Nitrogen uptake kinetics in the Ross Sea, Antarctica

The first estimates of uptake kinetic parameters for NH₄⁺, NO₃⁻, and urea in the Ross Sea, Antarctica were measured on three cruises during austral late winter–early spring 1996 (pre-bloom), late spring 1997 (bloom development), and summer 1997 (bloom decline). Nitrogen (N) uptake experiments were conducted with water collected at the 50% light penetration depth using trace-metal clean protocols and ¹⁵N tracer techniques. At all sites, ambient NO₃⁻ concentrations ranged from 5.8 to 30.5 μg-at N l⁻¹ and silicic acid concentrations were greater than 62.0 μg-at Si l⁻¹. The following trends were observed. First, based on maximum uptake rates (V_max), apparent N utilization followed the order NO₃⁻>NH₄⁺>urea during the pre-bloom and bloom development cruises. During the summer cruise, as the bloom was declining, the apparent order of utilization was NH₄⁺>NO₃⁻>urea. Second, evidence for possible repression of NO₃⁻ uptake by elevated NH₄⁺ concentrations was only observed at one site. Third, the kinetic parameters of NH₄⁺ uptake rates corrected for isotope dilution were compared with the kinetic parameters determined from uncorrected rates. In this comparison, the measure of substrate affinity, α (α=V_max/K_s) increased by an average of 4.6-fold when rates were corrected for isotope dilution, but values of V_max remained unchanged. Fourth, using bacterial production data, the magnitude of bacterial N uptake was estimated. Assuming that all bacterial N demands were met with NH₄⁺, the estimated bacterial portion of NH₄⁺ uptake ranged from <1%, when the ratio of bacteria to autotrophic biomass was low, to 35%, when bacterial abundance and biomass were highest. Finally, dramatic changes in NH₄⁺ uptake capacity were observed at one station (Stn. O), where kinetic parameters were measured during all three cruises. We hypothesize that a mutualistic relationship exists between phytoplankton and heterotrophic bacteria, and that the creation of microzones of high NH₄⁺ concentrations contributed to the changes seen at this station.     

Helium isotope geochemistry of mid-ocean ridge basalts from the South Atlantic

We report new helium isotope results for 49 basalt glass samples from the Mid-Atlantic Ridge between 1°N and 47°S.³He/⁴He in South Atlantic mid-ocean ridge basalts (MORB) varies between 6.5 and 9.0 R_A (R_A is the atmospheric ratio of1.39 × 10⁻⁶), encompassing the range of previously reported values for MORB erupted away from high³He/⁴He hotspots such as Iceland. He, Sr and Pb isotopes show systematic relationships along the ridge axis. The ridge axis is segmented with respect to geochemical variations, and local spike-like anomalies in³He/⁴He, Pb and Sr isotopes, and trace element ratios such as(La/Sm)_N are prevalent at the latitudes of the islands of St. Helena, Tristan da Cunha and Gough to the east of the ridge. The isotope systematics are consistent with injection beneath the ridge of mantle “blobs” enriched in radiogenic He, Pb and Sr, derived from off-axis hotspot sources. The variability in³He/⁴He along the ridge can be used to refine the hotspot source-migrating-ridge sink model.

MORB from the 2–7°S segment are systematically the least radiogenic samples found along the mid-ocean ridge system to date. Here the depleted mantle source is characterized by⁸⁷Sr/⁸⁶Sr of 0.7022, Pb isotopes close to the geochron and with²⁰⁶Pb/²⁰⁴Pb of 17.7, and³He/⁴He of 8.6–8.9 R_A. The “background contamination” of the subridge mantle, by radiogenic helium derived from off-ridge hotspots, displays a maximum between 20 and 24°S. The HePb and HeSr isotope relations along the ridge indicate that the³He/⁴He ratios are lower for the hotspot sources of St. Helena, Tristan da Cunha and Gough than for the MORB source, consistent with direct measurements of³He/⁴He ratios in the island lavas. Details of the HeSrPb isotope systematics between 12 and 22°S are consistent with early, widespread dispersion of the St. Helena plume into the asthenosphere, probably during flattening of the plume head beneath the thick lithosphere prior to continental breakup. The geographical variation in theHe/Pbratio deduced from the isotope systematics suggests only minor degassing of the plume during this stage. Subsequently, it appears that the plume component reaching the mid-Atlantic ridge was partially outgassed of He during off-ridge hotspot volcanism and related melting activity.

