Seasonal Study of Methane and Nitrous Oxide in the Coastal Waters of the Southern Baltic Sea

Atmospheric and dissolved methane (CH₄) and nitrous oxide (N₂O) were measured in the unique coastal ecosystem of theBoddenwaters, including the western Oder estuary, (southern Baltic Sea) during five campaigns between 1994 and 1997. The CH₄saturations, ranging from 105–15 500%, showed great spatial and temporal variability with maximum values in September and minimum values in December. The N₂O saturations were in the range of 91–312% with a maximum in March. Enhanced concentrations of both gases were observed only in the western Oder estuary near the mouth of the Peene River. Thus, we conclude that the distributions of CH₄and N₂O in the investigatedBoddenwaters are, directly or indirectly, linked to the Peene River runoff and not to the Oder River. Our estimate of the annual CH₄emissions from theBoddenwaters to the atmosphere indicates a significant contribution (c. 17%) to the overall CH₄emissions from the Baltic Sea. In contrast, theBoddenwaters represent only a small source for atmospheric N₂O.CH₄production rates estimated from sediment slurry experiments revealed a significant spatial variability and indicated that methanogenic activity was related to acetate consumption in the surface sediment layer. Sedimentary CH₄production might depend on different amounts of accumulation of organic material.     

Uptake of fluoride by aragonite

The uptake of F by aragonite is attributed to the ion-exchange process, in which one CO₃^2? ion in the structure is replaced by two F^? ions. Under the equilibrium condition at 15° C and 1 atm., the partition of F between aragonite and aqueous solution is described by:

$\text{log}\text{(}\text{[}\text{F}\text{]}\text{a}{}_{\mathrm{<mtext>F</mtext>}}\text{)=1.95 + 0.54}\text{log}\text{a}{}_{\mathrm{<mtext>Ca</mtext>}}$

were [F] denotes the F content of aragonite in mol/g, and a_F and a_Ca are the aqueous activities of F^? and Ca²⁺, respectively. The equation was successfully applied to estimating the F content of marine aragonite.     

Simulation of seasonal anomalies of atmospheric circulation using coupled atmosphere-ocean model

A coupled atmosphere-ocean model intended for the simulation of coupled circulation at time scales up to a season is developed. The semi-Lagrangian atmospheric general circulation model of the Hydrometeorological Centre of Russia, SLAV, is coupled with the sigma model of ocean general circulation developed at the Institute of Numerical Mathematics, Russian Academy of Sciences (INM RAS), INMOM. Using this coupled model, numerical experiments on ensemble modeling of the atmosphere and ocean circulation for up to 4 months are carried out using real initial data for all seasons of an annual cycle in 1989–2010. Results of these experiments are compared to the results of the SLAV model with the simple evolution of the sea surface temperature. A comparative analysis of seasonally averaged anomalies of atmospheric circulation shows prospects in applying the coupled model for forecasts. It is shown with the example of the El Niño phenomenon of 1997–1998 that the coupled model forecasts the seasonally averaged anomalies for the period of the nonstationary El Niño phase significantly better.     

Late Quaternary history of contourite drifts and variations in Labrador Current flow,Flemish Pass,offshore eastern Canada

Contourite drifts of alternating sand and mud, shaped by the Labrador Current, formed during the late Quaternary in Flemish Pass seaward of the Grand Banks of Newfoundland, Canada. The drifts preserve a record of Labrador Current flow variations through the last glacial maximum. A high-resolution seismic profile and a transect of four cores were collected across Beothuk drift on the southeast side of Flemish Pass. Downcore and lateral trends in grain size and sedimentation rate provide evidence that, between 16 and 13 ka, sediment was partitioned across Beothuk drift and the adjacent Flemish Pass floor by a strong current flow but, from 29 to 16 ka, sedimentation was more of a blanketing style, represented by draped reflections interpreted as being due to a weaker current. The data poorly resolve the low sedimentation rates since 13 ka, but the modern Labrador Current in Flemish Pass is the strongest it has been in at least the past 29 ka. Pre-29 ka current flow is interpreted based on reflection architecture in seismic profiles. A prominent drift on the southwestern side of Flemish Pass formed above a mid-Miocene erosion surface, but was buried by a mass-transport deposit after the penultimate glacial maximum and after drift deposition switched to eastern Flemish Pass. These findings illustrate the temporal complexity of drift sedimentation and provide the first detailed proxy for Labrador Current flow since the last glacial maximum.     

