Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine

To investigate the solubility and the sites of incorporation of hydrogen in olivine as a function of point defect concentration, two-stage high-temperature annealing experiments have been carried out. The first annealing stage (the dry preannealing stage) was conducted at a total pressure of 0.1 MPa, a temperature of 1300° C and various oxygen fugacities in the range 10^?11–10^?4 MPa for times > 12 h. In these heat treatments, the samples were buffered against either orthopyroxene or magnesiowustite, or they remained unbuffered. The second annealing stage (the hydrothermal annealing stage) was performed at 300 MPa and 900–1050 ° C under a hydrogen fugacity of ～ 158 MPa for 1–5 h. Infrared spectra from the annealed samples revealed two distinct groups of bands. Group I bands occurred at wavenumbers in the range 3450–3650 cm^?1, while Group II bands occurred in the range 3200–3450 cm^?1. The hydrogen solubility associated with Group I bands is proportional to f _{O 2} to the 1/6 power for samples preannealed in contact with orthopyroxene, to the 1/3 power for samples preannealed in contact with magnesiowustite, and to the 1/13 power for samples preannealed in the absence of a solid-state buffer. The hydrogen concentration for Group II bands varies with f _{o 2} to the 1/3 power for opxbuffered samples, to the 1/2 power for mw-buffered samples, and to the 1/3 power for unbuffered samples. The dependence of hydrogen solubility on oxygen fugacity and orthopyroxene activity suggests that hydrogen is incorporated into the olivine structure via association with point defects. The presence of two distinct groups of absorption bands indicates that hydrogen is associated with two distinct lattice defects. The following point defect model for the mechanism of incorporation of hydrogen in olivine is consistent with these results: Hydrogen ions responsible for the Group I bands are associated with doubly charged oxygen interstitials, while hydrogen ions responsible for the Group II bands are associated with singly charged oxygen interstitials. Furthermore, the infrared bands observed in naturally derived olivines are present in spectra from our hydrothermally annealed crystals. Thus, the mechanisms of incorporation of hydrogen in olivine under geological conditions are the same as those operative under laboratory conditions. The maximum solubility reached in these experiments was ～ 360H/10⁶Si, which corresponds to ～ 0.002 wt% of H₂O. This value is a lower bound for the solubility of hydrogen in olivine under upper mantle conditions.     

The typing of Au and base-metal occurrences by plasma/mass spectrometry: initial results

This paper discusses the application of the newly developed ELAN 250 I.C.P./mass spectrometer to exploration geochemistry. This instrument combines an inductively coupled plasma with a quadrupole mass spectrometer. The combination of these two existing technologies makes it possible for the first time to perform stable-isotope and elemental analysis rapidly and concurrently.Particular attention is paid to the use of lead isotopes to type Au and base-metal occurrences. Data are presented on galena samples obtained from the Geological Survey of Canada and the Royal Ontario Museum. Consideration is also given to the potential usefulness of Pb isotopes and trace-element data to type mineral occurrences and to identify new ones.     

台湾费丛峡谷对强地面运动的影响研究──利用单台资料及2．5维SH混合方法

本文通过格林函数反褶积方法，由台湾峡谷附近的记录资料预测峡谷区的强地面运动的时程曲线．峡谷区的理论格林函数应用２．５维ＳＨ混合方法求解．通过格林函数反褶积方法得到的峡谷区费丛１及费丛２台的位移、速度、加速度和实际资料对比，取得了满意结果．计算结果表明，峡谷底部的峰值加速度相对峡谷边缘为最小；在靠近震中的一侧，峡谷的加速度的最大振幅相对比另一侧大．还给出了其余３个台的预测结果，研究了它们的加速度傅里叶谱和反应谱．     

位场小波分析的物理解释

采用二进小波变换,构造了位场基小波,通过简单模型,分析了位场信号小波分解与重构的物理实质,阐明了小波变换的频带分布与“归一化”位场空间分布的一致性,以及小波重构的规律,并叙述了小波重构与异常分解的关系.     

1904～1907年拉萨气候特征再分析

通过对以《有泰拉萨天气日志》为主的历史文献资料的深入挖掘 ,作者分析了 1 90 4年 2月 9日～ 1 90 7年 4月 1 7日拉萨的气候特征 :气候温暖 ,暖冬现象显著 ,而且 1 90 5年气温高于 1 90 4年 ;干旱气候占主导地位 ,间有多雨期 ;天气多变 ,多风 ,有雾 ;水灾、雪灾、干旱等自然灾害严重。拉萨与全球同时段的气候变化大体一致。     

广东山区大中型水库淤积与整治

广东是全国水资源较丰富的省区,但是由于环境污染,全省已普遍出现水质性缺水危机。目前除了东江、西江、北江和韩江等大江河外,沿海地区许多中、小河流和池塘等地表水水质已经恶化,不宜饮用,有的甚至不宜灌溉,有些地方连浅层地下水也不宜饮用。故此,山区水库已成为我省最后的水源"阵地",各地纷纷直接从水库引水饮用。然而,平原地区周围丘陵台地的库、塘水质也已严重恶化。目前全省321宗大、中型水库将成为本省水源的最后防线,而这些水库也存在不同程度泥沙淤积、水质污染和管理体制弊端等问题,必须采取有效措施进行整治和维护,并改革管理体制和加强管理,以保证其可持续利用和社会发展的水源需求。     

地下水超采对农业灌溉的影响及对策研究

在北方一些灌区,由于地下水的过量开采,出现了水位持续下降、地下水矿化度增加、土壤盐渍化等一系列环境问题.一些灌区对地下水的可采资源量估计过高,造成目前超采仍有进一步发展的趋势.因此必须采取有效措施控制地下水超采,实现灌区农业的可持续发展、保护环境.讨论灌区地下水超采的判别方法、超采对灌区的影响、以及应采取的对策.     

新疆阿尔泰山南缘产于麦兹泥盆纪火山-沉积盆地铅锌矿床稳定同位素特征

麦兹火山-沉积盆地内铅锌矿呈似层状、透镜状,矿石构造以条纹条带状、块状、斑杂状为主,矿物成分相对简单,矿体直接容矿围岩为火山-沉积岩.矿床δ34S值为-20.6‰～-10‰;矿床石英流体包裹体水的δD值为-89.1‰～-49.48‰,δ18OSMOW值为4.7‰～1.2‰.矿化层中方解石的δ13C值介于-6.7‰～-14.3‰之间,δ18O值在10.3‰～12.9‰之间.矿床属火山-沉积岩容矿的块状硫化物矿床,介于典型的火山岩容矿的块状硫化物型矿床(VHMS)和典型沉积岩容矿的硫化物矿床(SEDEX型)之间的过渡类型(一种新类型块状硫化物矿床).     

青藏高原雪盖异常对福建雨季旱涝影响的环流诊断

利用19555-1994年多种不同类型青藏高原积雪资料的综合再分析结果，通过分析青藏高原雪盖异常年冬季和初夏北半球大气环流特征，及北半球大气环流与福建雨季降水的遥相关，讨论高原雪盖异常反馈影响大气环流，进而导致福建雨季旱涝的可能途径，为在福建雨季旱涝预测中应用积雪因子提供一定的物理基础。     

利用GPS技术遥感大气对流层水汽含量的研究

讨论了利用 GPS系统探测大气对流层水汽含量的原理和数学模型 ,对利用 GPS遥感大气对流层水汽的加权平均温度、水汽含量随时间的变化等一些关键问题进行了探讨。通过对我国沿海地区大连、青岛、闸坡、坎门、厦门 5个测站的实验数据的解算 ,获得了较为满意的结果。