Overall, the similar behavior of He and Pb isotopes along the ridge indicates that the respective mantle sources have evolved under conditions which produced related He and Pb isotope variations.     

Pedogenic zones in postglacial sediment of lake manitoba,Canada

The postglacial sediment record of Lake Manitoba is composed dominantly of silty clay to clayey silt with little variation in most physical, chemical, and mineralogical properties. Distinct in the sedimentary sequence of this large lake, however, are four zones that have a low moisture content, blocky to pelletal structure, and gleyed colour. All of these zones formed during the warmest and driest postglacial period in the region, 9500 to 4500 years ago. Although several possible hypotheses can be formulated regarding the origin of these zones including changes in sedimentation rate, clay mineralogy, lake chemistry, and depth of winter freezing, the most likely explanation is that they represent pedogenic horizons. Formation by pedogenesis during dry or extremely low water conditions is not mutually exclusive of the other hypotheses, and several are favoured by low water conditions.     

Implications of the saltation–abrasion bedrock incision model for steady‐state river longitudinal profile relief and concavity

The saltation–abrasion model predicts rates of river incision into bedrock as an explicit function of sediment supply, grain size, boundary shear stress and rock strength. Here we use this experimentally calibrated model to explore the controls on river longitudinal profile concavity and relief for the simple but illustrative case of steady‐state topography. Over a wide range of rock uplift rates we find a characteristic downstream trend, in which upstream reaches are close to the threshold of sediment motion with large extents of bedrock exposure in the channel bed, while downstream reaches have higher excess shear stresses and lesser extents of bedrock exposure. Profile concavity is most sensitive to spatial gradients in runoff and the rate of downstream sediment fining. Concavity is also sensitive to the supply rate of coarse sediment, which varies with rock uplift rate and with the fraction of the total sediment load in the bedload size class. Variations in rock strength have little influence on profile concavity. Profile relief is most sensitive to grain size and amount of runoff. Rock uplift rate and rock strength influence relief most strongly for high rates of rock uplift. Analysis of potential covariation of grain size with rock uplift rate and rock strength suggests that the influence of these variables on profile form could occur in large part through their influence on grain size. Similarly, covariation between grain size and the fraction of sediment load in the bedload size class provides another indirect avenue for rock uplift and strength to influence profile form. Copyright © 2008 John Wiley & Sons, Ltd.     

Late Holocene sea-level changes and isostasy in western Denmark

Cores and exposed cliff sections in salt marshes around Ho Bugt, a tidal embayment in the northernmost part of the Danish Wadden Sea, were subjected to ¹⁴C dating and litho- and biostratigraphical analyses to reconstruct paleoenvironmental changes and to establish a late Holocene relative sea-level history. Four stages in the late Holocene development of Ho Bugt can be identified: (1) groundwater-table rise and growth of basal peat (from at least 2300 BC to AD 0); (2) salt-marsh formation (0 to AD 250); (3) a freshening phase (AD 250 to AD 1600?), culminating in the drying out of the marshes and producing a distinct black horizon followed by an aeolian phase with sand deposition; and (4) renewed salt-marsh deposition (AD 1600? to present). From 16 calibrated AMS radiocarbon ages on fossil plant fragments and 4 calibrated conventional radiocarbon ages on peat, we reconstructed a local relative sea-level history that shows a steady sea-level rise of 4 m since 4000 cal yr BP. Contrary to suggestions made in the literature, the relative sea-level record of Ho Bugt does not contain a late Holocene highstand. Relative sea-level changes at Ho Bugt are controlled by glacio-isostatic subsidence and can be duplicated by a glacial isostatic adjustment model in which no water is added to the world's oceans after ca. 5000 cal yr BP.     