Residual hydrodynamic fields after tsunami generation by an earthquake

The linear theory of long waves was applied to study horizontal motions of the water layer in a rotating ocean which appear after tsunami generation by an earthquake. The structures of residual potential and eddy fields are analyzed on the basis of the analytical solution of a model axisymmetric problem for an ocean of constant depth. The estimates of the horizontal displacements of water particles, velocity of the eddy current, and energy of the geostrophic eddy are calculated for typical conditions of the tsunami source. Particular features of the residual fields related to the existence of stable stratification are considered. Static and dynamic numerical models are described that allow us to calculate the residual potential field and its evolution related to the realistic events. The field of residual horizontal displacements of water particles for the catastrophic earthquake near the coasts of Japan on March 11, 2011, is calculated and analyzed.     

Diets of eight fish species from the upper slope off the Wairarapa coast,North Island,New Zealand,with notes on the diets of others

The diets of eight demersal fish species from the upper continental slope (c. 24CM‐50 m) were determined from samples taken during late January and early February 2004, off the Wairarapa coast, North Island, New Zealand. Diets were from a combination of benthopelagic and benthic sources, with most species exhibiting ontogenetic shifts in diet, in that larger‐bodied food (fish and/or natant decapod prawns) was more important in the diets of larger fish. Javelinfish (Lepidorhynchus denticulatus), silver roughy (Hoplostethus mediterraneus), and capro dory (Capromimus abbreviatus) had predominantly benthopelagic diets, whereas the diets of sea perch (Helicolenus percoides), Bollons’ rattail (Caelorinchus bollonsi), two‐banded rattail (C. biclinozonalis), and silverside (Argentina elongata) were predominantly benthic, with the crab Carcinoplax victoriensis an important food item. The diet of Oliver's rattail (C. oliverianus) was a mix of benthopelagic and benthic organisms. Generally, levels of dietary overlap between the eight species were low. Overall, the diets of these fish probably reflect regional and seasonal levels of food availability. Notes on food observed in the stomachs of a further 18 species, for which there were fewer than 10 stomach samples per species are also provided.     

Risks of shifting baselines highlighted by anecdotal accounts of New Zealand's snapper (Pagrus auratus) fishery

Anecdotal data sources may constitute an important component of the information available about an exploited species, as record keeping may not have occurred until after exploitation began. Here, we aimed to fill any gaps in the exploitative history of the sparid snapper (Pagrus auratus), using social and historical research methods. Social research consisted of interviews with recreational fishers, focusing on the most and largest snapper they had caught. In addition, the diary‐logs of two recreational fishers were analysed. Historical research consisted of investigation of old books, photos, archives and unpublished sources unconventional to fishery science. Interviews with fishers demonstrated no or weak trends in snapper abundance or size, and were likely impeded by a lack of ability to detect change in a fish stock that may still be considered abundant. The fishers’ perception of change, however, largely reflected recent experiences (last c. 10 years), when biomass is understood to have increased, and mostly did not consider experiences before the 1980s. Alternatively, diary‐logs of fisher catch rates produced a pattern that matched formal stock assessments of snapper biomass, suggesting declines in abundance up until the 1990s and an increase in biomass after that time. Historical research, although more qualitative, had the ability to investigate periods where formal records were not kept and described a fishery vastly different from the current one. Snapper were easily caught, in great abundance and in unusual locations. Localised depletion of snapper was first noticed in the early 20th century, despite spectacular catches of snapper occurring after that time. Snapper behaviour was also likely different, with visual sightings of snapper by onlookers a common occurrence. Although predictions from stock assessment models are consistent with that of the anecdotes listed here (i.e., high biomass in the past), these anecdotes are valuable as they explain lost biomass in a perspective meaningful to all. This perspective may be valuable for managers trying to consider the non‐financial value of a shared fishery but, if unrecognised, represents a shifting baseline.     

Nitrogen and phosphorus in New Zealand streams and rivers: Control and impact of eutrophication and the influence of land management

