Characterizing hyporheic transport processes — Interpretation of electrical geophysical data in coupled stream–hyporheic zone systems during solute tracer studies

Quantifying hyporheic solute dynamics has been limited by our ability to assess the magnitude and extent of stream interactions with multiple domains: mobile subsurface storage (MSS, e.g., freely flowing pore water) and immobile subsurface storage (ISS, e.g., poorly connected pore water). Stream-tracer experiments coupled with solute transport modeling are frequently used to characterize lumped MSS and ISS dynamics, but are limited by the ability to sample only “mobile” water and by window of detection issues. Here, we couple simulations of near-surface electrical resistivity (ER) methods with conservative solute transport to directly compare solute transport with ER interpretations, and to determine the ability of ER to predict spatial and temporal trends of solute distribution and transport in stream–hyporheic systems. Results show that temporal moments from both ER and solute transport data are well correlated for locations where advection is not the dominant solute transport process. Mean arrival time and variance are especially well-predicted by ER interpretation, providing the potential to estimate rate-limited mass transport (i.e. diffusive) parameters from these data in a distributed domain, substantially increasing our knowledge of the fate and transport of subsurface solutes.     

Microbial hydrocarbon gases in the Witwatersrand Basin, South Africa: Implications for the deep biosphere

In this study, compositions and δ¹³C and δ²H isotopic values of hydrocarbon gases from 5 mines in the Witwatersrand basin, South Africa, support the widespread occurrence of microbially produced methane in millions of years-old fissure waters. The presence of microbial methane is, to a large extent, controlled by the geologic formations in which the gases are found. Samples from the Witwatersand Supergroup have the largest microbial component based on δ¹³C and δ²H signatures and CH₄/C₂+ values. Based on mixing between a microbial CH₄ component and a more ¹³C-enriched and ²H-depleted C₂+-rich end member, conservative estimates of the % contribution of microbial CH₄ to the gas samples range from >90% microbial CH₄ at Beatrix, Masimong, and Merriespruit, to between 5 and 80% microbial CH₄ at Evander, and <18% microbial CH₄ at Kloof. The Witwatersrand basin’s history of thermal alteration of organic-rich ancient sedimentary units suggests a thermogenic origin for this ¹³C-enriched end member. Alternatively, the potential for an abiogenic origin similar to hydrocarbon gases produced by water-rock interaction at other Precambrian Shield mines is discussed. Microbial methane is predominantly found in paleo-meteoric fissure waters with δ¹⁸O and δ²H values that fall on the meteoric waterline, and have temperatures between 30 to 40°C. In contrast, fissure waters with a larger component of nonmicrobial hydrocarbon gases show a trend towards more enriched δ¹⁸O and δ²H values that fall well above the meteoric waterline, and temperatures of 45 to 60°C. The enrichment in ¹⁸O and ²H in these samples, and their high salinity, are similar to the isotopic and compositional characteristics of saline groundwaters and brines produced by water-rock interaction at Precambrian Shield sites elsewhere. The reported 100 Ma ages of fissure waters from the Witwatersrand and Ventersdorp formations suggest that these microbial hydrocarbon gases are the product of in situ methanogenic communities in the deep subsurface of the Witswaterand basin. Small subunit ribosomal RNA genes were amplified using archaeal-specific primer sets from DNA extracts derived from several of these waters. Fissure waters with a high proportion of microbial methane also contained sequences resembling those of known methanogens.     

Mineral matter and trace elements in coals of the Gunnedah Basin, New South Wales, Australia

