Early Palaeozoic tectonothermal events in basement complexes of the eastern Greywacke Zone (Eastern Alps): evidence from U–Pb zircon data

Field observations and U-Pb zircon data yield evidence that the Kaintaleck Complex represents a distinct crystalline basement unit of the eastern Greywacke Zone and contrasts partly with other pre-Alpine basement complexes of the Eastern Alps. The age data indicate possible Late Archean rock formation, several magmatic and metamorphic events in the Early Palaeozoic (ca. 520-490 and ca. 400-360 Ma), and low-grade metamorphic overprint in the Cretaceous. Zircons from a garnet gneiss layer in a plagioclase gneiss and amphibolite sequence yield an upper intercept age of ca. 2.55 Ga which is interpreted as a possible protolith age. The lower intercept age at 514 Ma represents either (1) a magmatic event or (2) a metamorphic overprint within amphibolite facies conditions. Magmatic zircons derived from granitic orthogneiss boulders of the Kalwang Conglomerate, which covers the crystalline basement, crystallised at ca. 500 Ma. The lower discordia intercepts of the orthogneiss boulders mark the Cretaceous low-grade metamorphic overprint. The lower intercept age of paragneiss zircons from another slice of the Kaintaleck Complex suggests a likely Devonian metamorphic event at ca. 390-400 Ma. The new data demonstrate that the Kaintaleck Complex experienced several stages of tectonothermal evolutions, which are in contrast to the evolution of the main mass of the Austroalpine basement. The data constrain linkages of this part of the Austroalpine basement to the Cordillere Ligérienne and Cadomian block within West-European Variscides.     

Accretionary history of the Rhenodanubian flysch zone in the Eastern Alps – evidence from apatite fission-track geochronology

The thermotectonic evolution of the East Alpine Rhenodanubian flysch zone (RDFZ) and the collisional history along the orogenic front is reconstructed using apatite fission-track (FT) thermochronology. The apatite FT data provides evidence for a burial depth of at least 6 km for the samples, which were totally reset. Burial was not deeper than 11 km, since the zircon fission-track system was not reset. The RDFZ represents an accretionary wedge with a complex burial and cooling history due to successive and differential accretion and exhumation. The sedimentary sequences were deposited along a convergent margin, where accretion started before Maastrichtian and lasted until Miocene. Accretion propagated from a central area (Salzburg-Ybbsitz) both to the west and to the east. In the west, accretion lasted from Middle Eocene to Early Oligocene, reflecting underplating of the RDFZ by the European continental margin sediments. In the east, where three nappes (Greifenstein, Kahlenberg and Laab nappes) can be distinguished, the exhumation started between Late Oligocene and Early Miocene. The Kahlenberg and Laab nappes show total resetting of the apatite FT ages, while in the Greifenstein nappe there is only partial resetting. According to a new paleogeographic reconstruction, the Kahlenberg and Laab nappes were placed on top of the Greifenstein nappe by an out-of-sequence thrust.     

Evolution of quartz microstructures and textures during polyphase deformation within the Tauern Window (Eastern Alps)

