Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Chronology and evolution of the northern Iceland Plateau

New aeromagnetic data, K-Ar age determinations of dredged marine igneous rocks, as well as other geophysical evidence have shed light on the chronology, nature and evolution of the northern Iceland Plateau. Correspondence between seismic refraction profiles taken on the Jan Mayen Ridge and westward through Jan Mayen Island, suppressed aeromagnetic anomalies, earthquake surface wave studies, and ages of dredged igneous rocks suggest these strata may form an extended region of thickened crust, possibly of Caledonian age, extending westward toward the Kolbeinsey Ridge and northwest to the south wall of the Jan Mayen Fracture Zone.     

Characterization of soil's structural crust by spectral reflectance in the SWIR region (1.2–2.5 μm)

Structural crust is a thin layer formed on the soil surface after a rainstorm. The crust is the result of a physical segregation and rearrangement of soil particles in a way that affects some of the soil properties, such as infiltration, runoff and soil erosion. In practice, there is no rapid, in situ method for monitoring, assessing and mapping crust intensity and quality. In this study, a controlled spectral investigation of the structural crust across the NIR–SWIR spectral region was conducted on three selected Israeli soils, to study the potential of reflectance radiation to detect structural crust in soils. Two major factors served as the driving forces for this study: (1) there is no valid method for in situ assessment of the crust's characteristics in the agriculture field, and (2) the crust might bias thematic remote sensing of soils, because the thin layer of crust blocks photon–matter interaction, which represents the relevant soil body. Through the use of a laboratory rainfall simulator and a sensitive spectrometer, it was revealed that for three selected soils, significant spectral differences occurred between the crust and its bulk soil. The spectral information was found to be related to changes in particle size distribution and texture at the surface of the soil. This conclusion was based on indications of absorption of OH in clay lattice, OH in adsorbed water and CO₃ in carbonates. It was concluded that the structural crust is a phenomenon that should not be ignored by remote-sensing users. In fact, in the field of agriculture, the spectral properties of crust can be used as tools for estimating the crust's intensity.     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000     

Pre-collisional high pressure metamorphism and nappe tectonics at active continental margins: a numerical simulation

The evolution of a subduction channel and orogenic wedge is simulated in 2D for an active continental margin, with P-T paths being displayed for selected markers. In our simulation, subduction erosion affects the active margin and a structural pattern develops within a few tens of millions of years, with four zones from the trench into the forearc: (i) an accretionary complex of low grade metamorphic sedimentary material, (ii) a wedge of nappes with alternating upper and lower crustal provenance, and minor interleaving of oceanic or hydrated mantle material, (iii) a megascale melange composed of high pressure (HP) and ultra-high pressure (UHP) metamorphic rocks extruded from the subduction channel, and (iv) the upward tilted frontal part of the remaining lid. The P–T paths and time scales correspond to those typically recorded in orogenic belts. The simulation shows that HP/UHP metamorphism of continental crust does not necessarily indicate collision, but that the material can be derived from the active margin by subduction erosion and extruded from the subduction channel beneath the forearc during ongoing subduction.     

Deep-ocean vertical noise directionality

The structure of beam noise measured at the output of a vertical array in a range dependent ocean basin was investigated using the modified wide-angle parabolic equation (PE). Noise sources were distributed throughout the basin, and the field due to each noise source at an array located in the midbasin was calculated. The response of the array to the superposition of the noise sources was found by beamforming. An efficient and direct approach that superimposes the noise sources on the PE field as the field is marched toward the array was developed. Downslope calculations of the midbasin vertical directionality were made between 50 and 400 Hz with this technique. Use of a geoacoustic model shows that the bottom behaves as a low-pass filter     

Inverted echo sounder measurement of dynamic height through an ENSOcycle in the central equatorial Pacific

A four-year record from an inverted echo sounder deployed near Palmyra Island at 6°N in the central Pacific Ocean is compared with a simultaneous record of subsurface pressure from this island lagoon. A factor m, converting round-trip acoustic travel time to surface dynamic height relative to a deep pressure level, was estimated from the ratio of the spectra of the two records in the energetic synoptic oscillation band. Year-to-year variation in m was not statistically significant. For the overall record, m was found to be -70±8 dynamic m/s, where the error bounds represent a 90% confidence interval. This is consistent with first-baroclinic-mode excitation     

Three-dimensional linear solution for wave propagation with slopingbottom

This paper presents a three-dimensional analytic linear wave solution for surface gravity wave propagation over a sloping bottom that is valid for small, but realistic, slopes. The sloping-bottom linear model is compared to published laboratory data and to predictions of two-dimensional, constant-bottom nonlinear theories. The model is shown to describe the measured wave-height growth in the wave transformation region up to a limiting local Ursell number U_r of 0.35-1.0, depending on the wave type, although, as a linear model, it does not predict the harmonics observed in that range. For U_r<0.35, the harmonics can generally be neglected and the sloping-bottom linear theory agrees closely with both the published wave-height data and third-order Stokes nonlinear theory. As a three-dimensional linear model, superposition can be invoked to synthesize and relate wave structure in the transformation region to complex incident ocean spectra with both wind wave and swell components that arrive with a range of incidence angles. As such, the sloping-bottom linear model presented here should be a convenient useful tool for ocean modeling through a significant portion of the wave transformation region