Agricultural policy reforms and sustainable land management: a New Zealand case study

This paper examines the link between poverty and land management within the context of New Zealand's almost total removal of subsidies to agriculture since 1984. The impact of these policy changes is explored through the findings from a detailed study of sixteen farms in the North Island hill country. Stress is identified as a primary link between social damage and environmental degradation. This link reinforces the impact of other linkages expressed in reduced production, lower stocking rates, and reduced capital inputs. Deregulation is claimed to be good. This paper shows that in certain circumstances this is not so.     

An experimental study on the ripple–dune transition

Flume experiments were conducted on different bed stages across the ripple–dune transition. As flow velocity increases, an initially flat bed surface (made of fairly uniform sandy material) is gradually transformed into a two‐dimensional rippled bed. With further increase in velocity, two‐dimensional ripples are replaced by irregular, linguoid ripples. As the average velocity necessary for the ripple–dune transition to occur is imposed on the bed surface, these non‐equilibrium linguoid ripples are further transformed into larger, two‐dimensional dunes. For each of these stages across the transition, a concrete mould of the bed was created and the flow structure above each fixed bed surface investigated. An acoustic Doppler velocimeter was used to study the flow characteristics above each bed surface. Detailed profiles were used along a transect located in the middle of the channel. Results are presented in the form of spatially averaged profiles of various flow characteristics and of contour maps of flow fields (section view). They clearly illustrate some important distinctions in the flow structure above the different bedform types associated with different stages during the transition. Turbulence intensity and Reynolds stresses gradually increase throughout the transition. Two‐dimensional ripples present a fairly uniform spatial distribution of turbulent flow characteristics above the bed. Linguoid ripples induce three‐dimensional turbulence structure at greater heights above the bed surface and turbulence intensity tends to increase steadily with height above bed surface in the wake region. A very significant increase in turbulence intensity and momentum exchange occurs during the transition from linguoid ripples to dunes. The turbulent flow field properties above dunes are highly dependent on the position along and above the bed surface and these fields present a very high degree of spatial variability (when compared with the rippled beds). Further investigations under natural conditions emphasizing sediment transport mechanisms and rates during the transition should represent the next step of analysis, together with an emphasis on quadrant analysis. Copyright © 2001 John Wiley & Sons, Ltd.     

Polarimetry of Pluto

The polarization of Pluto has been measured for a range of solar phase angles from 0.8 to 1.8°. A mean linear polarization of 0.29 ± 0.01% (error of the mean) was found. No dependence of both the amount of polarization and position angles with rotational phase or solar phase angle could be detected. The positional angles of polarization agree with calculated position angles of the defect of illumination and are therefore parallel to the scattering plane. The observed polarization cannot be explained as resulting purely from a surface material which is similar to asteroidal surfaces. A hypothesis of polarization from a thin atmosphere, in addition to the surface polarization, is advanced.     

Hydrated sulphuric acid in dense molecular clouds

We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H₂SO₄ ·  n H₂O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.     

Deep-water renewal in a Scottish fjord: temperature, salinity and oxygen isotopes

The sea lochs (fjords) of north-west Scotland are located in a region of Europe particularly well situated to monitor changes in westerly air streams. The moisture transported in these air streams has a profound effect on regional precipitation, freshwater run-off and, in turn, sea loch circulation. The gentle slope of the regional salinity:δ¹⁸O mixing-line, defined as 0.18 ‰ per salinity unit, suggests that the temperature: δ¹⁸O relationship may be readily resolved in these coastal waters. Deep-water renewal events, both observed and predicted from empirical models, in the bottom-waters of Loch Etive provide an opportunity to assess the temperature, salinity and δ¹⁸O relationship. Predicted changes in δ¹⁸O_calcite as a function of changing salinity (ΔS) and changing temperature (ΔT) during deep-water renewal events suggest that >80% fall above analytical detection limits. The theoretical likelihood of recording such renewal events in the "palaeoclimate" record appears to be promising, but temperature and salinity change during renewal events may have either sign. Scottish fjords, because of the relatively small impact which salinity has on δ¹⁸O_water, may provide useful study sites in palaeoclimate research, particularly where palaeotemperature is the primary record of interest.