The interior of the Tauern Window exposes underplated Penninic continental lithosphere and the overlying obducted Penninic oceanic crust within a large antiformal dome in the internal zone of the Eastern Alps. These units have been affected by a polyphase deformation history. Generally, three deformation events are distinguished. D₁ is related to underplating of, and top-to-the-N nappe stacking within, the Penninic continental units of the Tauern Window. Deformation stage D₂ is interpreted to reflect the subsequent continent collision between the Penninic continental units and the European foreland, D₃ is related to the formation of the dome structure within the Tauern Window. During thickening of continental lithosphere and nappe stacking (D₁), and subsequent intracontinental shortening (D₂), these tectonic units have been ductilely deformed close to a plane strain geometry. Conditions for the plastic deformation of the main rock-forming mineral phases (quartz, feldspar, dolomite, calcite) have prevailed during all three phases of crustal deformation. Generally, two types of quartz microstructures that are related to D₁ are distinguished within the Tauern Window: (a) Equilibrated and annealed fabrics without crystallographic preferred orientations (CPO) have only been observed in the central part of the southeastern Tauern Window, corresponding with amphibolite-grade metamorphic conditions. (b) In the northeastern and central part of the Tauern Window microstructures are characterized by quartz grains that show equilibrated shape fabrics, but well preserved CPO with type-I cross girdle distributions, indicating a deformation geometry close to plane strain. During D₂, two types of quartz microstructures are distinguished, too: (a) Quartz grains that show equilibrated shape fabrics, but well-preserved CPO. The c-axes distributions generally are characterized by type-I cross girdles, locally by type-II cross girdles, and in places, oblique single girdle distributions. (b) A second type of quartz microstructure is characterized by highly elongated grains and fabrics typical for dislocation creep and grain-boundary migration, and strong CPO. This type is restricted to the southern sections of the western and eastern Tauern Window. The c-axis distributions show type-I cross girdles in the western part of the Tauern Window and single girdles in the southeastern part. In the western part of the Tauern Window, a continuous transition from type (b) microstructures in the south to type (a) microstructures in the north is documented. The microstructural evolution also documents that the dome formation in the southeastern and western Tauern Window has already started during D₂ and has continued subsequent to the equilibration during amphibolite to greenschist facies metamorphism. D₃ is restricted to distinct zones of localized deformation. D₃-related quartz fabrics are characterized by the formation of ribbon grains; the c-axes show small-circle distributions around the Z-axis of the finite-strain ellipsoid. During exhumation and doming (D₃), deformation occurred under continuously decreasing temperatures.     

Evaluation of the long term groundwater pollution by the open cast lignite mine Jänschwalde (Germany)

The reconstruction of the hydrogeochemical composition of the dumps in the active Lusatian lignite mining region is necessary to forecast the acid mine drainage into the residual lakes and the natural groundwater systems. Therefore, a three-dimensional geochemical model of the Jänschwalde dump was developed. By analysing the geological situation and the mining technology, it is possible to calculate the pyrite oxidation in different parts of the mine (groundwater lowering in front of the mine, natural and dump slopes, marginal pits and the dump surface).Only 4% of the total pyrite content is oxidised during the mining process within its time of operation (43 years). The major fraction (about 60%) is oxidised on the surface of the dumps, whereas the other zones contribute less to the production of acidity (groundwater lowering 5.4%, short term exposed slopes (1.2% natural slopes; 7.4% dump slopes) and 22.4% inclusion of O₂ during the tipping). It may be concluded that the technology of conveyor belt bridges, combined with the selective tipping of loamy sediments on the surface is very favourable to minimise the oxidation of pyrite. It is also shown that in the open cast mine of Jänschwalde the buffer capacity of the carbonate dominates over the produced acid.     

Morphology and curvature of delta slopes in Swiss lakes: lessons for the interpretation of clinoforms in seismic data

Seismic surveys were conducted and bathymetric data obtained from four alpine lakes in Switzerland. The curvature of the delta slopes was analysed with mathematical equations. Linear or exponential profiles are observed, representing planar or concave morphologies respectively. Planar profiles are interpreted to represent sediment that rests at the angle-of-repose. The slope angle of these profiles shows a correlation with sediment calibre. Exponential profiles do not show a clear correlation between sediment calibre and slope angle; they do not rest at the angle-of-repose, and different kinds of sediment can rest at the same slope angle. At the transition from lower slope to toe- of-slope, the exponential equation fails to predict the present-day morphology. The toe-of-slope lies above the predicted trend. This is attributed to a drastic increase in turbidite deposition that provides additional sediment and raises the basin-floor profile above the predicted trend. The breaks between delta plain and slope are sharp, reflecting an abrupt change from transport by river flow and waves to gravity-driven transport. In these lakes, the base-level fluctuations relative to supply are small and insufficient to alter this sharp topographic break. The absence of sigmoidal profiles on the Swiss deltas is attributed to the high rate of progradation coupled with small fluctuations in base level.     

