Use of oxygen isotope ratios in correlation of tuffs,East Rudolf Basin,northern Kenya

Oxygen isotope determinations were made using CoF₃ to extract oxygen from 27 volcanic glass samples from the East Rudolf Basin, northern Kenya. Results show that the older tuffs are progressively enriched in¹⁸O and that this index can be used in the correlation of volcanic ash units. This method could not distinguish individual samples from the youngest units studied because their ranges of δ¹⁸O overlap. The δ¹⁸O values for the shards in the Tulu Bor Tuff, the KBS Tuff, the Koobi Fora Tuff and the Chari Tuff range from 14.5 to 16.4, from 8.9 to 9.5, from 6.6 to 7.0 and from 7.0 to 7.2, respectively, in decreasing age. Determinations from pumice cobbles are consistently higher than the above values.     

Pollen and fragments of plant tissue in core samples from the Greenland Ice Cap

Investigation of two Late-Wisconsin and two sub-recent core samples from the Greenland Ice Cap has shown the presence ol determinable pollen, wood fragments and other plant remains in the ice.     

Migration of a pattern of plate motion

A pattern of plate motion is documented to have migrated from the South Pacific into the Indian Ocean during the Cretaceous and Early Tertiary, and then across the Indian Ocean during the Tertiary. The opening of the Gulf of Aden may be a more recent extension of this migration. The migration takes place by the episodic formation of new segments of sea-floor spreading having the new direction of plate motion; or by development of the new direction of motion in segments where sea-floor spreading had previously been active. In this manner plate motions can extend beyond their previously limiting plate boundaries.     

Scale dependence of mineral dissolution rates within single pores and fractures

The possibility that gradients in concentration may develop within single pores and fractures, potentially giving rise to scale-dependent mineral dissolution rates, was investigated with experimentally validated reactive transport modeling. Three important subsurface mineral phases that dissolve at widely different rates, calcite, plagioclase, and iron hydroxide, were considered. Two models for analyzing mineral dissolution kinetics within a single pore were developed: (1) a Poiseuille Flow model that applies laboratory-measured dissolution kinetics at the pore or fracture wall and couples this to a rigorous treatment of both advective and diffusive transport within the pore, and (2) a Well-Mixed Reactor model that assumes complete mixing within the pore, while maintaining the same reactive surface area, average flow rate, geometry, and multicomponent chemistry as the Poiseuille Flow model. For the case of a single fracture, a 1D Plug Flow Reactor model was also considered to quantify the effects of longitudinal versus transverse mixing. Excellent agreement was obtained between results from the Poiseuille Flow model and microfluidic laboratory experiments in which pH 4 and 5 solutions were flowed through a single 500 μm diameter by 4000 μm long cylindrical pore in calcite. The numerical modeling and time scale analysis indicated that rate discrepancies arise primarily where concentration gradients develop under two necessary conditions: (1) comparable rates of reaction and advective transport, and (2) incomplete mixing via molecular diffusion. For plagioclase and iron hydroxide, the scaling effects are negligible at the single pore and fracture scale because of their slow rates. In the case of calcite, where dissolution rates are rapid, scaling effects can develop at high flow rates from 0.1 to 1000 cm/s and for fracture lengths less than 1 cm. Under more normal flow conditions where flow is usually slower than 0.001 cm/s, however, mixing via molecular diffusion is effective in homogenizing the concentration field, thus eliminating any discrepancies between the Poiseuille Flow and the Well-Mixed Reactor model. The analysis suggests that concentration gradients are unlikely to develop within single pores and fractures under typical geological/hydrologic conditions, implying that the discrepancy between laboratory and field rates must be attributed to other factors.     

Metamorphic history and geodynamic significance of high-grade metabasites from the ophiolitic mélange beneath the Yarlung Zangbo ophiolites, Xigaze area, Tibet

Blocks of highly foliated amphibolite are locally embedded within a serpentinite mélange underlying the Yarlung Zangbo ophiolites in the Xigaze area of southern Tibet. The ophiolites are remnants of an Early Cretaceous back-arc basin within the Permo-Cretaceous Tethys Ocean, which are exposed along in the Yarlung Zangbo Suture Zone (YZSZ). These amphibolites are interpreted as fragments of a dismembered dynamothermal sole. Three types of amphibolite are present: (1) common amphibolite with assemblages of Hbl + Pl ± Ep ± Ap ± Ttn, (2) clinopyroxene-bearing amphibolite with Hbl ± Pl ± Cpx ± Ep ± Ttn ± Qtz ± Ap and (3) garnet–clinopyroxene-bearing amphibolite characterized by the assemblages Hbl + Cpx + Grt + Pl ± Rt and Grt + Hbl + Pl (corona assemblage). In all three types, plagioclase is pseudomorphed by late albite–prehnite. Retrograde cataclastic veins containing assemblages of Prh + Ab + Ep ± Chl are also present. P–T estimates indicate that the amphibolites reached peak metamorphic conditions of 13–15 kbar and 750–875 °C. Partial replacement of pyrope-rich (up to 35 mole%) garnet by Al-tschermakite (Al₂O₃ up to 21 wt%) reflects a high pressure (≈18 kbar, 600 °C) metamorphic event followed by rapid exhumation. Soon after exhumation, the amphibolites were intruded by very fine-grained diabase dykes that were then hydrothermally altered. The field relationships and metamorphic history of the amphibolites indicate formation during inception of subduction within a back-arc basin prior to obduction of the ophiolites onto the Indian passive margin.     

