Malleable disc base for direct infiltration measurements using the tension infiltrometry technique

The correct use of the tension disc infiltrometer requires the membrane of the disc base to be completely in contact with the soil surface. To achieve this contact, a thick layer of sand is commonly placed between the soil surface and the disc base. This paper presents an alternative disc (M_DB), which, by incorporating a malleable membrane, allows direct infiltration measurements without using a contact sand layer. Infiltration curves obtained with this new design in a soil under three different tillage management treatments were compared with the corresponding curves obtained with a conventional disc (C_DB) that uses a contact sand layer. The cumulative infiltration curves measured with C_DB were analysed by the differentiated linearization (DL) method, and the corresponding curves obtained with M_DB were analysed using both the DL and the cumulative linearization (CL) models. The values of hydraulic conductivity (K₀) and sorptivity (S₀) estimated with C_DB were also compared with those obtained with M_DB. Finally, the cumulative infiltration curves measured with C_DB and M_DB were compared with the corresponding modelled function for the respective K₀ and S₀ values calculated with the CL and DL models. The results show that, compared with C_DB without a contact sand layer, M_DB allows complete soil surface wetting even when non‐smoothed soil surfaces are used. The C_DB, which yielded average K₀ values 18% lower than those estimated with M_DB, gave the highest values of standard error for the hydraulic parameters calculated. Furthermore, the subjective method employed in the C_DB‐DL technique, which requires the first points of the differential infiltration line corresponding to the sand layer to be manually removed, introduces additional uncertainties in estimating S₀ and K₀. Comparison between the modelled and measured infiltration curves demonstrates that the DL or CL methods applied to M_DB gave excellent estimates of S₀ and K₀. Copyright © 2012 John Wiley & Sons, Ltd.     

The simulation of European heat waves from an ensemble of regional climate models within the EURO-CORDEX project

The ability of a large ensemble of regional climate models to accurately simulate heat waves at the regional scale of Europe was evaluated. Within the EURO-CORDEX project, several state-of-the art models, including non-hydrostatic meso-scale models, were run for an extended time period (20 years) at high resolution (12 km), over a large domain allowing for the first time the simultaneous representation of atmospheric phenomena over a large range of spatial scales. Eight models were run in this configuration, and thirteen models were run at a classical resolution of 50 km. The models were driven with the same boundary conditions, the ERA-Interim re-analysis, and except for one simulation, no observations were assimilated in the inner domain. Results, which are compared with daily temperature and precipitation observations (ECA&D and E-OBS data sets) show that, even forced by the same re-analysis, the ensemble exhibits a large spread. A preliminary analysis of the sources of spread, using in particular simulations of the same model with different parameterizations, shows that the simulation of hot temperature is primarily sensitive to the convection and the microphysics schemes, which affect incoming energy and the Bowen ratio. Further, most models exhibit an overestimation of summertime temperature extremes in Mediterranean regions and an underestimation over Scandinavia. Even after bias removal, the simulated heat wave events were found to be too persistent, but a higher resolution reduced this deficiency. The amplitude of events as well as the variability beyond the 90th percentile threshold were found to be too strong in almost all simulations and increasing resolution did not generally improve this deficiency. Resolution increase was also shown to induce large-scale 90th percentile warming or cooling for some models, with beneficial or detrimental effects on the overall biases. Even though full causality cannot be established on the basis of this evaluation work, the drivers of such regional differences were shown to be linked to changes in precipitation due to resolution changes, affecting the energy partitioning. Finally, the inter-annual sequence of hot summers over central/southern Europe was found to be fairly well simulated in most experiments despite an overestimation of the number of hot days and of the variability. The accurate simulation of inter-annual variability for a few models is independent of the model bias. This indicates that internal variability of high summer temperatures should not play a major role in controlling inter-annual variability. Despite some improvements, especially along coastlines, the analyses conducted here did not allow us to generally conclude that a higher resolution is clearly beneficial for a correct representation of heat waves by regional climate models. Even though local-scale feedbacks should be better represented at high resolution, combinations of parameterizations have to be improved or adapted accordingly.     

Sedimentology of a wreck: the Rainbow Warrior revisited

The wreck of the Rainbow Warrior, a 40-m ship sunk on 12 December 1987 in Matauri Bay (34° 59′ S, 173° 56′ E), Cavalli Islands, northeastern New Zealand, offers an opportunity to investigate the impact of artificial substrate on temperate carbonate sedimentation. Surface sediment samples showed no significant textural or compositional difference between sediments near the wreck and those far from it. The large and diverse carbonate-producing community resident on the wreck (dominated by bryozoans, corals and sponges) has not had a measurable influence on adjacent bottom sediments (dominated by bivalves and barnacles), even after 21 years. It is likely that carbonate production on the Rainbow Warrior is insufficient to leave any sedimentary record over the potential lifetime of the wreck on the seafloor, which informs our understanding of the long-term impacts of shipwrecks (and other artificial substrata) on the local benthic environment in shallow temperate ecosystems.     

Microencapsulation of okadaic acid as a tool for studying the accumulation of DSP toxins in mussels

The possibility and effectiveness of microencapsulation of okadaic acid (OA) in gelatin-acacia microcapsules has been studied. The encapsulation efficiency was higher than 33%. The microcapsules were shown to be very stable, not leaching more than 9% of the encapsulated OA in a 20-h period. OA from the microcapsules was absorbed by the mussels very efficiently, accumulating--after 3 days of feeding and one of depuration--65% of the OA in microcapsules and 22% of the total OA used at the beginning of the microencapsulation process. These efficiencies and the possibility of encapsulating single DSP toxins and derivatives constitute a valuable tool for the study of the accumulation and biotransformation of DSP toxins in bivalves.     

