Abnormal composition of carbon isotopes in underground alkaline waters of Kuzbass

The first data on abnormally high δ¹³С values in hydrocarbonates (НСО ₃^-) dissolved in underground waters of coal deposits of Kuzbass (up to +30.9‰) are reported. It is shown that such an unusual isotope composition of waters results from the long, strictly directed interaction in the water–rock–gas–organic material system occurring under the conditions of hindered water exchange. Extensive fractionation of C isotopes is the result of the evolution of the water–rock–gas–coal system after penetration of infiltration waters into the coal deposits and their long interaction with all these components, rather than metamorphism of organic material upon its transformation into coal. With respect to such an approach, the isotope composition of dissolved C may indicate the duration of the evolution in the water–rock–gas–organic material system.     

Petrophysical features of the tectonic structures of the Okhotsk continent–ocean transition zone

Petrophysical characteristics are determined for the rock complexes of the Okhotsk margin within the continent–ocean transition zone. Petrophysical maps showing the major inhomogeneities of the main tectonic elements of the studied area are constructed. Petrophysical inhomogeneities and the corresponding geophysical field anomalies are compared. A relationship between the magnetic field anomalies and subsurface rock complexes is revealed. The gravity field anomalies are related to deep inhomogeneities and are almost independent of the subsurface rock complexes of relatively low thickness.     

Rapid incorporation of lipids into macromolecules during experimental decay of invertebrates: Initiation of geopolymer formation

Diagenetic alteration is critical for the preservation of fossil cuticles of plant and animal origin and to the formation of kerogen. The process takes place over millions of years, but the stage at which it is initiated is not known. Laboratory decay experiments were carried out on shrimps, scorpions and cockroaches to monitor changes in the chitin–protein of the arthropod cuticle and associated lipids. The cockroach and scorpion exoskeleton remained largely unaltered morphologically, but the shrimp experienced rapid decomposition within a month, which progressed through the 44 week duration of the experiment as revealed using electron microscopy. Mass spectrometry and ¹³C NMR (nuclear magnetic resonance) spectroscopy revealed the association of an n-alkyl component with labile lipids, such as fatty acids with up to 24 carbon atoms, which were incorporated into the decaying macromolecule. The scorpion and cockroach cuticle did not reveal the incorporation of additional lipids, indicating that decay is important in initiating in situ lipid association. This experiment provides evidence that lipids can become associated with carbohydrate and proteinaceous macromolecules during the very early stages of decay, representing the first stage in the transformation process that contributes to the aliphatic rich composition ubiquitous in organic fossils and kerogen.     

Granitoids of the Ufalei block (South Urals): Sr-Nd isotope systematics, geodynamic position and genetic reconstructions

Petrogeochemical and isotopic-geochronological signatures in granitoids developed in structures with complex geological history represent an important feature for reconstructing paleogeodynamic settings. Granitoids are widespread in the western slope of the Urals, where the Uralian Orogen contacts via a collage of different-age blocks of the east European Platform. The Ufalei block located in the Central Urals megazone at the junction between the South and Middle Urals’ segments represents one such boundary structure with multistage geological evolution. The isotopic ages obtained by different methods for acid igneous rocks range from 1290 to 245 Ma. We determined close Rb-Sr and Sm-Nd ages (317 Ma) for granites of the Nizhnii Ufalei Massif. By their petrochemical parameters, granitoids and host granite-gneisses differ principally from each other: the former are close to subduction-related, while the latter, to continental-riftogenic varieties. The primary ratio (⁸⁷Sr/8⁶Sr)₀ = 0.70428 and ?_Nd ≈ +4 values indicate significant contribution of oceanic (island-arc?) material to the substrate, which served as a source for granites of the Nizhnii Ufalei Massif. Model Nd ages of granites vary from 641 to 550 Ma. Distinct oceanic rocks and varieties with such ages are missing from the surrounding structures. New isotopic dates obtained for ultramafic and mafic rocks from different zones of the Urals related to the Cadomian cycle imply development of unexposed Upper Riphean-Vendian “oceanic” rocks in the central part of the Ufalei block, which played a substantial role in the formation of the Nizhnii Ufalei granitoids. Such rocks could be represented, for example, by fragments of the Precambrian Timanide-type ophiolite association. The analysis of original materials combined with published data point to the heterogeneous composition and structure of the Ufalei block and a significant part of the western segment of the Central Uralian Uplift and extremely complex geological history of the region coupling the Uralian Orogen with the East European Platform in the present-day structure.     

