Nonequilibrium Radiative Hypersonic Flows: Aerospace Applications

Hyperenthalpic flows are encountered when spatial vehicules reenter the atmosphere (Anderson 1989) or in some astrophysical situations as in envelopes of cool pulsating stars (Lafon 1991). In reentry applications, a bow shock is created at the front of the vehicule. The plasma in the shock layer is highly collisional and the radiative heat flux is of the same order of magnitude as the convective heat flux. It is then necessary to take into account the coupling between aerodynamics and radiation. For high mach numbers, electronic collisional processes are out of equilibrium, and each atomic electronic level has to be considered as a distinct chemical species. The structure of the system is globally non-linear and the coupling is taken into account by mass conservation, energy exchange, and radiation-matter interaction. The radiative transfer also depends on atomic and molecular spectra in conditions of nonequilibrium for which cross sections and reaction rates are not well known and difficult to calculate. This revised version was published online in July 2006 with corrections to the Cover Date.     

Morphostructure of the Egyptian Continental Margin: Insights from Swath Bathymetry Surveys

In the Eastern Mediterranean, offshore Egypt, the Nile continental margin is characterized by a large deep water turbiditic system known as the Nile Deep Sea Fan. This post-Miocene terrigenous construction covers an approximately 10 km-thick sedimentary pile, including 1–3 km of Messinian salt layers. Systematically collected swath bathymetric data proved to be the most powerful tool to discover, describe and study many sea floor features of this sedimentary construction which reflects competition between active tectonic, sedimentary, and geochemical processes. Gravity tectonics, triggered by underlying mobile salt layers, construction of channel-levee systems, the passage of turbidite flows, sedimentary slope failures at various scales, massive mud expulsions and fluid seepages are all interfering to shape the Nile Deep Sea Fan seabed.     

Marble-hosted ruby deposits from Central and Southeast Asia: Towards a new genetic model

Marble-hosted ruby deposits represent the most important source of colored gemstones from Central and South East Asia. These deposits are located in the Himalayan mountain belt which developed during Tertiary collision of the Indian plate northward into the Eurasian plate. They are spatially related to granitoid intrusions and are contained in platform carbonates series that underwent high-grade metamorphism. All occurrences are located close to major tectonic features formed during Himalayan orogenesis, directly in suture zones in the Himalayas, or in shear zones that guided extrusion of the Indochina block after the collision in South East Asia. Ar–Ar dating of micas syngenetic with ruby and U–Pb dating of zircon included in ruby gives evidence that these deposits formed during Himalayan orogenesis, and the ages document the extensional tectonics that were active, from Afghanistan to Vietnam, between the Oligocene and the Pliocene.The petrography shows that ruby-bearing marbles formed in the amphibolite facies (T = 610 to 790 °C and P ~ 6 kbar). A fluid inclusion study defines the conditions of gem ruby formation during the retrograde metamorphic path (620 < T < 670 °C and 2.6 < P < 3.3 kbar) for the deposits of Jegdalek, Hunza and northern Vietnam.Whole rock analyses of non-ruby-bearing marbles indicate that they contain enough aluminum and chromiferous elements to produce all the ruby crystals that they contain. In addition, (C, O)-isotopic analyses of carbonates from the marbles lead to the conclusion that the marbles acted as a metamorphic closed fluid system that were not infiltrated by externally-derived fluids. The carbon isotopic composition of graphite in marbles reveals that it is of organic origin and that it exchanged C-isotopes with the carbonates during metamorphism. Moreover, the O-isotopic composition of ruby was buffered by metamorphic CO₂ released during devolatilisation of marble and the H-isotopic composition of mica is consistent with a metamorphic origin for water in equilibrium with the micas. The (C, O, H)-isotopic compositions of minerals associated with marble-hosted ruby are all in agreement with the hypothesis, drawn from the unusual chemistry of CO₂–H₂S–COS–S₈–AlO(OH)-bearing fluids contained in fluid inclusions, that gem ruby formed at P ~ 3 kbar and 620 < T < 670 °C, during thermal reduction of evaporite by organic matter, at high temperature-medium pressure metamorphism of platform carbonates during the Tertiary India–Asia collision. The carbonates were enriched in Al- and chromiferous-bearing detrital minerals, such as clay minerals that were deposited on the platform with the carbonates, and in organic matter. Ruby formed during the retrograde metamorphic path, mainly by destabilization of muscovite or spinel. The metamorphic fluid system was rich in CO₂ released from devolatilisation of carbonates, and in fluorine, chlorine and boron released by molten salts (NaCl, KCl, CaSO₄). Evaporites are key to explaining the formation of these deposits. Molten salts mobilized in situ Al and metal transition elements contained in marbles, leading to crystallization of ruby.     

