Environmental impact of blasting at Drenovac limestone quarry (Serbia)

In present paper, the blast-induced ground motion and its effect on the neighboring structures are analyzed at the limestone quarry "Drenovac" in central part of Serbia. Ground motion is examined by means of existing conventional predictors, with scaled distance as a main influential parameter, which gave satisfying prediction accuracy (R > 0.8), except in the case of Ambraseys–Hendron predictor. In the next step of the analysis, a feed-forward three-layer back-propagation neural network is developed, with three input units (total charge, maximum charge per delay and distance from explosive charge to monitoring point) and only one output unit (peak particle velocity). The network is tested for the cases with different number of hidden nodes. The obtained results indicate that the model with six hidden nodes gives reasonable predictive precision (R ≈ 0.9), but with much lower values of mean-squared error in comparison to conventional predictors. In order to predict the influence level to the neighboring buildings, recorded peak particle velocities and frequency values were evaluated according to United States Bureau of Mines, USSR standard, German DIN4150, Australian standard, Indian DMGS circular 7 and Chinese safety regulations for blasting. Using the best conventional predictor, the relationship between the allowable amount of explosive and distance from explosive charge is determined for every vibration standard. Furthermore, the effect of air-blast overpressure is analyzed according to domestic regulations, with construction of a blasting chart for the permissible amount of explosive as a function of distance, for the allowable value of air-blast overpressure (200 Pa). The performed analysis indicates only small number of recordings above the upper allowable limit according to DIN4150 and DMGS standard, while, for all other vibration codes the registered values of ground velocity are within the permissible limits. As for the air-blast overpressure, no damage is expected to occur.     

Mercury speciation in surface and deep waters of the Mediterranean Sea

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.     

The relation between rigorous and Helmert’s definitions of orthometric heights

Following our earlier definition of the rigorous orthometric height [J Geod 79(1-3):82–92 (2005)] we present the derivation and calculation of the differences between this and the Helmert orthometric height, which is embedded in the vertical datums used in numerous countries. By way of comparison, we also consider Mader and Niethammer’s refinements to the Helmert orthometric height. For a profile across the Canadian Rocky Mountains (maximum height of ~2,800 m), the rigorous correction to Helmert’s height reaches ~13 cm, whereas the Mader and Niethammer corrections only reach ~3 cm. The discrepancy is due mostly to the rigorous correction’s consideration of the geoid-generated gravity disturbance. We also point out that several of the terms derived here are the same as those used in regional gravimetric geoid models, thus simplifying their implementation. This will enable those who currently use Helmert orthometric heights to upgrade them to a more rigorous height system based on the Earth’s gravity field and one that is more compatible with a regional geoid model.     

Central Paratethys paleoenvironment during the Badenian (Middle Miocene): evidence from foraminifera and stable isotope (δ<Superscript>13</Superscript>C and δ<Superscript>18</Superscript>O) study in the Vienna Basin (Slovakia)

Stable isotope data of the foraminiferal carbonate shells and bulk sediment samples from the Central Paratethys were investigated to contribute to better knowledge of the paleoenvironmental changes in Badenian (Middle Miocene). Five benthic (Uvigerina semiornata, U. aculeata, Ammonia beccarii, Elphidium sp. and Heterolepa dutemplei) and three planktonic taxa (Globigerina bulloides, G. diplostoma and Globigerinoides trilobus), characterising the bottom, intermediate and superficial layers of the water column, were selected from the Vienna Basin (W Slovakia). The foraminiferal fauna and its isotope signal point out to temperature-stratified, nutrient-rich and consequently less-oxygenated marine water during the Middle/Late Badenian. Negative carbon isotope ratios indicate increased input of ¹²C-enriched organic matter to the bottom of the Vienna Basin. Positive benthic δ¹⁸O implies that the global cooling tendency recorded in the Middle Miocene has also affected the intramountain Vienna Basin. In this time, the Central Paratethys has been in the process of isolation. Our stable isotope trend suggests that the communication with Mediterranean Sea has been still more or less active on the south of Vienna Basin (Slovak part) in the Late Badenian, whereas the seawater exchange towards north was apparently reduced already during the Middle Badenian.     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.     

Impact of an inter‐basin water transfer and reservoir operation on a karst open streamflow hydrological regime: an example from the Dinaric karst (Croatia)

This paper describes the hydrological changes caused by inter‐basin water transfer and the reservoir development on the hydrological regimes of two rivers. The Sabljaki Reservoir in the Zagorska Mre?nica River and the Bukovik Reservoir in the upper Dobra River began operation in 1959. Both are part of the hydroelectric power plant (HEPP) Gojak, whose installed capacity is 50 m³/s. Their water volumes at the spillway altitudes of 320·10 and 320·15 m a. s. l. are 3·3 × 10⁶ and 0·24 × 10⁶ m³ respectively. Both the Dobra and Mre?nica Rivers are losing, sinking and underground karst rivers. A 9376‐m‐long tunnel provides water from the Sabljaki Reservoir to the HEPP Gojak, which was constructed in the Lower Dobra River. The Sabljaki Reservoir is located in the Pla?ki karst polje, while the Bukovik Reservoir is located in the neighbouring Ogulin karst polje. The consequences of the inter‐basin water transfer are strong and have caused abrupt changes in the hydrological regimes of the downstream sections of both rivers. At the same time, the construction and development of both the reservoirs have also caused hydrological changes to the upstream section of the Upper Dobra River. Copyright © 2010 John Wiley & Sons, Ltd.     

Magnetic susceptibility anisotropy of deformed rocks

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Some long-lived supergranules

Evidence is given that some supergranules have lifetimes of 72 hours or more.     

Electrical conductivity of rocks in the heating and cooling cycle

Summary The values of the electrical conductivity, recorded during the heating and cooling cycle, of eclogites and basalts are compared. The observed difference in the values is explained by reversible and irreversible changes which take place in the samples.