Natural Gas Hazard (CO2, 222 Rn) within a Quiescent Volcanic Region and Its Relations with Tectonics: The Case of the Ciampino-Marino Area, Alban Hills Volcano, Italy

Groundwater surveys were performed by detailed(around 300 sites) grid-analysis of water temperature, pH, redox potential, electrical conductivity, ²²²Rn, alkalinity and by calculating the pCO₂, throughout the Ciampino and Marino towns in the Alban Hills quiescent volcano (Central Italy). Following several episodes of dangerous CO₂ exhalation from soils during the last 20 years and earlier ashistorically recorded, the work aimed at assessing the Natural Gas Hazard (NGH) including the indoor-Rn hazard. The NGH was defined as the probability of an area to become a site of poisonous peri-volcanic gas exhalations from soils to the lower atmosphere (comprising buildings). CO₂ was found to be a ``carrier' for the other poisonous minor and in trace components (H<sub>s</sub>S, CH<sub>4</sub>, <sup>222</sup>Rn, etc.). This assessment was performed by extrapolating in the aquifer CO<sub>2</sub> and <sup>222</sup>Rn conditions, and discriminating sectors where future CO<sub>2</sub> flux in soils as well as indoor-Rn measurements have to be noted. A preliminary indoor-Rn survey was performed at about 200 sites. The highest values were found in the highest pCO<sub>2</sub> and high <sup>222</sup>Rn values in groundwater. This indicates convection and enhanced permeability in certain sectors of the main aquifer, i.e., along the bordering faults and inside the gas-trap of the Ciampino Horst., where ``continuous gas-phase micro-macro seepage mechanism' is invoked to explain the high peri-volcanic gases flux.     

Interannual variability of Kelvin wave propagation in the wave guides of the equatorial Indian Ocean,the coastal Bay of Bengal and the southeastern Arabian Sea during 1993–2006

The observed variability of the Kelvin waves and their propagation in the equatorial wave guide of the Indian Ocean and in the coastal wave guides of the Bay of Bengal (BoB) and the southeastern Arabian Sea (AS) on seasonal to interannual time scales during years 1993–2006 is examined utilizing all the available satellite and in-situ measurements. The Kelvin wave regime inferred from the satellite-derived sea surface height anomalies (SSHA) shows a distinct annual cycle composed of two pairs of alternate upwelling (first one occurring during January–March and the second one occurring during August–September) and downwelling (first one occurring during April–June and the second one occurring during October–December) Kelvin waves that propagate eastward along the equator and hit the Sumatra coast and bifurcate. The northern branches propagate counterclockwise over varied distances along the coastal wave guide of the BoB. The potential mechanisms that contribute to the mid-way termination of the first upwelling and the first downwelling Kelvin waves in the wave guide of the BoB are hypothesized. The second downwelling Kelvin wave alone reaches the southeastern AS, and it shows large interannual variability caused primarily by similar variability in the equatorial westerly winds during boreal fall. The westward propagating downwelling Rossby waves triggered by the second downwelling Kelvin wave off the eastern rim of the BoB also shows large interannual variability in the near surface thermal structure derived from SODA analysis. The strength of the equatorial westerlies driven by the east–west gradient of the heat sources in the troposphere appears to be a critical factor in determining the observed interannual variability of the second downwelling Kelvin wave in the wave guides of the equatorial Indian Ocean, the coastal BoB, and the southeastern AS.     