Statistical Distributions of Hydraulic Conductivity from Reliability Analysis Data

This paper describes a first-order reliability-based analysis to identify the best-fit probability distributions for hydraulic conductivity. The analysis involved the use of existing hydraulic conductivity model developed from laboratory data and applied to lateritic soils, considering variations in soil parameters. Plots of reliability indices versus coefficients of variation were first made for hydraulic conductivity as well as for initial degree of saturation, plasticity index and clay content, considering three compactive efforts and log-normally distributed hydraulic conductivity. The traditional two-parameter log-normal distribution was compared to four alternative distributions: normal, gamma, Gumbel (extreme value type I-EVT-I) and Weibull (extreme value type III-EVT-III). The analysis showed that the Weibull and normal are the best-fit probability distributions for the hydraulic conductivity based reliability data. Hydraulic conductivities predicted from reliability analysis were used to demonstrate the possibility of applying the results obtained in this research by practising engineers. Experimentally-determined hydraulic conductivities were shown to be in good agreement with predicted values.     

Atomistic calculations of structural and elastic properties of serpentine minerals: the case of lizardite

The physical properties of the hydrous phyllosilicate lizardite have been investigated by atomistic simulation using the GULP code based on transferable semi-empirical interatomic potentials. Lizardite behavior was first investigated during structure relaxation at room temperature. The Helmholtz free energy is minimum for an equilibrium structure that is in agreement with experiment. The bulk, shear, and Young modulii for lizardite were calculated along with the Poisson ratio. From the shear and bulk modulii, we also calculated translational and longitudinal acoustic wave velocities that are important quantities for tectonophysics models. As expected, lizardite is stiffer in the a direction parallel to the layers than in the c perpendicular direction; the variation of the unit cell parameters with pressure is in good agreement with experiment. The cohesive energy between two successive layers along c direction was calculated at 0.33 eV (i.e., 0.11 eV per OH bond) in good agreement with recent ab initio calculations. Upon pressure and temperature variations, we evidenced that structural changes are mainly pressure induced; pressure being accommodated by a decrease of the c parameter up to 10 GPa. We also found that the change of slope in the derivative of the c cell parameter with respect to pressure occurring around 2 GPa originates from the bending of the interlayer hydroxyl groups with respect to the layer normal direction.     

Cyclic variations in the differential rotation of the solar corona

The rotation of the solar corona is analyzed using the original database on the brightness of the FeXIV 530.3 nm coronal green line covering six recent activity cycles. The rate of the differential rotation of the corona depends on the cycle phase. In decay phases, there are only small differences in the rotation, which are similar to that of a rigid body. The differences are more significant (though less pronounced than in the photosphere) during rise phases, just before maxima, and sometimes at maxima. The total rate of the coronal rotation is represented as a superposition of two, i.e., fast and slow modes. The synodic period of the fast mode is approximately 27 days at the equator and varies slightly with time. This mode displays weak differences in rotation and is most pronounced in the middle of decay phases. The slow mode is manifested only at high latitudes during the rise phases of activity, and displays a mean period of 31 days. The relative contribution of each mode to the total rotational rate is determined as a function of time and heliographic latitude. These results indicate that the structure of the velocity field in the convective zone must also vary with time. This conclusion can be verified by helioseismology measurements in the near future.     

A Petrologic Perspective of Kilauea Volcano's Summit Magma Reservoir

Two hundred years of magmatic history are documented by thelavas and tephra sampled from K