Relationship between substrate concentration and oxidation of ammonium and methane in a stratified water column

Distributions and oxidation rates of methane and ammonium were investigated during two cruises in Saanich Inlet, British Columbia in late summer. Distributions of inorganic nutrients were related to oxygen distribution, exhibiting large gradients associated with the oxic-anoxic interface. The depth distributions of oxidation rates were also defined by the oxic-anoxic interface: ammonium oxidation occurred at variable rates (up to 120 nM day⁻¹) between the photic zone and the oxic-anoxic interface. Methane oxidation occurred throughout the oxic layer and increased near the interface. The possibility of interactions such as inhibition and competition between the two substrates, methane and ammonium, were investigated in kinetic experiments. Ammonium oxidation rate was independent of both ammonium and methane concentrations. Methane oxidation rates were linearly related to methane concentration, both in manipulation experiments, and in relation to ambient methane concentrations. There was no evidence of interaction between methane and ammonium as alternative substrates for methanotrophic and ammonium oxidizing populations, which were both present in the environment. In September, we observed a bolus-type mixing event, which introduced oxygenated deep water into the inlet beneath a wedge of anoxic, methane-rich water. This kind of event is probably important in determining the rate of methane loss, due to increased microbial oxidation at the boundaries of the anoxic wedge.     

Bubble coalescence in basalt flows: comparison of a numerical model with natural examples

Gas accumulation in magma may be aided by coalescence of bubbles because large coalesced bubbles rise faster than small bubbles. The observed size distribution of gas bubbles (vesicles) in lava flows supports the concept of post-eruptive coalescence. A numerical model predicts the effects of rise and coalescence consistent with observed features. The model uses given values for flow thickness, viscosity, volume percentage of gas bubbles, and an initial size distribution of bubbles together with a gravitational collection kernel to numerically integrate the stochastic collection equation and thereby compute a new size spectrum of bubbles after each time increment of conductive cooling of the flow. Bubbles rise and coalesce within a fluid interior sandwiched between fronts of solidification that advance inward with time from top and bottom. Bubbles that are overtaken by the solidification fronts cease to migrate. The model predicts the formation of upper and lower vesicle-rich zones separated by a vesicle-poor interior. The upper zone is broader, more vesicular, and has larger bubbles than the lower zone. Basaltic lava flows in northern California exhibit the predicted zonation of vesicularity and size distribution of vesicles as determined by an impregnation technique. In particular, the size distribution at the tops and bottoms of flows is essentially the same as the initial distribution, reflecting the rapid initial solidification at the bases and tops of the flows. Many large vesicles are present in the upper vesicular zones, consistent with expected formation as a result of bubble coalescence during solidification of the lava flows. Both the rocks and model show a bimodal or trimodal size distribution for the upper vesicular zone. This polymodality is explained by preferential coalescence of larger bubbles with subequal sizes. Vesicularity and vesicle size distribution are sensitive to atmospheric pressure because bubbles expand as they decompress during rise through the flow. The ratio of vesicularity in the upper to that in the lower part of a flow therefore depends not only on bubble rise and coalescence, but also on flow thickness and atmospheric pressure. Application of simple theory to the natural basalts suggests solidification of the basalts at 1.0±0.2 atm, consistent with the present atmospheric pressure. Paleobathymetry and paleoaltimetry are possible in view of the sensitivity of vesicle size distributions to atmospheric pressure. Thus, vesicular lava flows can be used to crudely estimate ancient elevations and/or sea level air pressure.     

Mineral matter in triassic and tertiary low-rank coals from South Australia

The minerals and non-mineral inorganic constituents in Triassic and Tertiary low-rank coals from various coal deposits in South Australia were studied using selective chemical leaching and oxygen-plasma ashing techniques. Although gypsum may be present in some samples, most of the sodium, calcium and magnesium, as well as part of the sulphur, appears to occur as a combination of dissolved ions in pore water and exchangeable ions attached to carboxylate groups. Significant concentrations of iron and aluminium occur in acid-soluble form, probably as organometallic complexes within the hydrocarbon structure.Quartz is the dominant mineral in the Tertiary coal samples. It appears to be mainly detrital, but doubly terminated euhedral crystals suggest an authigenic origin in one of the deposits. Well crystallized kaolinite is common in the Triassic coals, while poorly crystallized kaolinite occurs in the Tertiary samples. Siderite, calcite and possibly collophane occur in the Triassic coals; sparse pyrite is present in both the Tertiary and the Triassic samples.The differences in minerals and other inorganic constituents between the Tertiary and Triassic deposits can be explained partly by variations in the composition of the pore waters permeating the strata, and partly by mobility of silica and alumina from different sources within the peat deposit. The relative mobility of the different inorganic constituents is also significant in beneficiation of the coal for use in combustion processes.     

