Quantitative climate reconstruction linking meteorological,limnological and XRF core scanner datasets: the Lake Sanabria case study,NW Spain

Monthly limnological monitoring in Lake Sanabria (Spain) since 1986 provided a unique opportunity to test relationships among climate, hydrology and lake dynamics and how they are recorded in the lake sediments. Four datasets were employed: (1) meteorological (monthly maximum and minimum air temperature and total precipitation), (2) limnological (Secchi disk, water temperature, conductivity, pH, dissolved oxygen, nitrate, silicon, total and reactive phosphorus, and total chlorophylls and chlorophyll a), (3) hydrological (Tera River water input and output), and (4) XRF core scanner measurements carried out in short cores. Linear models between the different dataset variables allowed us to characterize the climate signal transmission from one to the other and cross-correlation analyses permitted us to identify the different response times (if any) between them. Principal Component Analyses (PCA) of the limnological and geochemical datasets allowed us to identify the main processes that link lake dynamics, primarily nutrient supply and organic productivity, with some sedimentological processes, e.g. organic matter and phosphorus accumulation. Sediment chronology was established by gamma spectrometry (²¹⁰Pb). Water input to Lake Sanabria is controlled mostly by the Tera River input and is linked directly to precipitation. Response of the Lake Sanabria water budget to climate oscillations is immediate, as the strongest correlation between these two datasets occurs with no lag time. PCA of the limnological dataset indicated that most of the variance is related to nutrient input, and comparison with the Tera River water discharge shows that nutrient input was controlled mainly by oscillations in the hydrological balance. The lag time between the hydrological and limnological datasets is 1 month. The PCA of the XRF core scanner dataset showed that the principal process that controls the chemical composition of the Lake Sanabria sediments is related to sediment and nutrient delivery from the Tera River and organic productivity. Comparison of the nutrient input reconstructed using the limnological dataset and the XRF core scanner data indicated that the sediments act as a low-pass filter, smoothing the climate signal. It was, however, possible to establish the link between these datasets, and obtain a quantitative reconstruction of precipitation for the 1959–2005 AD period that captures the regional variability. This quantitative precipitation reconstruction suggests it is possible to obtain accurate climate reconstructions using non-laminated sediments.     

Seasonal and diel patterns of total gaseous mercury concentration in the atmosphere of the Central Valley of Costa Rica

Monitoring of Hg in the atmosphere near volcanoes is limited with no previous data for Costa Rica. Seasonal and daily patterns of total gaseous mercury (TGM) were observed at the main sampling location at the Universidad Nacional, Heredia, Costa Rica. The area (lat. 10.000230 long. −84.109499) is located in the Central Valley of Costa Rica and is 27 km SE of the Poas volcano (lat. 10.199486 long. −84.231388). Measurements were made from May 2008 to May 2009 at this location with some additional values obtained at other sites near the Poas volcano including San Luis and Grecia as well as near, Turrialba and Irazu volcanoes. Total gaseous Hg was determined in samples collected at a height of 2 m using the Tekran 2537A (Tekran Inc.) gas-phase Hg vapor analyzer. Meteorological data (temperature, relative humidity, wind speed, wind direction, radiation and precipitation) were obtained from the airport weather station located at Alajuela. Monthly precipitation is typically 85 mm during the dry season (December to April) with winds from the west. The wet season begins in late April and continues to December with monthly rainfall of 328 mm and winds from the NE. The annual mean temperature is 20 °C. With the onset of the wet season TGM increased from typical values near 10 to 905 ng m⁻³. Measurements made within 5 km of the Poas volcano were higher than at Heredia at that time. Diel values measured at the university site increased until midday along with temperature and radiation. Relative humidity showed a reciprocal pattern. It was found that high values of TGM were not related to wind velocity or direction. The strong diel pattern increased with sunrise, peaked at midday and was lowest during the night time. It would seem that Hg⁰ from the volcano is oxidized and is deposited to the soils during the dry season when winds are blowing from the volcano. With the onset of heavy rains in April, Hg in the soil is reduced and re-volatilized resulting in the high levels in the atmosphere. Values at other volcano sites were provided. The role of atmospheric pollutants such as H₂O₂ and O₃ should be included in future studies as they may result in oxidation of reduced Hg. The instability in the air masses may also be a factor and local pollution sources may result in high levels that is emitted from the volcanoes of Hg being circulated to ground level as radiation intensity increases.     