Plant responses to global change: next generation biogeography

Global change has become a major ecological concern that has the potential to dramatically alter plant distributions and assemblages worldwide. The specific response of plants to global change will depend on their ability to move, evolve, or adjust through phenotypic plasticity. Advances in biogeographic research are on the verge of a giant leap forward if we can take advantage of emerging tools in genetics and genomics. In this review, we appraise how new, post-Sanger, high-throughput sequencing and associated technologies can be used by next generation biogeographers to assess plant responses to global change. First, we briefly review the recent advances in genome sequencing and available approaches of genomic analysis. Secondly, we discuss the three main plant responses to global change: migration, adaptation, and phenotypic plasticity. This review is intended to spark the interest of biogeographers who do not traditionally use genetics but could benefit from including genetic and genomic tools into their research. Our goal is to illustrate that their use can contribute to new perspective and add an additional level of resolution into future biogeographic research.     

Variability of precipitation intensity: sensitivity to treatment of moist convection in an RCM and a GCM

The present study investigates the sensitivity of the frequency distribution of precipitation rates to the closure employed in the penetrative mass flux cumulus parameterization of Zhang and McFarlane in the Canadian regional climate model (CRCM) and in the Canadian Centre for Climate Modelling and Analysis third generation global atmospheric general circulation model (AGCM3). The effects of an alternative prognostic closure for mass flux cumulus parameterization in place of the original diagnostic closure are investigated. A set of experiments is performed in which changes in the frequency distribution of precipitation rates and cloud base mass-flux are examined as a function of the parameters that define each closure scheme. The relationship between the frequency distribution of precipitation and cloud base mass flux is examined and a self-consistent relation is found when the depth of convection is taken into account. Experiments performed with the prognostic closure favor relatively strong cloud base mass-flux and deep penetrative convection with relatively more intense convective precipitation. The mean of the frequency distribution of convective precipitation is larger and the heavier events become more intense. Also, experiments performed with the prognostic closure favor less frequent convective activity. However these changes in the distribution of convective component of precipitation are generally offset by opposite changes in the distribution of the resolved large-scale component of precipitation, resulting in relatively smaller changes in total precipitation. The altered partition of precipitation between convective and large-scale components is found to alter the energy balance and the thermodynamic equilibrium structure of the troposphere. The robustness found in the CRCM results regarding the sensitivity of the frequency distribution of precipitation to changes in the closure of the deep convection parameterization is investigated by performing a similar analysis of AGCM3 simulations. A remarkable similarity of AGCM3 and CRCM results is found suggesting that the closure sensitivity identified in this study is robust.     

Enrichment of redox-sensitive trace metals (U,V, Mo,As) associated with the late Hauterivian Faraoni oceanic anoxic event

The Faraoni Level is a short-lived oxygen-deficient event that took place during the latest Hauterivian. In order to improve our understanding of the palaeoenvironmental conditions that occurred during this event, we have analysed the contents of several redox-sensitive trace elements (U, V, Mo, As, Co, Cd, Cu, Zn, Ni, Pb, Cr) from bulk limestone samples of late Hauterivian–early Barremian age from three reference sections. U, V, Mo and As show consistent and significant enrichments during the Faraoni event whereas the other redox-sensitive trace elements analysed here are not systematically enriched. In order to explain this discrepant behaviour, we propose that the Faraoni Level was deposited during a period of anoxic conditions near the sediment–water interface. The distinctive peaks in U, V, Mo and As contents are traceable throughout the three studied sections and represent a good correlation tool which helps to identify the Faraoni Level and its equivalents in the western Tethyan realm and outside of the Tethys. For example, a peak in U contents in upper Hauterivian sediments of the northwestern Pacific realm (ODP leg 185, site 1149) may well be an expression of the Faraoni event in this particular basin.