Retrograde formation of NaCl-scapolite in high pressure metaevaporites from the Cordilleras Béticas (Spain)

A Permo-Triassic pelite-carbonate rock series (with interacalated metabasitic rocks) in the Cordilleras Béticas, Spain, was metamorphosed during the Alpine metamorphism at high pressures (P _min near 18 kbar). The rocks show well preserved sedimentary features of evaporites such as pseudomorphs of talc, of kyanite-phengitetalc-biotite, and of quartz after sulfate minerals, and relicts of baryte, anhydrite, NaCl, and KCl, indicating a salt-clay mixture of illite, chlorite, talc, and halite as the original rock. The evaporitic metapelites have a whole rock composition characterized by high Mg/(Mg+Ca) ratios>0.7, variable alkaline and Sr, Ba, contents, but are mostly K₂O rich (<8.8 wt%). The F (<2600 ppm), Cl (<3600 ppm), and P₂O₅ (<0.24 wt%) contents are also high. The pelitic member of this series is a fine grained biotite rock. Kyanite-phengite-talc-biotite aggregates in pseudomorphs developed in the high pressure stage. Albite-rich plagioclase was formed when the rocks crossed the albite stability curve in the early stages of the uplift. Scapolite, rich in NaCl (Ca/(Ca+Na) mol% 24–40) and poor in SO₄, with Cl/(Cl+CO₃) ratios between 0.6 and 0.8, formed as porphyroblasts, sometimes replacing up to 60% of the rock in a late stage of metamorphism (between 10 and 5 kbar, near 600°C). No reaction with albite is observed, and the scapolite formed from biotite by: $$\begin{gathered} Al - biotite + CaCO_3 + NaCl + SiO_2 \hfill \\ = Al - poor biotite + scapolite + MgCO_3 + KCl \hfill \\ + MgCl_2 + H_2 O \hfill \\ \end{gathered}$$ Calculated fluid composition in equilibrium with scapolite indicates varying salt concentrations in the fluid. Distribution of Cl and F in biotite and apatite also indicates varying fluid compositions.     

Unstable flow,magma mixing and magma-rock deformation in a deep-seated conduit: the Gil-Márquez Complex,south-west Spain

The Gil-Marquez Complex is an exceptional outcrop of plutonic rocks ranging in composition from diorites to granites emplaced into Devonian terrigenous metasediments of the southernmost part of the Hercynian basement of Iberia. A combined study of this complex, including field geology, petrology, structural geology and geochemistry, reveals that it represents an ancient conduit of magma transport through the continental crust. This conduit allowed the intrusion of magmas of contrasted compositions. Two end-members and several hybrids are identified. The first end-member is a biotite granite and the second is a basaltic magma generated by partial melting of a depletedmantle source. Both magmas rose through a common channel in which favorable conditions for unstable flow and magma mixing occurred. The observed relations in the Gil-Márquez Complex show that mixing in conduits may be an important mechanism for producing homogeneous hybrid magmas.     

Dissemination, technology transfer and environmental education criteria applied to hydrogeology, and specially, to managed aquifer recharge: proposal for a strategy to introduce these techniques to the population, and some examples for Spain

Information and environmental education play a very important role in raising awareness of hydrogeology, particularly the Managed Aquifer Recharge (MAR). One of the landmarks of the DINA-MAR (Depth Investigation of New Areas for Managed Aquifer Recharge) i&R&D project has been the design of a dissemination plan applicable to hydrogeology, and specially, to MAR activities. The initial planning included reviewing various proposals of strategies for information, training and dissemination aimed at different sectors of the population grouped into homogenous groups. Upon execution of the dissemination plan, it has been revealed that the combination of dissemination and technology transference techniques (hereafter D&TT) with environmental education and psychological techniques has a synergetic effect with respect to the classical dissemination of knowledge in hydrogeology. It is being tested and applied in the implantation of the technique of managed aquifer recharge in countries where implantation is not widespread, such as Spain. As a result of the development of material and procedures for dissemination over 4 years, an embryonic strategy has been drawn up. It is a complex process which finally leads to a master catalogue that relates activities to target groups and their impact rate. This master catalogue allows the roll-out process of D&TT to be handled with a certain degree of planning, incorporating technical criteria with the transfer of the philosophy of dissemination, as a centrifugal process, from development groups to homogenous groups, from management and authorities to the general public, defining the limits of the circles of dissemination and the strategic directions. It also considers feedback methods and establishes stages to give the process a chronological order. In addition, some examples already tested in Spain to date are presented, not only activities, but also materials, most of them within the framework of the referenced project.     

Groundwater quality assessment using data clustering based on hybrid Bayesian networks

Bayesian networks (BNs) have become a standard in the field of Artificial Intelligence as a means of dealing with uncertainty and risk modelling. In recent years, there has been particular interest in the simultaneous use of continuous and discrete domains, obviating the need for discretization, using so-called hybrid BNs. In these hybrid environments, Mixtures of Truncated Exponentials (MTEs) provide a suitable solution for working without any restriction. The objective of this study is the assessment of groundwater quality through the design and application of a probabilistic clustering, based on hybrid Bayesian networks with MTEs. Firstly, the results obtained allows the differentiation of three groups of sampling points, indicating three different classes of groundwater quality. Secondly, the probability that a sampling point belongs to each cluster allows the uncertainty in the clusters to be assessed, as well as the risks associated in terms of water quality management. The methodology developed could be applied to other fields in environmental sciences.