The astronomical theory of climatic change on Mars

We examine the response of Martian climate to changes in solar energy deposition caused by variations of the Martian orbit and obliquity. We systematically investigate the seasonal cycles of carbon dioxide, water, and dust to provide a complete picture of the climate for various orbital configurations. We find that at low obliquity (15°) the atmospheric pressure will fall below 1 mbar; dust storms will cease; thick permanent CO₂ caps will form; the regolith will release CO₂; and H₂O polar ice sheets will develop as the permafrost boundaries move poleward. At high obliquity (35°) the annual average polar temperature will increase by about 10°K, slightly desorbing the polar regolith and causing the atmospheric pressure to increase by not more than 10 to 20 mbar. Summer polar ground temperatures as high as 273°K will occur. Water ice caps will be unstable and may disappear as the equilibrium permafrost boundary moves equatorward. However, at high eccentricity, polar ice sheets will be favored at one pole over the other. At high obliquity dust storms may occur during summers in both hemispheres, independent of the eccentricity cycle. Eccentricity and longitude of perihelion are most significant at modest obliquity (25°). At high eccentricity and when the longitude of perihelion is close to the location of solstice hemispherical asymmetry in dust-storm generation and in polar ice extent and albedo will occur.The systematic examination of the relation of climate and planetary orbit provides a new theory for the formation of the polar laminae. The terraced structure of the polar laminae originates when eccentricity and/or obliquity variations begin to drive water ice off the dusty permanent H₂O polar caps. Then a thin (meters) layer of consolidated dust forms on top of a dirty, slightly thicker (tens of meters) ice sheet and the composite is preserved as a layer of laminae composed predominately of water ice. Because of insolation variation on slopes, a series of poleward- and equatorward-facing scarps are formed where the edges of the laminae are exposed. Independently of orbital variations, these scarps propagate poleward both by erosion of the equatorward slopes and by deposition on the poleward slopes. Scarp propagation resurfaces and recycles the laminae forming the distinctive spiral bands of terraces observed and provides a supply of water to form new permanent ice caps. The polar laminae boundary marks the furthest eqautorward extension of the permanent H₂O caps as the orbit varies. The polar debris boundary marks the furthest equatorward extension of the annual CO₂ caps as the orbit varies.The Martian regolith is now a significant geochemical sink for carbon dioxide. CO₂ has been irreversibly removed from the atmosphere by carbonate formation. CO₂ has also benn removed by regolith adsorption. Polar temperature increases caused by orbital variations are not great enough     

Quantifying Turbulence Heterogeneity in a Vineyard Using Eddy-Covariance and Scintillometer Measurements

Boundary-Layer Meteorology - Scintillometry is a non-invasive measurement technique for acquiring spatially-averaged surface heat and moisture fluxes in areas where setting up arrays of instruments...     

A comparison of landslide rates following helicopter and conventional cable-based clear-cut logging operations in the Southwest Coast Mountains of British Columbia

A comparison of landslide rates following helicopter and conventional, cable-based, clear-cut logging was carried out using results from two independent terrain attribute studies in the Eldred and Lois River watersheds in the Southwest Coast Mountains of British Columbia. Landslides initiating from directly within a road prism were excluded from the study in order to focus the comparison on landslides related primarily to conventional versus helicopter yarding methods. A landslide rate of 0.02 landslides/ha was observed in 162 terrain polygons logged by helicopter 8 years prior to this study. Landslide rates in 38 gullied polygons were 0.06 landslides/ha. No landslides were observed in 124 open-slope polygons. Over a similar 8-year average period, 0.03 landslides/ha were observed in 142 cable-yarded terrain polygons; 0.06 and 0.02 landslides/ha occurred in gullied and open-slope polygons, respectively. t-Tests indicate that total landslide rates are not significantly different following helicopter and conventional logging; however, a dichotomy exists between gullied and open-slope terrain polygons. Landslide rates are not significantly different in gullied terrain but are significantly higher on open-slopes following conventional cable logging. Consequently, landslides appear to have a greater potential to occur in open-slope terrain following conventional logging, but differences in gullied polygons are less likely. Increased post-logging landslide rates in conventionally logged, open slopes are more likely the result of undetected road-related drainage changes than differences between helicopter and conventional yarding-related ground disturbance.