Discharge and transport processes along the German Baltic Sea Coast

The western Baltic Sea infront of the German coast is a highly variable dynamical system, dominated by a complex and small-scale morphometry, the water exchange between the Baltic and North Seas, and driven by local wind. Neither data collection, nor satellite images or model simulations alone were able to explain the observed spatial patterns and transport processes. Therefore, all these methods were combined to explain the dynamical features and to systematise them according to the typical local wind pattern and time series. The aim was to develop an instrument for regional authorities which supports the interpretation of coastal water monitoring data and forms a basis for an improved monitoring strategy. Satellite data of sea surface temperature and ocean colour from the sensors NOAA-AVHRR and SeaWiFS were applied for synoptic investigations in the entire region and Landsat-7-ETM+ for regional studies. Model simulations were performed for the western Baltic using a 3D model MOM-3 and for the Szczecin Lagoon using 2D model FEMFLOW. For the first time, regional particularities in the coastal dynamical features and processes are derived for the main wind directions and for transitions between dominant wind situations west and east as derived from wind statistics. The simulated transport of particles released from different coastal and open sea sources indicate the affected areas during changing forcing conditions. The results support the interpretation of acquired coastal monitoring data as well as the assessment and optimisation of the monitoring programme.     

Studying the City Plume of Berlin on 20 July 1998 with Three Different Modelling Approaches

In this paper we try to identify and describe the specifics of the Berlin city plume characterised by a zone of enhanced photochemical activity downwind of the urban area, where the major emissions of ozone precursors (NO_x and VOC) take place. Two Eulerian CTM systems (EURAD and REM3/CALGRID) and one Euler–Lagrangian model (LaMM5) are applied to thearea of Berlin/Brandenburg to investigate the processes involved in the evolution of the Berlin plume inherent to the models. The study focuses on 20 July 1998,the first special observation period (SOP) during BERLIOZ. The examination includes (1) the role of turbulence and transport and the role of mass flux to the surface during the evolution of the plume, (2) the import situation of the ground based measurement sites, (3)the terms of the ozone budget equation and their contribution to precursor distribution and ozone formation, (4) the substructures of the plume defined by its chemical regimes. Main results show that the complex meteorological conditions during this SOP with considerable turbulent transports demand an Euler–Lagrangian approach to determine the source receptor relationshipsfor the ground based measurement sites. These relations reveal that only a minor part (5%) of the air approaching Pabstthum and the more downwind (north-western) stations origins from Berlin and that the mutual transport between all sites was limited. The latter result afflicts the joint interpretation of data from different stations because the presumption to measure the same air mass is violated in many cases for this SOP. The CTM results reveal that the local net production of ozone within the plume was controlled by transport ad chemical processes both owning the same importance but tending to counteract each other. At this SOP far distance sources of ozone precursors originating from the Bohemian basin did not interfere the Berlin city plume although they generally have the potential to do so.     

Extracting central places from the link structure in Wikipedia

Explicit information about places is captured in an increasing number of geospatial datasets. This article presents evidence that relationships between places can also be captured implicitly. It demonstrates that the hierarchy of central places in Germany is reflected in the link structure of the German language edition of Wikipedia. The official upper and middle centers declared, based on German spatial laws, are used as a reference dataset. The characteristics of the link structure around their Wikipedia pages, which link to each other or mention each other, and how often, are used to develop a bottom‐up method for extracting central places from Wikipedia. The method relies solely on the structure and number of links and mentions between the corresponding Wikipedia pages; no spatial information is used in the extraction process. The output of this method shows significant overlap with the official central place structure, especially for the upper centers. The results indicate that real‐world relationships are in fact reflected in the link structure on the web in the case of Wikipedia.     

Highly Time Resolved Measurements of OH during POPCORN Using Laser-Induced Fluorescence Spectroscopy

Tropospheric hydroxyl radical (OH) concentrations were measured by laser-induced fluorescence (LIF) during the POPCORN field campaign in August 1994 at a rural site in the North East of Germany. Ambient air spectra were recorded by tuning the laser wavelength over a spectral region covering the Q11(3), Q21(3), and P11(1) rotational transitions of the (0-0) band in the A-X system of OH around 308 nm. The observed spectra clearly identify the OH radical in the atmosphere. Besides the OH absorption lines there was no sign of any other narrow-band spectral structure nearby demonstrating the high specificity of the method. For OH measurements with a typical time resolution of 60–100 seconds per data point the laser wavelength was tuned repetitively over small spectral intervals covering the peak position of the P11(1) OH-line and background positions. A total of 2300 measurements were recorded including diurnal cycles of OH with more than 300 data points. The OH as well as the LIF background signal data will be presented. In a first analysis the background signal will be characterized and the correlation between OH and the ozone photolysis frequency will be derived.     

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Recovery of Zn from wastewater of zinc plating industry by precipitation of doped ZnO nanoparticles

In this study, a facile precipitation process to treat wastewater from zinc plating industry is presented. Water purification rates of Zn range between 96.40 % and 99.99 % depending on the reaction conditions. Optimal results are gained at a low pH value of 9, low temperature of 40 °C and a fast alkalization using NaOH solution containing 16 % pure NaOH. Traces of Ni, Fe, Zn, Cu and Cr present in the wastewater were almost completely removed. The precipitates were analysed by X-ray diffraction, infrared and Raman spectroscopy, electron microscopy and magnetic measurements. They consist of doped ZnO as a main phase. Although ZnO exclusively crystallizes in nanoparticle size, the morphology is directly influenced by the experimental parameters. Additionally, very small amounts of ZnCO₃ and Zn(OH)₂ were detected. Magnetic investigations indicate the incorporation of Ni and Fe into the ZnO lattice. The measured saturation magnetization is ~0.01 emu/g and the Curie temperature is ~75 °C.     

Biologische Gedanken in der Meteorologie

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