Modelling the effect of soil burn severity on soil erosion at hillslope scale in the first year following wildfire in NW Spain

Fire severity is recognized as a key factor in explaining post‐fire soil erosion. However, the relationship between soil burn severity and soil loss has not been fully established until now. Sediment availability may also affect the extent of post‐fire soil erosion. The objective of this study was to determine whether soil burn severity, estimated by an operational classification system based on visual indicators, can significantly explain soil loss in the first year after wildfire in shrubland and other areas affected by crown fires in northwest (NW) Spain. An additional aim was to establish indicators of sediment availability for use as explanatory variables for post‐fire soil loss. For these purposes, we measured hillslope‐scale sediment production rates and site characteristics during the first year after wildfire in 15 experimental sites using 65 plots. Sediment yields varied from 0.2 Mg ha^?1 to 50.1 Mg ha^?1 and soil burn severity ranged from low (1.8) to very high (4.5) in the study period. A model that included soil burn severity, annual precipitation and a land use factor (as a surrogate for sediment availability) as explanatory variables reasonably explained the erosion losses measured during the first year after fire. Model validation confirmed the usefulness of this empirical model. The proposed empirical model could be used by forest managers to help evaluate erosion risks and to plan post‐fire stabilization activities. Copyright © 2015 John Wiley & Sons, Ltd.     

A new jadeitite jade locality (Sierra del Convento, Cuba): first report and some petrological and archeological implications

A new jadeitite jade locality has been discovered in the serpentinite-matrix subduction mélange of the Sierra del Convento (eastern Cuba) in a context associated with tectonic blocks of garnet-epidote amphibolite, tonalitic–trondhjemitic epidote gneiss, and blueschist. The mineral assemblages of jadeitite jade and jadeite rocks are varied and include combinations of jadeite, omphacite, albite, paragonite, analcime, clinozoisite-epidote, apatite, phlogopite, phengite, chlorite, glaucophane, titanite, rutile, zircon, and quartz formed during various stages in their P–T evolution. Field relationships are obscure, but some samples made almost exclusively of jadeite show evidence of crystallization from fluid in veins. In one of these samples studied in detail jadeite shows complex textural and chemical characteristics (including oscillatory zoning) that denote growth in a changing chemical medium. It is proposed that interaction of an Al–Na rich fluid with ultramafic rocks produced Al–Na–Mg–Ca fluids of varying composition. Episodic infiltration of these fluids, as a result of episodic opening of the veins, developed oscillatory zoning by direct precipitation from fluid and after reaction of fluid with pre-existing jadeite. The latest infiltrating fluids were richer in Mg–Ca, favouring the formation of omphacite and Mg–Ca rich jadeite in open voids and the replacement of earlier jadeite by fine-grained omphacite + jadeite at 550–560°C. This new occurrence of jadeite in Cuba opens important perspectives for archeological studies of pre-Columbian jade artifacts in the Caribbean region.     

