Friction characteristics of Cd-rich carbonate films on calcite surfaces: implications for compositional differentiation at the nanometer scale

Lateral Force Microscopy (LFM) studies were carried out on cleaved calcite sections in contact with solutions supersaturated with respect to otavite (CdCO₃) or calcite-otavite solid solutions (SS) as a means to examine the potential for future application of LFM as a nanometer-scale mineral surface composition mapping technique. Layer-by-layer growth of surface films took place either by step advancement or by a surface nucleation and step advancement mechanisms. Friction vs. applied load data acquired on the films and the calcite substrate were successfully fitted to the Johnson Kendall Roberts (JKR) model for single asperity contacts. Following this model, friction differences between film and substrate at low loads were dictated by differences in adhesion, whereas at higher load they reflect differences in contact shear strength. In most experiments at fixed load, the film showed higher friction than the calcite surface, but the friction-load dependence for the different surfaces revealed that at low loads (0–40 nN), a calcian otavite film has lower friction than calcite; a result that is contrary to earlier LFM reports of the same system. Multilayer films of calcian-otavite displayed increasing friction with film thickness, consistent with the expectation that the film surface composition will become increasingly Cd-rich with increasing thickness. Both load- and thickness-dependence trends support the hypothesis that the contact shear strength correlates with the hydration enthalpy of the surface ions, thereby imparting friction sensitivity in the LFM to mineral-water interface composition.     

Noble gas and carbon abundances of the Haverö, Dingo Pup Donga,and North Haig ureilites

Total carbon determinations on the Haverö, Dingo Pup Donga, and North Haig ureilites yield values of 2.07, 3.17, and 5.58 wt.%, respectively. Haverö and Dingo Pup Donga contain relatively large amounts of trapped Ar, Kr and Xe, which like the carbon content varies with grain size for Haverö. These two meteorites also contain dominant cosmic rayproduced He and Ne, and show ³He exposure ages of ~23 m.y. and ~7 m.y., respectively. North Haig contains much smaller amounts of trapped gases and spallogenic gases, which may result from loss due to terrestrial weathering. The isotopic composition of Xe in five grain size analyses of Haverö and a whole rock analysis of Dingo Pup Donga shows the presence of a major solar-like Xe component. The presence of this solar component adds an additional complication to the concept of forming ureilites from carbonaceous chondrites.     

Considerations on the seismotectonics of the Northern Apennines

The Northern Apennines have been subdivided into homogeneous zones, on the basis of recent structural evolution and crustal structure, in which the earthquake distribution can find a coherent framework. These zones, whose physiography is in strict connection with their structure, are: the Internal Peri-Tyrrhenian Belt; the External or Main Belt; the Buried Belt; and the Pede-Alpine Homocline. Earthquake activity has a tendency to cluster along well-defined bands, particularly in the easternmost border of the Peri-Tyrrhenian Belt, as well as along the zone between the External Belt and the Buried Belt, i.e. along the Padanian margin of the Northern Apennines.A minimum of seismic activity seems to be correlated with some zones of the External Belt, as well as with the Late Tertiary and Quaternary magmatic province of Tyrrhenian Southern Tuscany.The fault-plane solutions are coherent with the structural picture.A tentative seismotectonic model of the Northern Apennines is discussed.     

Theoretical density distribution of plasma streaming around a cylinder

The distribution of plasma density around a metallic cylinder in a collisionfree plasma is determined by the system of Vlassov equations and the Poisson equation. The plasma may have a streaming velocity perpendicular to the cylinder axis producing a wake behind the cylinder. In the region outside a thin double layer at the cylinder surface the problem allows some simplification. Then numerical solutions become possible-even if the streaming velocity is low. Some numerical solutions are presented. A magnetic field produces an asymmetric shape of the wake, if the gyration radius of the ion becomes comparable to the cylinder radius.     

Refined relationship between the position of the fundamental OH stretching and the first overtones for clays

The aim of this paper is to determine a relationship between the wavenumbers of the first OH-stretching overtones (W_2OH) and the wavenumbers of the OH-stretching fundamentals (W_OH) to help to interpret the near-infrared (NIR) spectra. The first overtone (2OH) bands appear at wavenumbers less than twice those of the fundamental bands (OH), due to the anharmonic character of vibrations, X = W_2OH/2 - W_OH, with X being the anharmonicity constant. Talc samples with various crystal chemistries are used to solve the equation and the experimental data are well fitted with X = –85.6 cm^–1. As far as the authors are aware, it is the first time that the anharmonicity constant for the OH-stretching vibrations is determined for phyllosilicates. The anharmonicity constant remains almost unchanged for several types of clay samples. Therefore the relation, established from talc samples because their absorption bands are narrow and their wavenumber range of OH vibrations is wide, can be used for any other clay minerals.     

CONGRESS AND THE CHANGING DISTRIBUTION OF FEDERAL OUTLAYS,FY81-FY86*

Did Congressional influence play a role in the distribution of federal outlays between FY81 and FY86? This study hypothesizes that states with majority party House and Senate delegations and with seniority in the delegations experienced the largest increases in federal expenditures. These two hypotheses are tested for fifteen divisions of federal outlays using a stepwise regression model. The results provide only very modest evidence of any systematic Congressional influence over changes in the distribution of federal outlays during the study period.     

Hydromorphology of a part of Azamgarh and Ghazipur districts,Uttar Pradesh

Hydrogeological studies in the Quaternary alluvial plain of a part of Azamgarh and Ghazipur districts, using air photos on scale 1:60,000 indicate the presence of five hydromorphic units namely, Alluvial upland, older alluvial plain of Mangat-Besu, older flood plain of Ganga—Gomti, youngest terrace of Ganga—Gomti and present flood plain of Ganga-Gomti. From the groundwater point of view older flood plain of Ganga—Gomti is the most promising hydromorphic unit. Abandoned channel of river Ganga offers favourable site for deep groundwater exploration with high potentiality. Chemical quality of shallow and deep aquifers is suitable for irrigation and other purposes.