Characterization of the 1.2 μm M1 pyroxene band: Extracting cooling history from near‐IR spectra of pyroxenes and pyroxene‐dominated rocks

Abstract— The 1.2 μm band in near‐infrared spectra of pyroxenes results from Fe²⁺in the M1 crystallographic site. The distribution of Fe and Mg between the M1 and M2 sites is in part a function of the cooling rate and thermal history of a pyroxene. Combining near‐infrared and Mössbauer spectra for a series of compositionally controlled synthetic Mg, Fe, Ca pyroxenes, we quantify the strength of the 1.2 μm band as a function of Fe²⁺in the M1 site. Near‐infrared spectra are deconvolved into component absorptions that can be assigned to the M1 and M2 sites using the modified Gaussian model. The relative strength of the 1.2 μm band is shown to be directly related to the amount of Fe²⁺in the M1 site measured by Mössbauer spectroscopy. The strength of the 1.2 μm band relative to the combined strengths of the 1.2 and 2 μm bands, or the M1 intensity ratio, is calculated for 51 howardite, eucrite, and diogenite (HED) meteorites. Diogenites and cumulate eucrites exhibit the lowest M1 intensity ratios, consistent with their formation as slowly cooled cumulates. Basaltic eucrites exhibit a large range of M1 intensity ratios, all of which are consistently higher than the diogenites and cumulate eucrites. This example illustrates how the M1 intensity ratio can be a used as a tool for characterizing the cooling history of remotely detected pyroxene‐dominated rocks.     

A survey of small fast rotating asteroids among the near-Earth asteroid population

A survey of 62 small near-Earth asteroids was conducted to determine the rotation state of these objects and to search for rapid rotation. Since results for 9 of the asteroids were previously published (Pravec, P., Hergenrother, C.W., Whiteley, R.J., Šarounová, L., Kušnirák, P., Wolf, M. [2000]. Icarus 147, 477-486; Pravec, P. et al. [2005] Icarus 173, 108-131; Whiteley, R.J., Tholen, D.J., Hergenrother, C.W. [2002a]. Icarus 157, 139-154; Hergenrother, C.W., Whiteley, R.J., Christensen, E.J. [2009]. Minor Planet Bull. 36, 16-18.), this paper will present results for the remaining 53 objects. Rotation periods significantly less than 2 h are indicative of intrinsic strength in the asteroids, while periods longer than 2 h are typically associated with gravitationally bound aggregates. Asteroids with absolute magnitude (H) values ranging from 20.4 to 27.4 were characterized. The slowest rotator with a definite period is 2004 BW₁₈ with a period of 8.3 h, while 2000 DO₈ and 2000 WH₁₀ are the fastest with periods of 1.3 min. A minimum of two-thirds of asteroids with H > 20 are fast rotating and have periods significantly faster than 2.0 h. The percentage of rapid rotators increases with decreasing size and a minimum of 79% of H ? 24 objects are rapid rotators. Slowly-rotating objects, some with periods as long as 10-20 h, make up a small though significant fraction of the small asteroid population. There are three fast rotators with relatively large possible diameters (D): 2001 OE₈₄ with 470 ? D ? 820 m (Pravec, P., Kušnirák, P., Šarounová, L., Harris, A.W., Binzel, R.P., Rivkin, A.S. [2002b]. Large coherent Asteroid 2001 OE84. In: Warmbein, B. (Eds.), Proceedings of Asteroids, Comets, Meteors - ACM 2002. Springer, Berlin, pp. 743-745), 2001 FE₉₀ with 265 ? D ? 594 m (Hicks, M., Lawrence, K., Rhoades, H., Somers, J., McAuley, A., Barajas, T. [2009]. The Astronomer’s Telegrams, # 2116), and 2001 VF₂ with a possible D of 145 ? D ? 665 m. Using the diameters derived from nominal absolute magnitudes and albedos, the remainder of the fast rotating population is completely consistent with D ? 200 m. Even when taking into account the largest possible uncertainties in the determination of diameters, the remainder must all have D ? 400 m. With the exceptions of 2001 OE₈₄, this result agrees with previous upper diameter limits for fast rotators in Pravec and Harris (Pravec, P., Harris, A.W. [2000]. Icarus 148, 589-593) and Whiteley et al. (Whiteley, R.J, Tholen, D.J., Hergenrother, C.W. [2002a]. Icarus 157, 139-154.