point of view. The time series consists of monthly rainfall amounts recorded over 128 years without interruption. Monthly positive and negative anomalies, obtained as the difference between monthly amounts and monthly threshold values, are used for both types of analyses. The threshold levels are derived form the deciles of theoretical monthly rainfall distributions, which have been previously modelled by the gamma distribution. Positive and negative anomalies of the monthly rain amounts are investigated for these threshold levels. The statistical analysis is applied to each decile considered, yielding empirical exponential laws that can be used to forecast the cumulative number of episodes of consecutive months with either positive or negative anomalies equalling or exceeding a fixed length. A set of linear laws, relating the expected rainfall amount cumulated during an episode of a fixed length, is also deduced. It is worthy of mention that, independently of the decile considered, all the exponential and linear laws have satisfactory regression coefficients. At the same time, it has also been possible to establish the evolution of the coefficients of these laws with respect to the different deciles considered. The exponential laws for episodes of positive and negative anomalies are the starting point, together with two hypotheses, to model probabilities of repeated long episodes over an arbitrary number of years and their return periods in terms of the Poisson distribution model. Moreover, power spectra are derived for anomalies relative to the 50% decile at monthly and seasonal scale. The spectral estimates obtained are then compared with theoretical spectra deduced from possible Markovian or random behaviour of the time series of anomalies. Finally, the significant spectral peaks are discussed and compared with other significant spectral components deduced for some areas of the Mediterranean domain. Received November 11, 1999 Revised February 28, 2000     

Water accumulation in soil by gravel and sand mulches: Influence of textural composition and thickness of mulch layers

The use of gravel and sand as mulch has been an indigenous farming technique for crop production for over 300 years in the semiarid loess region of northwest China. The objective of this study was to determine the influence of texture and thickness of gravel and sand mulch layers on soil water storage by field experiments. The texture experiment consists of three commonly used gravel mulch types: pebble, mixed pebble and sand, fine sand; and the thickness experiment consists of 1, 2 and 3-layers of 2 cm pebbles. Each treatment has three replications. The results indicate that gravel-sand mulches were more effective in conserving soil water, as compared with the bare soil treatment, and the mixed pebble and sand mulch was more effective to conserve soil water than the sole pebble or sand mulch. Soil water content increased with mulch thickness (the number of gravel layers), 1-layer treatment had an average soil water content of 10.85% at 0-60 cm soil layer after a rainfall of 10 mm, 2.42% and 4.92% less than the 2-layers and 3-layers treatments. From May to October in 2004, two and three layers of pebbles conserved 9.8 ± 6.6 mm and 20.0 ± 14.3 mm more water, respectively, as compared with the one layer of 2 cm pebbles at the soil depth of 0-100 cm.