Chlorine-36 in groundwater of the United States: empirical data

Natural production of the radionuclide chlorine-36 (³⁶Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear weapons, has also produced large amounts of ³⁶Cl that can be detected in many samples of groundwater. In order to be most useful in hydrologic studies, the natural production prior to 1952 should be distinguished from more recent artificial sources. The object of this study was to reconstruct the probable preanthropogenic levels of ³⁶Cl in groundwater in the United States. Although significant local variations exist, they are superimposed on a broad regional pattern of ³⁶Cl/Cl ratios in the United States. Owing to the influence of atmospherically transported ocean salt, natural ratios of ³⁶Cl/total Cl are lowest near the coast and increase to a maximum in the central Rocky Mountains of the United States. Electronic Publication     

Serpentinization of abyssal peridotites from the MARK area, Mid-Atlantic Ridge: sulfur geochemistry and reaction modeling

The opaque mineralogy and the contents and isotope compositions of sulfur in serpentinized peridotites from the MARK (Mid-Atlantic Ridge, Kane Fracture Zone) area were examined to understand the conditions of serpentinization and evaluate this process as a sink for seawater sulfur. The serpentinites contain a sulfur-rich secondary mineral assemblage and have high sulfur contents (up to 1 wt.%) and elevated δ³⁴S_sulfide (3.7 to 12.7‰). Geochemical reaction modeling indicates that seawater-peridotite interaction at 300 to 400°C alone cannot account for both the high sulfur contents and high δ³⁴S_sulfide. These require a multistage reaction with leaching of sulfide from subjacent gabbro during higher temperature (∼400°C) reactions with seawater and subsequent deposition of sulfide during serpentinization of peridotite at ∼300°C. Serpentinization produces highly reducing conditions and significant amounts of H₂ and results in the partial reduction of seawater carbonate to methane. The latter is documented by formation of carbonate veins enriched in ¹³C (up to 4.5‰) at temperatures above 250°C. Although different processes produce variable sulfur isotope effects in other oceanic serpentinites, sulfur is consistently added to abyssal peridotites during serpentinization. Data for serpentinites drilled and dredged from oceanic crust and from ophiolites indicate that oceanic peridotites are a sink for up to 0.4 to 6.0 × 10¹² g seawater S yr⁻¹. This is comparable to sulfur exchange that occurs in hydrothermal systems in mafic oceanic crust at midocean ridges and on ridge flanks and amounts to 2 to 30% of the riverine sulfate source and sedimentary sulfide sink in the oceans. The high concentrations and modified isotope compositions of sulfur in serpentinites could be important for mantle metasomatism during subduction of crust generated at slow spreading rates.     

Water quality impacts from mining in the Black Hills,South Dakota,USA

The focus of this research was to determine if abandoned mines constitute a major environmental hazard in the Black Hills. Many abandoned gold mines in the Black Hills contribute acid and heavy metals to streams. In some areas of sulfide mineralization local impacts are severe, but in most areas the impacts are small because most ore deposits consist of small quartz veins with few sulfides. Pegmatite mines appear to have negligible effects on water due to the insoluble nature of pegmatite minerals. Uranium mines in the southern Black Hills contribute some radioactivity to surface water, but the impact is limited because of the dry climate and lack of runoff in that area.     

Porewater pressure increases in soil and rock from underground chemical and nuclear explosions

A review and analysis of chemical and nuclear explosive-induced porewater pressure increases and induced rise in groundwater table elevations (groundwater mounding) is presented. Our analysis indicates that residual pore pressure increases and groundwater mounding can be induced by underground chemical and nuclear explosions to scaled distances of 879 m/(kt)^1/3. This relationship is linear over seven orders of magnitude of explosive energy ranging from a 0.01 kg chemical explosion to a 100 kt nuclear explosion and is valid for a wide variety of saturated geological profiles. Underground chemical explosions, and probably underground nuclear explosions have the potential to induce liquefaction of water-saturated soils to scaled distances of about 260 m/(kt)^1/3.     

Comparative study of activation energies of conductance and desiccation rates of some marine algae

Measurements of the activation energy of electrical conductance and desiccation rates on subtidal marine algae from Florida were compared to similar data from the Bay of Fundy, Nova Scotia, on intertidal marine algae frequently subjected to long periods of exposure to air. We have developed a method for calculating the reaction rate constant of desiccation of fully hydrated marine algae. Values of activation energies and desiccation rate constants are consistent with the requirements for survival of these algae under widely different environmental conditions.     

