台山玉矿物学特征研究

广东江门五邑地区盛产的黄蜡石(简称台山玉),具有色彩绚丽、质地细腻温润、硬度高等特点,从外观看,台山玉与黄龙玉、石英质玉同属于二氧化硅质玉石,外观相似。从结构来说,它们的内部石英粒度是逐渐变化的,并没有一个截然的界限来划分种类,关于台山玉的定名,如何区别台山玉及黄龙玉成了普遍问题。此外,关于台山玉的地质产状、矿床学成因等方面研究较为薄弱。该文利用偏光显微镜、化学分析、红外光谱分析等方法,重点对台山玉的形成,宝石学矿物学性质进行研究与分析,力求给予五邑地区台山玉商业运作当中的理论层面上的支持。     

MCM-41/β介孔—微孔复合分子筛的合成、表征及催化性能

以β分子筛为前驱体,水玻璃和硫酸铝为外加硅铝源,采用二元混合表面活性剂为结构导向剂,水热晶化合成MCM-41/β介孔—微孔复合分子筛,并利用XRD、SEM、TEM、N2吸附—脱附和Py-IR等对复合分子筛进行表征,以十氢萘为模型化合物考察复合样品的催化裂解反应性能.结果表明:MCM-41/β介孔—微孔复合分子筛中存在MCM-41分子筛六方介孔结构和β分子筛微孔结构,对十氢萘具有较强的催化反应活性,催化裂解转化率为93.16%.     

A catastrophic natural disaster chain of typhoon–rainstorm–landslide–barrier lake–flooding in Zhejiang Province,China

On August 10, 2019, due to the effect of a rainstorm caused by Super Typhoon Lekima, a landslide occurred in Shanzao Village, China. It blocked the Shanzao stream, forming a barrier lake, and then the barrier lake burst. This is a rare natural disaster chain of typhoon–rainstorm–landslide–barrier lake–flooding. This study was built on field surveys, satellite image interpretation, the digital elevation model(DEM), engineering geological analysis and empirical regression. The purpose was to reveal the characteristics and causes of the landslide, the features and formation process of the barrier lake and the dam break flooding discharge. The results show that the volume of the landslide deposit is approximately 2.4 × 105 m3. The burst mode of the landslide dam is overtopping, which took only 22 minutes from the formation of the landslide dam to its overtopping. The dam-break peak flow was 1353 m3/s, and the average velocity was 2.8-3.0 m/s. This study shows that the strongly weathered rock and soil slope has low strength and high permeability under the condition of heavy rainfall, which reminds us the high risk of landslides and the importance of accurate early warning of landslides under heavy rainfalls in densely populated areas of Southeast China, as well as the severity of the disaster chain of typhoon–rainstorm–landslide–barrier lake–flooding.     

光及补料条件对室内管道光反应器中三角褐指藻生长和岩藻黄素积累的影响

【目的】制备富含岩藻黄素的三角褐指藻(Phaeodactylum tricornutum)生物质。【方法】采用470 L室内管道光生物反应器系统,研究自养培养下光源、调光策略、补料培养操作条件对于细胞生长、生物量浓度和岩藻黄素积累的影响。【结果】在采用LED灯、梯度提升照度及重复补料半连续培养模式下,三角褐指藻细胞密度、生物量和岩藻黄素产率最高分别可达3.16×10⁷mL^-1、1.64 g/L和1.90 mg/(L·d),分别是日光灯为光源条件下的2.77倍、3.09倍和2.38倍(P<0.01)。【结论】在管道光生物反应器中获得的自养培养条件,可强化三角褐指藻生物量和岩藻黄素积累,为三角褐指藻积累岩藻黄素的室内可控规模化技术开发提供指导。     

近20年东莞市城市扩张的时空特征分析

深入分析建设用地演变过程,掌握城市扩张不同阶段的时空特征,对科学推进国土空间规划编制实施具有重要意义.基于多时相卫星遥感影像来解译东莞市建设用地,使用重心空间轨迹模型及空间扩张象限分析法,实现对东莞市近20年来城市扩张的时空特征分析.结果表明:2000—2020年,东莞市建设用地面积增加显著,城市扩张明显,部分区域的建...     