Abstract

Given sufficient light and heat, the growth of aquatic macrophytes and algae associated with eutrophication is generally controlled by the concentration, form and ratio between nitrogen (N) and phosphorus (P). Data from 1100 freshwater sites monitored for the last 10 years by New Zealand's regional councils and unitary authorities were assessed for streams and rivers with mean nitrate/ nitrite‐N (NNN), dissolved reactive P (DRP), total N (TN) and total P (TP) concentrations in excess of New Zealand guidelines, and to generate a data set of N:P ratios to predict potential periphyton response according to the concentration of the limiting nutrient. The frequency of sites exceeding the guidelines varied from 0 to 100% depending on the parameter and region, but South Island regions were generally more compliant. The dissolved inorganic N (DIN) to dissolved reactive P (DRP) ratio was used to group data into three nutrient limitation classes: <7:1 (N‐limited), between 7:1 and 15:1 (co‐limited), and>15:l (P‐limited), by mass. P‐limitation was the most frequent scenario in New Zealand streams (overall, 76% of sites were P‐limited, 12% N‐limited, and 12% co‐limited). The mean concentration of the limiting nutrient for each site was combined with empirical relationships to predict periphyton densities (the average of N‐and P‐limited growth was used for sites with co‐limitation). This assessment predicted that 22 sites were likely to exceed the periphyton guideline for protecting benthic biodiversity (50 mg chlorophyll a m^?2), but this assessment is likely to be highly changeable in response to climatic conditions and present and future land use. As an example, we modelled N and P losses from an average sheep and a dairy farm in Southland (South Island, New Zealand) in 1958, 1988, 2008 and 2028. We predicted that with time, as farm systems have and continue to intensify, N losses increase at a greater rate than P losses. Since the pathway for N to reach fresh waters may be more tortuous and take longer than P to reach a stream or river, focusing mitigation on P losses may have a quicker effect on potential algal growth. In addition, with time, it is expected that P‐limitation in New Zealand's rivers and streams will be more widespread as N‐losses are unabated. Hence, although strategies to decrease N losses should be practised, mitigating P losses is also central to preventing eutrophication.     

Ibiza Absolute Calibration Experiment: Survey and Preliminary Results

Within the framework of a project comprising part of the Spanish Space Program related to the JASON-1 CNES (Centre National d'Etudes Spatiales)/NASA (National Aeronautics and Space Administration) mission, a campaign was conducted from June 9–17, 2003, on the Absolute Calibration Site of the island of Ibiza. The objective was to determine the local marine geoid slope under the ascending (187) and descending (248) Jason-1 ground tracks, in order to allow a better extrapolation of the open-ocean altimetric data with on-shore tide gauge locations, and thereby improve the overall precision of the calibration process. For this we have used a catamaran with two GPS antennas onboard, following the Corsica/Senetosa design (Bonnefond et al. 2003a Bonnefond, P., Exertier, P., Laurain, O., Menard, Y., Orsoni, A., Jeansou, E., Haines, B., Kubitschek, D. and Born, G. 2003a. Leveling Sea Surface using a GPS catamaran. Marine Geodesy, 26(3–4): 319–334. [Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]). Five GPS reference stations were deployed in order to reduce the distance between the areas covered by the catamaran and the fixed GPS receiver used in the kinematic process. The geodetic activities (e.g., GPS, leveling) have enabled the building of a very accurate (few mm) network in a reference frame compatible with the satellite altimetry missions (ITRF 2000). The GPS kinematic data were processed using two different software programmes, allowing checking of the consistency of the solutions. If the standard deviation of the differences (3.3 cm) is close to the kinematic process precision, they exhibit some large values (up to 14 cm). These large discrepancies have been reduced using a weighting based on the crossover differences. Inasmuch as the distances between the tide gauges and the areas covered by the GPS catamaran were becoming large, we have used the MOG2D ocean model (Carrère and Lyard 2003 Carrère, L. and Lyard, F. 2003. Modelling the barotropic response of the global ocean to atmospheric wind and pressure forcing—comparisons with observations. Geophys. Res. Letters, 30(6) [Google Scholar]) to correct the sea surface from tides. In the farthest areas, the crossover differences show an improvement by a factor of two. Finally, we also present preliminary results on Jason-1 altimeter calibration using the derived marine geoid. From this analysis, the altimeter bias is estimated to be 120 ± 5 mm. The quality of this first result validates the whole GPS-based marine geoid processing, for which the accuracy is estimated to be better than 3 cm rms at crossovers.     

Pacific decadal oscillation and European climatic anomalies

By using the NCEP/NCAR reanalysis data sets for 1951–2001, we study the characteristics of Pacific cyclones. It is shown that the northeast-southwest direction is predominant in the displacements of cyclones in the North Pacific. We study the variability of the field of surface atmospheric pressure in different phases of the Pacific decadal oscillation characterizing the temperature anomalies on the surface of the ocean in the region bounded by 20 and 60°N. It is shown that the decadal variations of the North Atlantic Oscillation supported by the large-scale anomalies of the Pacific decadal oscillation is the most important cause of natural decadal oscillations in the European region. We study and evaluate the regional response to the Pacific decadal oscillation by using, as an example, the analysis of variations of the discharge of European rivers. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 13–23, July–August, 2007.