Triassic carbonate buildup flanks in the Dolomites, northern Italy: breccias, boulder fabric and the importance of early diagenesis

The flanks of Middle Triassic carbonate buildups in the Dolomites show well‐developed clinostratification, with typical angles of 30–40°. This paper focuses on the metre‐scale fabric of these clinoforms and sets these within the context of their large‐scale and microscopic features. Clinoform stratification is caused by fibrous cement crusts, by stylolites paralleling a vague stratification and by pelagic limestone interbedded with the lower portions of the clinoforms. These parts of the clinoforms locally exhibit a boulder fabric. A fracture system, subvertical to clinostratification, is filled by fibrous cements and marine internal sediment. The analysis of clinoform fabric indicates that parts consist of in situ automicrite. Other parts of the clinoforms are made up of breccia. The breccias occur as isolated pockets and lenses with random orientation and dimensions ranging from a few square decimetres to hundreds of square metres. The breccias have gradual contacts with the unbrecciated host rock. Breccia components are mostly angular, show a microfacies similar to that of the unbrecciated host rock and are composed of millimetre‐ to decimetre‐sized particles that generally float in radiaxial‐fibrous cement. Matching grain boundaries are common. Calcite cement typically makes up 20 and 40 vol.% of the brecciated areas. Clinostratification, the fracture system, brecciation and boulder fabric point to gravity induced deformation of in situ flank deposits rather than gravity induced depositional processes. Brecciation appears to result from translational sliding (millimetres to metres) on the steep buildup flanks, which caused fracturing of the vaguely stratified automicrite, followed by displacive growth of fibrous cement. Cementation occurred in a (shallow) burial, marine phreatic environment, because cement clasts are virtually absent from the flank‐derived gravity flows in the adjoining basinal sediments. Displacive cement growth indicates a volume increase of the clinoforms during diagenesis of up to 20–40 vol.% and can account for the local drag of buildup interior limestones. Similarly, the boulder fabric appears to be a diagenetic feature, which resulted from differential settling of incompletely lithified boundstone and grainstone, and the interbedded pelagic limestone.     

Microbially induced cementation of carbonate sands: are micritic meniscus cements good indicators of vadose diagenesis?

Characteristic fabrics such as micrite envelopes, calcified filaments and micritic grain-to-grain bridges are observed in a modern subtidal firmground (Wood Cay, Bahamas) and in a variety of firm- and hardgrounds of Lower Cretaceous and Upper Jurassic platform carbonates (Swiss and French Jura Mountains). Their similarity to microbial fabrics described in grapestones and in intertidal to continental vadose environments suggests that microbial activity played an important role in the initial stabilization and cementation of carbonate sands. 'Meniscus-type cements' (to distinguish them from vadose meniscus cements), which clearly formed in subtidal environments, are related to filament calcification, trapping of percolating micrite and microbially induced carbonate formation. Such meniscus-type cements are commonly micritic, but meniscus-shaped precipitation of fibrous aragonite or sparitic calcite around organic filaments is also observed. Therefore, an interpretation of vadose early diagenesis should not be based on meniscus cements alone. Similarly, subtidally formed filamentous structures can strongly resemble alveolar septal structures and be interpreted incorrectly as related to subaerial exposure.     

Methane Production, Emission and Possible Control Measures in the Rice Agriculture

In the rice field methane is produced in the soil layer with depths of 2-25 cm. The vertical profile of methane production rate in the paddy soil during the water covering period differs from that in the paddy soil in dry phase. Only a small part, about 30%. of the produced methane is emitted to the atmosphere through rice plant, air bubbles, and molecular diffusion. Therefore, the methane emission rate from the rice field depends not only on the methane production rate in the soil, but also on the transport efficiency of the rice plant, air bubble formation that in turn depends on the production rate, and molecular diffusion.Field measurements show that methane emission rates from a particular rice field have very large diurnal, seasonal and interannual variations, which are related to soil characteristics, water regime, farming procedure, local climate, and rice growing activities. The relationship between the methane emission rate and the above mentioned factors is very complicated. The emission rate