Predicted signatures of pulsed reconnection in ESR data

Early in 1996, the latest of the European inco-herent-scatter (EISCAT) radars came into operation on the Svalbard islands. The EISCAT Svalbard Radar (ESR) has been built in order to study the ionosphere in the northern polar cap and in particular, the dayside cusp. Conditions in the upper atmosphere in the cusp region are complex, with magnetosheath plasma cascading freely into the atmosphere along open magnetic field lines as a result of magnetic reconnection at the dayside magnetopause. A model has been developed to predict the effects of pulsed reconnection and the subsequent cusp precipitation in the ionosphere. Using this model we have successfully recreated some of the major features seen in photometer and satellite data within the cusp. In this paper, the work is extended to predict the signatures of pulsed reconnection in ESR data when the radar is pointed along the magnetic field. It is expected that enhancements in both electron concentration and electron temperature will be observed. Whether these enhancements are continuous in time or occur as a series of separate events is shown to depend critically on where the open/closed field-line boundary is with respect to the radar. This is shown to be particularly true when reconnection pulses are superposed on a steady background rate.     

Subsidence breccias in kimberlite pipes—an application of fractal analysis

A particular variety of volcanogenic country rock breccia is described; a contact breccia that has been identified at Venetia, River Ranch and Wimbledon kimberlite pipes. The contact breccia is clast supported with no juvenile kimberlite component, has tightly packed, angular fragments (with occasional rounding of smaller particles), and has a shear-fabric dipping towards the center of each kimberlite pipe or volcanic event. Clasts have preferred orientations parallel to the fabric. Photographs of the breccia in the open pit face and measured data from drill core are analyzed specifically to quantify the clast size distributions and clast shapes by means of fractal analysis. The fractal dimension is one means of characterizing the breccia because the dimension can be specific to a fragmentation mechanism. Clast size distribution fractal dimensions in the coarser particles (greater than circa 3 cm) range from greater than 3 for nonsheared breccia, down to circa 2.3 for the sheared breccia. Breccia characterization based on this fractal analysis suggests that fragmentation occurred initially from confined high-energy explosions, followed by collapse and abrasion by subsequently gravity-induced rockmass subsidence. All studied contact breccias produced a distinctive fractal signature in the finer particles (<3 cm) of circa 1.6 that can be explained by a comminution fragmentation process in that particular particle size range. It is suggested that these subsidence breccias require a substantial volume deficit at depth within the volcanic pipe in order to explain their origin and size. The methodology used in this study could be used to characterize any other volcanic breccia and further model their origins.     

Comparison of llama fiber obtained from two production regions of Argentina

The Puna is an arid region running along the Andes mountains, more than 3600 m above sea level. Overgrazing has severely degraded much of this ecosystem, and this has dramatically reduced agricultural production and resulted in poverty for human inhabitants. Llamas are native to the Puna and are well suited to live there. Their grazing habits and digestive system make efficient use of native forages, and their padded feet keep soil disturbance to a minimum, thereby reducing erosion. Uncontrolled llama breeding over the last 500 years has degraded the quality of the fiber they produce, so today it is generally of low quality. Analysis of llama fibers obtained from two production regions of Argentina showed that some llamas possess sufficiently fine mean fiber diameters (less than 23 μm if guard hairs are excluded) to allow their fleeces to be sold at a premium. A higher price would make llamas more attractive to raise than the goats and sheep commonly found in the Puna today. Switching to llama production would increase grower income and sustainability of agriculture in the region.     

Fabric studies within the Cascade Lake shear zone, Sierra Nevada, California

The Cascade Lake shear zone occurs on the eastern margin of the Tuolumne Intrusive Suite, Sierra Nevada Batholith, California. Foliation in the zone is NNW trending and subvertical, and lineation is moderately south plunging. Deformation is syn-tectonic with emplacement of the Cathedral Peak granodiorite. A deformation gradient exists toward the NE margin of this pluton, with higher strains and lower temperatures of deformation found near the contact. We compare fabric data collected very densely in this shear zone using several techniques: field fabrics, 3D orientation of K-feldspar megacrysts, and AMS (anisotropy of magnetic susceptibility) analysis. In general, the results from the three different methods are in agreement. Deformation in this shear zone is part of a larger pattern of deformation within the Cathedral Peak granodiorite, as recorded by AMS analysis, and dextral shearing associated within the last stage of plutonism within the Sierra Nevada magmatic arc.