Detection of tannins in modern and fossil barks and in plant residues by high-resolution solid-state C nuclear magnetic resonance

Bark samples isolated from brown coal deposits in Victoria, Australia, and buried wood from Rhizophora mangle have been studies by high-resolution solid-state nuclear magnetic resonance (NMR) techniques. Dipolar dephasing ¹³C NMR appears to be a useful method of detecting the presence of tannins in geochemical samples including barks, buried woods, peats and leaf litter. It is shown that tannins are selectively preserved in bark during coalification to the brown coal stage.     

Correlation factors for impurity diffusion on the sublattice of dodecahedral sites in garnet

The method of Koiwa and Ishioka (Philos Mag A 47:927–938, 1983) is used, with slight modification, to evaluate the correlation factor for vacancy-mediated diffusion of impurity atoms on the sublattice of dodecahedral sites in garnet, as a function of the relevant vacancy-jump frequencies. The required values of the lattice Green’s function were obtained from multiple Monte Carlo simulations in lattices of progressively larger size, extrapolated to an infinite lattice using a model that linearizes the dependence of the functional value on lattice size. As Online Resources, codes are provided that permit evaluation of the correlation factor for any chosen set of vacancy-jump frequencies, for implementation in either Mathematica ^® or Matlab ^®.     

Sulfur isotopic zonation in the Cadia district,southeastern Australia: exploration significance and implications for the genesis of alkalic porphyry gold–copper deposits

The alkalic porphyry gold–copper deposits of the Cadia district occur in the eastern Lachlan Fold Belt of New South Wales, Australia. The district comprises four porphyry deposits (Ridgeway, Cadia Quarry, Cadia Hill, and Cadia East) and two iron–copper–gold skarn deposits (Big Cadia and Little Cadia). Almost 1,000 tonnes of contained gold and more than four million tonnes of copper have been discovered in these systems, making Cadia the world’s largest known alkalic porphyry district, in terms of contained gold. Porphyry gold–copper ore at Cadia is associated with quartz monzonite intrusive complexes, and is hosted by central stockwork and sheeted quartz–sulfide–(carbonate) vein systems. The Cadia porphyry deposits are characterized by cores of potassic and/or calc–potassic alteration assemblages, and peripheral halos of propylitic alteration, with late-stage phyllic alteration mostly restricted to fault zones. Hematite dusting is an important component of the propylitic alteration assemblage, and has produced a distinctive reddening of feldspar minerals in the volcanic wall rocks around the mineralized centers. Sulfide mineralization is strongly zoned at Ridgeway and Cadia East, with bornite-rich cores surrounded by chalcopyrite-rich halos and peripheral zones of pyrite mineralization. The Cadia Hill and Cadia Quarry deposits have chalcopyrite-rich cores and pyrite-rich halos, and Cadia Hill contains a high-level bornite-rich zone. Distinctive sulfur isotopic zonation patterns have been identified at Ridgeway, Cadia Hill, and Cadia East. The deposit cores are characterized by low δ³⁴S_sulfide values (−10 to −4‰), consistent with sulfide precipitation from an oxidized (sulfate-predominant) magmatic fluid at 450 to 400°C. Pyrite grains that occur in the propylitic alteration halos typically have δ³⁴S_sulfide values near 0‰. There is a gradual increase in δ³⁴S_sulfide values outwards from the deposit cores through the propylitic halos. Water–rock interaction during propylitic alteration caused magmatic sulfate reduction and concomitant oxidation of ferrous iron-bearing minerals, resulting in enrichment of ³⁴S in pyrite and also producing the distinctive reddened, hematite-rich alteration halos to the Cadia deposits. These results show that sulfur isotope analyses have potential applications in the exploration of alkalic porphyry-style deposits, with zones of depleted δ³⁴S_sulfide values most prospective for high-grade mineralization.     

Contrasting grain size and componentry in complex proximal deposits of the 1886 Tarawera basaltic Plinian eruption

The 1886 Plinian eruption of Tarawera, New Zealand, is a unique basaltic fissure-fed eruption with exceptionally well preserved fall deposits to within 200 meters of the source vents. These proximal deposits form a series of spatter/cinder half-cones along the northeastern 8-km-long segment of the 1886 fissure. Here we examine these deposits using grain size and clast componentry techniques. We contrast the products of the phreatomagmatic (phases I and III) and Plinian (Phase II) stages of the eruption and examine deposit variability as a function of contrasting eruptive intensity within the climactic phase (II) of the eruption. The opening phreatomagmatic phase I of the eruption involved gas-rich magma interacting with water and fragmenting at least 300 meters below the surface. The deposits of the climactic phase that followed have relatively uniform grain size but marked contrasts in the relative abundance of juvenile and wall rock (lithic) clasts. Deposits linked to vents associated with the high Plinian plume are more uniform than those characterized by a weaker cone-forming eruption style. During the third, and closing, phase of the eruption, magma withdrawal accompanied the onset of decoupling of the exsolved gas phase, leading to fragmentation at increasingly greater depths and significant wall rock collapse into the erupting vents. Variability in eruptive style during phase II along the fissure appears to be a function of shallow seated controls, in particular the variable extent of incorporation of lithic wall rock into the erupting jet, as a consequence of vent wall collapse. Widely dispersed beds centralized around Plinian sources along the fissure have very low lithic content; cone-forming beds at other craters that contain very high lithic contents. This incorporation led to a significant reduction of the velocity and stability of the jet at these latter steep-walled craters, and induced episodicity in the form of vent-clearing explosions. The result is a large reduction of the physical and thermal ability of these vents to contribute to a stable high eruptive plume. Instead large volumes of ejecta were sedimented prematurely from shallow heights at rates an order of magnitude greater than for historical Strombolian, Hawaiian and subPlinian eruptions. This study illustrates that sustained powerful Plinian eruptions can be accompanied by heterogeneities and instabilities of the eruptive jet. At Tarawera, the record of complex proximal transport and deposition processes in the eruptive jet cannot be inferred from the eruption products at distances greater than 400 m from the eruptive fissure. We suggest that study of ultraproximal deposits, as seen at Mt Tarawera, provides the only opportunity to document the complex, dynamic behavior of the jet region of Plinian eruptions.     

Effects of red mud on marine animals

Red mud is a waste product in the reduction of bauxite in the production of aluminium. The exact composition of red mud depends on the source of the bauxite and its treatment during production. This variation has been responsible for conflicting reports about the damage caused by dumping red mud at sea.