The concentrations of major and trace inorganic elements in a succession of Permian coals from the Gunnedah Basin, New South Wales, have been determined by X-ray fluorescence techniques applied to both whole-coal and high-temperature ash samples. The results have been evaluated in the light of quantitative data on the minerals in the same coals, determined from X-ray diffraction study of whole-coal samples using a Rietveld-based interpretation program ( ™), to determine relationships of the trace elements in the coals to the mineral species present. Comparison of the chemical composition of the coal ash interpreted from the quantitative mineralogical study to the actual ash composition determined by XRF analysis shows a high degree of consistency, confirming the validity of the XRD interpretations for the Gunnedah Basin materials. Quartz, illite and other minerals of detrital origin dominate the coals in the upper part of the sequence, whereas authigenic kaolinite is abundant in coals from the lower part of the Permian succession. These minerals are all reduced in abundance, however, and pyrite is a dominant constituent, in coals formed under marine influence at several stratigraphic levels. Calcite and dolomite occur as cleat and fracture infillings, mostly in seams near the top and bottom of the sequence. The potassium-bearing minerals in the detrital fraction are associated with significant concentrations of rubidium, and the authigenic kaolinite with relatively high proportions of titanium. Zirconium is also abundant, with associated P and Hf, in the Gunnedah Basin coal seams. Relationships exhibited by Ti, Zr, Nd and Y are consistent with derivation of the original sediment admixed with the seams from an acid volcanic source. Pyrite in the coals is associated with high concentrations of arsenic and minor proportions of thallium; no other element commonly associated with sulphides in coals, however, appears to occur in significant proportions with the pyrite in the sample suite. Small concentrations of Cl present in the coal are inversely related to the pyrite content, and appear to represent ion-exchange components associated with the organic matter. Strontium and barium are strongly associated with the cleat-filling carbonate minerals. Ge and Ga appear to be related to each other and to the coal's organic matter. Cr and V are also related to each other, as are Ce, La, Nd and Pr, but none of these show any relationship to the organic matter or a particular mineral component.     

Creation of Temperate-Climate Intertidal Mudflats: Factors Affecting Colonization and Use by Benthic Invertebrates and their Bird Predators

Colonization of a recreated area of intertidal land by marine invertebrates and their bird predators was studied from April 1993 to August 1997. The most important food of large shorebirds, the ragworm Nereis diversicolor, did not reappear until late summer 1995 and did not become abundant until the following autumn. Annual attempts at colonization by the crustacean Corophium volutator, the main food of several small shorebird species, failed until summer 1996 when animals survived through the subsequent winter for the first time. Colonization by the mud-snail Hydrobia ulvae took place a year after flooding of the site, but densities in 1997 were still well below those found elsewhere on the adjacent estuary.

The delay in successful colonization by Nereis and Corophium may be attributable in part to the compaction of the intertidal muds caused by the earthmoving equipment used to contour the site. The slow increase in Hydrobia density may be a consequence of low organic content of the mud. Bird use is concentrated chiefly during the hours when the adjacent estuarine mudflats (with unrestricted tidal flow) are covered by the tide, since the new site then provides a supplementary feeding area. Peak daytime usage occurs during the migratory passage periods when birds need to feed for longer periods than usual, in order to refuel for their migrations; high usage is also anticipated in cold winters.

On this evidence, creation of intertidal areas in mitigation for any lost nearby to industrial or other development should take place at least three years before the losses, in order to make the new areas profitable for feeding waterfowl.     

Riparian vegetation and island formation along the gravel‐bed Fiume Tagliamento,Italy

After more than 300 years of river management, scientific knowledge of European river systems has evolved with limited empirical knowledge of truly natural systems. In particular, little is known of the mechanisms supporting the evolution and maintenance of islands and secondary channels. The dynamic, gravel‐bed Fiume Tagliamento, Italy, provides an opportunity to acquire baseline data from a river where the level of direct engineering intervention along the main stem is remarkably small. Against a background of a strong alpine to mediterranean climatic and hydrological gradient, this paper explores relationships between topography, sediment and vegetation at eight sites along the active zone of the Tagliamento. A conceptual model of island development is proposed which integrates the interactions between large woody debris and vegetation, geomorphic features, sediment calibre and hydrological regime. Islands may develop on bare gravel sites or be dissected from the floodplain by channel avulsion. Depositional and erosional processes result in different island types and developmental stages. Differences in the apparent trajectories of island development are identified for each of the eight study sites along the river. The management implications of the model and associated observations of the role of riparian vegetation in island development are considered. In particular, the potential impacts of woody debris removal, riparian tree management, regulation of river flow and sediment regimes, and changes in riparian tree species' distribution are discussed. Copyright © 2001 John Wiley & Sons, Ltd.     

