Absence of extraterrestrial He in Permian-Triassic age sedimentary rocks

Helium concentration and isotopic composition were measured in a suite of samples across the Permian-Triassic boundary at Opal Creek, Canada, to determine whether high extraterrestrial helium concentrations are associated with a possible extinction-inducing impact event at this time. No extraterrestrial ³He was detected, implying that neither fullerene-hosted nor IDP-hosted He is present at or near the boundary. This observation is consistent with similar studies of some Permian-Triassic sections, but contrasts sharply with reports of both fullerene- and IDP-hosted extraterrestrial ³He at other sections.Step-heat experiments indicate rapid diffusion of extraterrestrial helium from sediments heated to temperatures above ∼ 70 °C. Given the likelihood of burial and associated heating in Permian-Triassic age rocks, the initially unexpected absence of IDP-hosted ³He likely indicates thermally induced diffusive loss. Indeed one of the key sections (Graphite Peak, Antarctica) from which extraterrestrial ³He has been reported at and near the Permian-Triassic boundary has been sufficiently heated that the reported preservation of extraterrestrial helium, in both IDPs and fullerenes, is inexplicable. Recent contamination provides a plausible explanation for extraterrestrial ³He in these samples.While no extraterrestrial ³He was detected at Opal Creek, there is a sharp increase in nucleogenic ³He very close to or at the Permian-Triassic boundary. This presumably arises from the major lithologic change at this time, from cherts in the Permian to shales and siltstones in the Triassic. Increased nucleogenic ³He is associated with increases in both lithium and organic carbon content into the Triassic. Either the production rate or the retention of this ³He is higher in the shales and siltstones than in the cherts. Care must be taken to eliminate such artifacts before interpreting changes in ³He concentration in terms of fluctuations in the delivery of ³He from space.     

Curie-point depth from spectral analysis of magnetic data in central-southern Europe

The basal depth of the outer layer with internal magnetic sources was calculated from magnetic data available within a roughly 500 km wide and 1200 km long area, running from central Germany to southern Italy. The dataset, deriving from different aeromagnetic surveys, is reduced to the reference altitude of 3000 m a.s.l. and a reference year of 1980.0. The adopted method, which transforms the spatial data into the frequency domain, provides a relationship between the two-dimensional spectrum of the magnetic anomalies and the top and centroid depths of the magnetic sources. The magnetic layer bottom depth (MLBD) thus obtained is 29-33 km deep in the stable areas (central Europe Variscan units, Corsica-Sardinia Variscan block) and corresponds to the Moho, having an average temperature of 560 °C. From the Alps to the Apennines, MLBD ranges between 22 and 28 km and is clearly shallower than the Moho. In these units, the wide variation of MLBD appears to be compatible with the presence of shallow magnetised bodies, consisting of lower crustal rocks (Ivrea-Verbano zone), ophiolitic units (Penninic zone and Voltri Massif) and intrasedimentary basic volcanic bodies (Po Basin). An average value of 25 km can be attributed to MLBD, which corresponds to a temperature of 550 °C. In the peri-Tyrrhenian zone and the Ligurian Sea, MLBD is below the Moho, which ranges from 17 to 20 km depth, and it has a temperature matching approximately to the Curie temperature of magnetite (580 °C).     

Controlling factors of gullying in the Maracujá Catchment,southeastern Brazil

Hundreds of gullies (‘voçorocas’) of huge dimensions (up to 400–500 m long, 150 m wide and 50 m deep) are very common in the small Maracujá Catchment in southeastern Brazil. These erosional features, which occur with an uneven intensity throughout the area, started due to bad soil management practices at the beginning of European settlement, at the end of the 17th century, and nowadays are still evolving, but at a slower rate. As surface soils are usually very resistant to erosion, the outcrop of the more erodible basement saprolites seems to be an essential condition for their beginning. An analysis of well known erosion controlling factors was performed, aiming to explain the beginning and evolution of these gullies and to understand the reasons for their spatial distribution. Data shows that geology and, mainly, geomorphology are the main controlling factors, since gullies tend to be concentrated in basement rock areas with lower relief (domain 2) of Maracujá Catchment, mainly at the fringes of broad and flat interfluves. At the detailed scale (1:10 000), gullies are more common in amphitheatre‐like headwater hollows that frequently represent upper Quaternary gullies (paleogullies), which demonstrate the recurrence of channel erosion. So, gullies occur in areas of thicker saprolites (domain 2), in places with a natural concentration of surface and underground water (hollows). Saprolites of the preserved, non‐eroded hollows are usually pressurized (confined aquifer) due to a thick seal of Quaternary clay layer, in a similar configuration to the ones found in hollows of mass movement (mudflow) sites in southeastern Brazil. Therefore, the erosion of the resistant soils by human activities, such as road cuts and trenches (‘valos’), or their mobilization by mudflow movements, seem to be likely mechanisms of gullying initiation. Afterwards, gullies evolve by a combination of surface and underground processes, such as wash and tunnel erosion and falls and slumps of gully walls. Copyright © 2005 John Wiley & Sons, Ltd.     

Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

Energetic Particles Observed in the CUSP Region During a Storm Recovery Phase

In this paper we report energetic ion behavior and its composition variations observed by the Cluster/RAPID instrument when the spacecraft was travelling in the high latitude magnetospheric boundary region on the day of the 31 March, 2001, strongest magnetic storm in the past 50 years. The Dst index reached −360 nT at about 09:00 UT. During its early recovery phase, large amounts of oxygen and helium ions were observed; the ratio of oxygen to hydrogen in the RAPID energy range reached as high as 250%, which suggests that the observed energetic particles might be of magnetospheric origin. The observations further show that enhanced energetic electron fluxes are confined in a very narrow region, while protons have occupied a larger region, and heavy ions have been observed in an even larger region. The flux of energetic electrons show a slight enhancement in a region where the magnetic field magnitude is around zero. These observed energetic ions could be quasi-trapped by the current sheet in the stagnation region of the cusp.     

Assessment of the Geochemical Background and Anthropogenic Load by Bioaccumulation of Microelements in Fish

Comparative characteristic of several microelements (Ni, Cu, Sr, Al, Zn, Co, Mn, Pb, Cd, Hg, As) found in fish (case study of breams in the Volga basin reservoirs) is presented. Regularities of accumulation of these elements in fish depending on their concentration in the water are analyzed. Main disturbances in fish caused by the accumulation of microelements in their organs and tissues are considered.