禁食暂养对卵形鲳鲹有水保活生理响应的影响

【目的】探究禁食暂养对卵形鲳鲹有水保活生理响应的影响,为卵形鲳鲹的保活运输奠定基础。【方法】通过测定暂养过程中水体的总氨氮和pH值、卵形鲳鲹血液生理生化指标、肌肉氧化应激指标等的变化,分析确定卵形鲳鲹有水保活的禁食暂养条件。【结果与结论】禁食暂养过程中,随着暂养时间的延长,水体总氨氮含量与pH值显著上升,但在禁食暂养时间为6 h时,其总氨氮质量浓度为3.22 mg/L和pH值为7.80;禁食暂养6 h可以降低或减少卵形鲳鲹的应激,使血液中乳酸脱氢酶(LDH)和谷草转氨酶(AST)活性以及皮质醇(Cortisol)、血糖(GLU)、尿素氮(BUN)和总胆固醇(T-CHO)含量处于较低水平,分别为2785.53 U/L、19.04 U/L、158.72 ng/mL、2.98 mmol/L、4.35 mmol/L和4.96 mmol/L;同时减轻了应激带来的肌肉组织氧化损失,使过氧化氢酶(CAT)活性和丙二醛(MDA)含量维持在较低水平,分别为6.34 U/L和5.86 mmol/L;卵形鲳鲹适宜的暂养条件为在鱼水比m鱼∶m水=1∶20和(25±1)℃的洁净海水中暂养6 h。     

扁舵鲣抗氧化肽分离纯化及结构鉴定

【目的】从扁舵鲣(Auxis thazard)的木瓜蛋白酶酶解产物中分离鉴定具有较高1,1-二苯基-2-三硝基苯肼(DPPH)自由基清除率的抗氧化肽。【方法】用木瓜蛋白酶水解扁舵鲣,以DPPH自由基清除能力为检测指标,通过超滤、凝胶过滤层析和反向高效液相色谱分离抗氧化肽,再经过超高效液相/三重四级杆飞行时间质谱(UPLC/Xevo G2-XS QTOF)进行结构鉴定。【结果】从酶解产物中获得3种抗氧化肽,其氨基酸序列分别为β-丙氨酸-1-甲基-L-组氨酸(241 u)、Gly-Ala-Gly-Gly-Pro(357 u)和Val-Glu(246 u)。【结论】扁舵鲣的木瓜蛋白酶酶解产物含有抗氧化活性的肽类,可为其抗氧化肽的开发提供理论依据。     

Effect of Penetration Rates on the Piezocone Penetration Test in the Yellow River Delta Silt

Partial drainage often occurs during piezocone penetration testing on Yellow River Delta silt because of its intermediate physical and mechanical properties between those of sand and clay.Yet,there is no accurate understanding for the range of penetra-tion rates to trigger the partial drainage of silt soils.In order to fully investigate cone penetration rate effects under partial drainage condi-tions,indoor 1 g penetration model tests and numerical simulations of cavity expansion at variable penetration rates were carried out on the Yellow River Delta silt.The boundary effect of the model tests and the variation of key parameters at the different cavity ex-pansion rates were analyzed.The 1 g penetration model test results and numerical simulations results consistently indicated that the penetration rate to trigger the partially drainage of typical silt varied at least three orders of magnitude.The numerical simulations also provide the reference values for the penetration resistance corresponding to zero dilation and zero viscosity at any given normalized penetration rate for silt in Yellow River Delta.These geotechnical properties can be used for the design of offshore platforms in Yel-low River Delta,and the understanding of cone penetration rate effects under the partially drained conditions would provide some technical support for geohazard evaluation of offshore platforms.     

中国东南沿海地区PWV直接转换模型研究

针对东南沿海地区GNSS大气可降水量(PWV)计算过程参数多、数据量大、效率不高且易产生累积误差等问题,本文基于中国东南沿海地区2017~2018年18个CORS站的GNSS数据,分析GNSS-PWV与对流层延迟(ZTD)、地面气温(T_s)和地面大气压(P_s)之间的线性关系,并利用多元线性拟合方法建立多因子GNSS-PWV直接转换模型,为研究区提供简捷高效的PWV计算方法。结果表明,GNSS-PWV与ZTD、P_s和T_s之间具有良好的相关性,相关系数分别为0.98、－0.65和0.78;基于ZTD、P_s和T_s的多因子PWV模型RMS为0.33 mm,精度最高,明显优于基于ZTD的单因子PWV模型（4.66 mm）,而基于ZTD和P_s的双因子PWV模型RMS为0.50 mm。     

延安新区地表垂直形变时空演化的经验正交函数分析

采用SBAS-InSAR技术对43景Sentinel-1A影像进行处理,获取延安新区（北区）地表形变信息,并运用经验正交函数对结果进行分解,得到研究区域的时间系数和空间分布。结果表明,延安新区（北区）的最大沉降速率为-56 mm/a,最大抬升速率为32 mm/a。从第1模态可以看出,挖方、填方是造成地表抬升和沉降的主要原因;第2模态则反映了工程建设不同时期对应的不同地表形变状态,即加速、减缓、平稳3个阶段。