Vibration Simulation Method to Control Stability in the Northeast Corner of Escondida Mine

Vibrations due to production blasting can induce damage to the rock mass at large distances by altering larger geological structures, fault areas or other structures, where the orientation with respect to the mine geometry is unfavorable and can cause displacement of large rock volumes. Past occurrences of this nature in Escondida Mine placed geomechanical safety restrictions as to maximum allowable blast size in the northeast area of the mine. These restrictions limited the efficiency of drilling and blasting operations seriously limiting daily production. This is what prompted this study to attempt to increase shot size while reducing stability problems. This would permit keeping stable the slope over which the ore extraction belts are located, as well as the main access ramp to the mine. Using a rigorous and systematic instrumentation and monitoring effort of blasting vibrations at multiple locations with respect to an unstable location allowed the development of a database to establish acceptable vibrations limits. A parallel effort was the development and gauging of a mechanistic model for the prediction and simulation of blasting vibrations. Excellent results were obtained from a comparison between the measured and predicted results. This allowed the use of the gauged model to verify the practicality of increasing the shot size in the restricted blasting zones, without exceeding safe vibration limits. The practical success achieved using this research approach resulted in increased blasting size, with a consequent increase of blasted material per shot, and contributed to more flexible mining operations.     

Streamflow drought time series forecasting: a case study in a small watershed in North West Spain

Drought is a climatic event that can cause significant damage both in natural environment and in human lives. Drought forecasting is an important issue in water resource planning. Due to the stochastic behaviour of droughts, a multiplicative seasonal autoregressive integrated moving average model was applied to forecast monthly streamflow in a small watershed in Galicia (NW Spain). A better streamflow forecast obtained when the Martone index was included in the model as explanatory variable. After forecasting 12 leading month streamflow, three drought thresholds: streamflow mean, monthly streamflow mean and standardized streamflow index were chosen. Both observed and forecasted streamflow showed no drought evidence in this basin.     

Chicxulub impact ejecta from Albion Island, Belize

Impact ejecta from the Albion Formation are exposed in northern Belize. The ejecta come from the outer portion of the continuous ejecta blanket of the Chicxulub crater, which is located 360 km to the northwest. The basal unit of the Albion Formation is a 1-m-thick clay and dolomite spheroid bed composed of up to four discrete flows. The clay spheroids are altered impact glass, and the dolomite spheroids are accretionary lapilli. The upper unit is a 15-m-thick coarse diamictite bed containing altered glass, large accretionary blocks, striated, polished, and impacted cobbles, and rare shocked quartz. The abundance of accretionary clasts, evidence for atmospheric drag sorting, and the presence of multiple flows in the Albion Formation indicate that atmospheres play an important role in the formation of the outer portions of continuous ejecta blankets of large craters.     

Visual versus digital analysis for vegetation mapping: Some examples on central Spain

Digital processing of Landsat images has been considered the most appropriate interpretation method for vegetation mapping. However, digital processing presents several difficulties: (i) it demands significant inversions, with respect both the images and the equipment; (ii) it presents problems to discriminate heterogeneous categories, and (iii) it requires much more training effort.

Visual analysis, on the other hand, is less demanding both in economic investments and training. Therefore, it is a fruitful alternative to digital mapping, especially when it is applied to small and medium scale inventories. A consistent methodology for visual interpretation of vegetation categories is presented in this paper. Benefits and disadvantages of this procedure are analyzed, as well as keys‐for visual identification of land cover categories. A TM Quarter of scene on Central Spain is presented as an example of this method. Two false‐color images from different seasons were interpreted at 1: 250,000 scale. Fourteen land cover categories were identified, yielding 83.03% of final accuracy.     

On soil-structure interaction in large non-slender partially buried structures

This paper addresses the seismic analysis of a deeply embedded non-slender structure hosting the pumping unit of a reservoir. The dynamic response in this type of problems is usually studied under the assumption of a perfectly rigid structure using a sub-structuring procedure (three-step solution) proposed specifically for this hypothesis. Such an approach enables a relatively simple assessment of the importance of some key factors influencing the structural response. In this work, the problem is also solved in a single step using a direct approach in which the structure and surrounding soil are modelled as a coupled system with its actual geometry and flexibility. Results indicate that, quite surprisingly, there are significant differences among prediction using both methods. Furthermore, neglecting the flexibility of the structure leads to a significant underestimation of the spectral accelerations at certain points of the structure.