Cryogenesis as a factor of methane distribution in layers of permafrost

The gas seeps in Kolyma lowland are associated with methane inclusions in permafrost. These inclusions are formed by methane squeezed by epigenetic freezing of methane saturated deposits. This is proved by the biological genesis of the methane, by the isotopic data and the lower radiocarbon age of the methane from the gas seep in comparison with the radiocarbon age of the host deposits. The experimental data and observations of methane distribution in permafrost indicate that the methane distribution in the stratum of frozen deposits is a result of methane migration during cryolithogenesis. The regularities of methane distribution in the deposits and formation of methane inclusions may change the idea of the character and volumes of emission of greenhouse gases into the atmosphere upon degradation of permafrost.     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

X-ray Raman scattering for structural investigation of silica/silicate minerals

We have performed X-ray Raman scattering (XRS) measurements on the oxygen K and silicon L absorption edges of four silica minerals: α-quartz, α-cristobalite, coesite, and stishovite. We have also calculated the partial electron densities of states (DOSs) and compared these with the XRS spectra. This study demonstrates that the short-range structure around the atom of interest strongly influences the XRS spectral features. Importantly, the oxygen K-edge XRS spectra are found to reflect the p-orbital DOS while the silicon L-edge spectra reflect the s- and d-orbital DOSs, even when a product of a momentum transfer and a mean radius of a electron orbit (1s for oxygen and 2p for silicon), Qr, is close to or larger than unity. Building on this, calculations of the partial DOSs for other silica phases are presented, including ultra-high-pressure phases, which provide a good reference for further XRS study of silica and silicate minerals. XRS measurements should be performed on not only either of oxygen or silicon but also on many kinds of constituent elements to reveal the structural change of glasses/melts of silicates under extreme conditions.     

Bioavailability: the organism as sensor

The use of a system of continuous culture of phytoplankton at constant population density, the ‘cage-culture’ turbidostat, as a monitor of the bioavailability of pollutant materials, is illustrated. In the case of proposed dredge spoils from two polluted areas, it is shown that bulk analyses for scheduled materials cannot be equated with bioavailability. Monitoring for the effect of the whole pollutant mixture on a properly chosen test population could obviate the necessity for chemical analyses for each component.     

BOWDITCH TRAVERSE ADJUSTMENT AND A MODIFICATION: NOTES

Abstract

In the second part of the paper on this subject in the last issue (30, 483) the references to the relative angular and linear closures are rather misleading. Mr Clendinning points out that the probable angular error at a station must be considered; the mean error is clearly different.     

Mapping of benthic enrichment patterns in Narragansett Bay,Rhode Island

A synoptic reconnaissance survey was performed over a five-day period in August 1988 to assess benthic habitat quality throughout Narragansett Bay, Rhode Island, using REMOTS^® sediment-profile photography and analysis in combination with measurements of the levels ofClostridium perfringens spores (a fecal indicator) in sediments. Three main areas of degraded benthic habitat quality related to either excessive organic enrichment or physical disturbance were identified based solely on the REMOTS^® analysis: the Providence River Reach, Greenwich Bay and its associated coves and harbors, and an area located along the southwest side of Prudence Island. Sediments at many stations in these areas exhibited shallow apparent redox-potential discontinuity (RPD) depths, high apparent oxygen demand, and low-order benthic successional stages. ElevatedClostridium perfringens spore counts in surface sediments were attributed to inputs from wastewater treatment facilities. The highest spore counts occurred at the head of the bay, where wastewater treatment discharges and associated combined sewer overflows are numerous. Using data from the REMOTS^® analysis and the sediment inventory ofC. perfringens spores, a distinction was made between organic enrichment of the bottom from sewage, versus nonsewage enrichment or physical disturbance. The combination of techniques employed in this investigation could be used to design more efficient monitoring programs to assess eutrophication effects in estuaries and determine the effectiveness of regulatory or management initiatives to reduce organic overenrichment of benthic habitats.     

天然地基强迫振动测试与分析

在试验块体分别为明置与埋置情形时,利用激振器对某工程场地天然地基分别进行竖向、水平回转及扭转稳态强迫振动试验。试验结果表明,埋置情形试验的动力特性参数值均大于明置情形试验相应值;同种试验情形下,地基第一振型共振频率竖向最大,水平回转向其次,扭转向最小;土的参振质量均远大于基础本身质量。