Anthropogenic influences on groundwater in the vicinity of a long‐lived radioactive waste repository

The groundwater flow system in the Culebra Dolomite Member (Culebra) of the Permian Rustler Formation is a potential radionuclide release pathway from the Waste Isolation Pilot Plant (WIPP), the only deep geological repository for transuranic waste in the United States. In early conceptual models of the Culebra, groundwater levels were not expected to fluctuate markedly, except in response to long‐term climatic changes, with response times on the order of hundreds to thousands of years. Recent groundwater pressures measured in monitoring wells record more than 25 m of drawdown. The fluctuations are attributed to pumping activities at a privately owned well that may be associated with the demand of the Permian Basin hydrocarbon industry for water. The unprecedented magnitude of drawdown provides an opportunity to quantitatively assess the influence of unplanned anthropogenic forcings near the WIPP. Spatially variable realizations of Culebra saturated hydraulic conductivity and specific storage were used to develop groundwater flow models to estimate a pumping rate for the private well and investigate its effect on advective transport. Simulated drawdown shows reasonable agreement with observations (average Model Efficiency coefficient = 0.7). Steepened hydraulic gradients associated with the pumping reduce estimates of conservative particle travel times across the domain by one half and shift the intersection of the average particle track with the compliance boundary by more than 2 km. The value of the transient simulations conducted for this study lies in their ability to (a) improve understanding of the Culebra groundwater flow system and (b) challenge the notion of time‐invariant land use in the vicinity of the WIPP.     

Sediment dynamics below retreating cliffs

The retreat of cliffs may constitute the dominant erosional response to base‐level fall in arid settings underlain by horizontally‐bedded sedimentary rock. These vertical cliffs typically loom above a relatively straight bedrock slope (‘plinth’) that is mantled with a thin layer of sediment and perched near the angle of repose. In detail, a plinth consists of a system of quasi‐parallel ridges and channels. We ask how the sediment supplied from a retreating cliff influences the erosion of the plinth hillslopes and channels, and how this affects the rate of cliff retreat. Motivated by field observations and high‐resolution topographic data from two sites in western Colorado, we develop a two‐dimensional (2D), rules‐based numerical model to simulate the erosion of channels draining a plinth and diffusive erosion of the intervening interfluves. In this model, retreat of a cliffband occurs when the height of the vertical cliff exceeds a threshold due to incision by channels on the plinth below. Debris derived from cliff retreat is distributed over the model plinth according to the local topography and distance from the source. This debris then weathers in place, and importantly can act to reduce local bedrock erosion rates, protecting both the plinth and ultimately the cliff from erosion. In this paper, we focus on two sets of numerical model experiments. In one suite, we regulate the rate of rockfall to limit the cliff retreat rate; in most cases, this results in complete loss of the plinth by erosion. In a second suite, we do not impose a limit on the cliff retreat rate, but instead vary the weathering rate of the rockfall debris. These runs result in temporally steady cliff‐plinth forms and retreat rates; both depend on the weathering rate of the debris. Copyright © 2011 John Wiley & Sons, Ltd.     

Coastal dunes and strandplains in southeast Queensland: Sequence and chronology

Parabolic dunes invade coastal strandplains and overlie prior blown dunes in southeast Queensland. These coastal dune landscapes were produced primarily by real changes in wind strength and frequency. Sand movement began in past glacial ages and in the most recent instance persisted into Holocene time. Four interglacial shores are identified with marine isotope stages 5, 7, 9 and 11, and allow estimation of the ages of the dune and beach sands, by correlation with the EPICA Dome C ice core, as follows: Triangle dune sand, n.d.; Garawongera dune sand, 65 ka; Woorim beach sand, 125 ka; Bribie beach sand, 245 ka; Bowarrady dune sand, 270 ka; Poyungan beach sand, 335 ka; Yankee Jack dune sand, 360 ka; Ungowa beach sand, 410 ka; Awinya dune sand, 430 – 486 ka; Cooloola dune sand, >486 ka.     

Frequency management support for remote sea-state sensing using the JINDALEE skywave radar

Successful operation of a skywave (over-the-horizon, OTH) radar in a remote sea-state sensing mode is critically dependent upon the application of comprehensive frequency management techniques. In addition to the problem of selecting a frequency yielding an adequate signal-to-noise ratio in the geographical area under investigation, attention must be paid to minimization of ionospheric multimode and other phenomena capable of distorting or convoluting the sea backscatter spectrum. This paper describes the manner in which these problems have been addressed in the JINDALEE skywave radar, and relates the practical difficulties inherent in the task of frequency management in support of an OTH radar involved in sea-state sensing. Measurement techniques include backscatter and oblique-incidence sounding, HF spectral surveillance, and a low-powered frequency-agile "miniradar" capable of operating in either a conventional backscatter or alternate oblique-incidence mode. In addition to providing the main radar with real-time frequency management advice, a principal emphasis has been the acquisition of a synoptic data base suitable for off-line statistical analysis.