The fate of nitrogen and sulfur in hard-rock aquifers as shown by sulfate-isotope tracing

Stable SO₄ isotopes (δ³⁴S_-SO4 and δ¹⁸O_-SO4), and more occasionally δ¹⁵N_-NO3 were studied in groundwater from seven hard-rock aquifer catchments. The sites are located in Brittany (France) and all are characterized by intensive agricultural activity. The purpose of the study was to investigate the potential use of these isotopes for highlighting the fate of both SO₄ and NO₃ in the different aquifer compartments. Nitrate-contaminated groundwater occurs in the regolith; δ³⁴S fingerprints the origin of SO₄, such as atmospheric deposition and fertilizers, and δ¹⁸O_-SO4 provides evidence of the cycling of S within soil. The correlation between the δ¹⁸O_-SO4 of sulfates and the δ¹⁵N_-NO3 of nitrates suggests that S and N were both cycled in soil before being leached to groundwater. Autotrophic and heterotrophic denitrification was noted in fissured aquifers and in wetlands, respectively, the two processes being distinguished on the basis of stable SO₄ isotopes. During autotrophic denitrification, both δ³⁴S_-SO4 and δ¹⁸O_-SO4 decrease due to the oxidation of pyrite and the incorporation of O from the NO₃ molecule in the newly formed SO₄. Within wetlands, fractionation occurs of O isotopes on SO₄ in favour of lighter isotopes, probably through reductive assimilation processes. Fractionation of S isotopes is negligible as the redox conditions are not sufficiently reductive for dissimilatory reduction. δ³⁴S_-SO4 and δ¹⁸O_-SO4 data fingerprint the presence of a NO₃-free brackish groundwater in the deepest parts of the aquifer. Through mixing with present-day denitrified groundwater, this brackish groundwater can contribute to significantly increase the salinity of pumped water from the fissured aquifer.     

Impact of the LMDZ atmospheric grid configuration on the climate and sensitivity of the IPSL-CM5A coupled model

The IPSL-CM5A climate model was used to perform a large number of control, historical and climate change simulations in the frame of CMIP5. The refined horizontal and vertical grid of the atmospheric component, LMDZ, constitutes a major difference compared to the previous IPSL-CM4 version used for CMIP3. From imposed-SST (Sea Surface Temperature) and coupled numerical experiments, we systematically analyze the impact of the horizontal and vertical grid resolution on the simulated climate. The refinement of the horizontal grid results in a systematic reduction of major biases in the mean tropospheric structures and SST. The mid-latitude jets, located too close to the equator with the coarsest grids, move poleward. This robust feature, is accompanied by a drying at mid-latitudes and a reduction of cold biases in mid-latitudes relative to the equator. The model was also extended to the stratosphere by increasing the number of layers on the vertical from 19 to 39 (15 in the stratosphere) and adding relevant parameterizations. The 39-layer version captures the dominant modes of the stratospheric variability and exhibits stratospheric sudden warmings. Changing either the vertical or horizontal resolution modifies the global energy balance in imposed-SST simulations by typically several W/m² which translates in the coupled atmosphere-ocean simulations into a different global-mean SST. The sensitivity is of about 1.2 K per 1 W/m² when varying the horizontal grid. A re-tuning of model parameters was thus required to restore this energy balance in the imposed-SST simulations and reduce the biases in the simulated mean surface temperature and, to some extent, latitudinal SST variations in the coupled experiments for the modern climate. The tuning hardly compensates, however, for robust biases of the coupled model. Despite the wide range of grid configurations explored and their significant impact on the present-day climate, the climate sensitivity remains essentially unchanged.