Simulation of acid water movement in canals

An attempt to tackle the problem of the propagation of acid water in canals is described, and a mathematical model to simulate the acid water movement is developed, in which the jurbanite equilibrium is found to prevail. The processes of settling owing to sedimentation, precipitation and redissolution have been considered in the modelling. Data available from Tan Thanh, in the Plain of Reeds of the Mekong Delta in Viet Nam, are used as a case study.     

Stochastic sketching of infiltration-advance isochrones

A technique has been developed for predicting the irregular advance pattern often observed as water spreads on the surface of the ground. The technique is a combination of stochastic sketching, potential theory, probability theory, and a mass balance equation in the form of an advance equation. The technique can be used on flat as well as sloping terrain and addresses any form of obstructions or constraints to the flow of the water. The stochastic sketching portion of the technique uses cellular automata with transition probability movement rules to sketch the dynamics of small volume water elements in the defined environment. Randomly selected small volume flow path segments are computed and plotted. The envelope of these segments defines the wetted area and the advance front. Several examples are presented showing the patterns produced for various situations.     

Temperature dependence of the 57Fe Mössbauer parameters in riebeckite

Mössbauer spectra for two riebeckite minerals were collected at temperatures in the range 4.2 to 500 K. The magnetic-ordering temperatures were found to be 33±1 and 31±1 K respectively. Fitting the paramagnetic spectra with a discrete number of doublets (three or four) did not lead to consistent results. Instead, a superposition of an Fe³⁺ (M2) doublet and one distributed ferrous component was found to produce adequate fits with reasonable parameter values. For both samples, a minor fraction of ferrous ions was observed to be present at the M4 sites and for one of the samples at the M2 sites as well. The temperature variations of the center shifts were well reproduced using the Debye model of the lattice vibrational spectrum to evaluate the second-order Doppler shift. The characteristic Mössbauer temperatures were calculated to be in the range 340–390 K for Fe²⁺, and 520 K for Fe³⁺. The temperature dependences of the various ferrous quadrupole splittings could not be explained in terms of the point-charge model and assuming a temperature-independent energy-level scheme for the ⁵D term. It is suggested that a gradual change with temperature of the orbital-level splittings takes place. All calculations yielded a positive sign for the principal component of the electric field gradient (EFG). The spectrum recorded at 4.2 K for one of the riebeckites was fitted with a superposition of an Fe³⁺ and a Fe²⁺ hyperfine-field distribution, the latter one primarily characterizing the Fe²⁺ (M1) cations. The following relevant hyperfine data were calculated: H _hf=161 kOe, ΔE _Q=3.11 mm/s, and V _zz<0, all referring to the maximum-propability values. For the second riebeckite at 4.2 K, an additional distributed ferrous component could independently be resolved. The two maximum-probability hyperfine fields were found to be 189 and 98 kOe and the corresponding ΔE _Q values 3.10 and 2.67 mm/s. Both components exhibit a negative V _zz. The subspectra were attributed to M1 and M3 sites respectively. The Fe³⁺ hyperfine fields are 548+-2 kOe for both riebeckites. The different values found for the Fe³⁺ quadrupole shift 2?_Q for the two samples is explained by a different angle between the hyperfine field and the EFG's principal axis. The magnetic spectra recorded at 15 K and higher, could not be reproduced adequately with reasonable parameter values.     

Planning of Soil-Pore Water Sampling Campaigns Using Pesticide Transport Modeling

Soil-pore water sampling by suction lysimeters monitors the fate of soil contaminants as a function of depth and time. However, sampling campaigns must be planned to most effectively monitor the migration of contaminants with a minimum expenditure of resources. The vertical migration of pesticides was studied at two sites treated with systemic s-triazine herbicides and equipped with suction lysimeters. The measured concentrations were compared with those calculated by a simulation model. This modeling was based on the processes that control the transport and fate of pesticide within the soil. The usefulness of such a tool was demonstrated by the good approximation obtained for pesticide concentrations and arrival times. Moreover, the significant spatial variability of concentrations observed justifies the use of a stochastic approach in modeling that takes into account the spatial variability of soil parameters. Also, the rapid transformation of herbicides observed in unsaturated soil zones demonstrates the importance of taking into account the sum of the toxic residues when evaluating the fate of s-triazines in soil.     

Pounding of buildings modelled by an impact oscillator

Pounding of adjacent buildings is modelled by an impact oscillator subjected to harmonic excitation. Non-linear impact stiffness is represented by a Hertz-type relationship. Spectra of impact velocity are presented for a range of model parameters. These spectra are characterized by a strong peak near a period equal to one half the natural period of a similar non-impacting oscillator. Bands of response are found in which periodic multiple impacts and non-periodic or chaotic impacts occur.     

Carbon sources in arc volcanism, with implications for the carbon cycle

New CO₂/³ He data from the East Sunda Arc (Indonesia) confirm earlier observations that arc volcanic gases have higher CO₂/³ He ratios than MOR environments.On average, > 80% of arc volcanic CO₂ is recycled, exogene carbon. Addition of a few percent of carbonate-bearing sediments to the mantle wedge explains much of the carbon abundance andcarbon isotopic data of arc gases, but can not explain the He isotope observations. The CO₂/³He in arc volcanoes is not strongly dependent on the composition of modem trough sediments (e.g. deep sea clays vs carbonate-rich sequences), and calcite veins in the hydrothermally altered subducted slab may provide a contribution to the recycled carbon flux of, arcs. The sum of globally deep-subducted sediment and slab carbon exceeds the estimated arc CO₂ flux, and approximately 3.5 teramole of carbon may return annually to the mantle in convergent zones. The modem combined processes of MOR volcanism, slab alteration, and subduction volcanism do not produce a substantial carbon flux into the exosphere, and rate-changes in ocean floor spreading are unlikely to cause major changes in atmospheric CO₂ as a result of changes in the volcanic CO₂ fluxes. Intense pulses of flood basalt volcanism, however, may alter the CO₂ contents of the atmosphere over the course of a millenium or so, and influence global climate.     

Land degradation impacts on tropical agricultural basins and their management: the Nigerian example

This study uses the fault-tree technique to identify the major effects of land degradation caused by the adoption of a malfunctioning shifting cultivation technology for food production in tropical basins. Through reference to existing empirical research, the sequence of events in the process of degradation of the Nigerian agricultural basins and the adjoining river systems was identified and related to the appropriate causal agent. A complete picture of the cost of land degradation goes beyond the degraded terrain and includes damage in areas where there is an unloading of large quantities of run-off and sediments. The causal pathway showed that existing land degradation management policies have focused on the symptoms rather than on the cause of the degradation process. Through a thorough examination of those malfunctioning components of the traditional farming technology, appropriate management strategies are proferred. An institutional organization for land degradation management in Nigeria which includes the federal, state and local governments is strongly recommended.